Decision-making on the optimum transition pathway to an energy economy that meets agreed carbon reduction goals in the European Union (EU) by 2050 is challenging, because of the size of the infrastructural legacy, technological uncertainties, affordability and assumptions on future energy demand. This task is even more complicated in transportation because of additional issues, such as minimum travel range at acceptable impact on payload and ensuring hazzle-free long-distance driving in case of regionally varying fuel economies. Biofuels were the first viable option for a large-scale partly renewable fuel economy. E10 and B7 fuels have been successfully and remarkably smoothly introduced, owing to the fact that these are liquid and can be used in conventional combustion engines with little impact on full-tank travel range. In contrast, the decision-making process on biofuels in the EU has been particularly turbulent, with an initially favourable assessment changing into controversial. Here the compatibility between the fuel economies of member states and avoidance of disruptive social effects are considered as essential pre-requisite of a viable transition pathway. Rebalancing three different aspects of the social dimension of sustainability is used to demonstrate that a succession of infrastructures based on liquid fuels, with biofuels as an interlock towards an economy that includes methanol-based eFuel, has the potential to bring continuity, reduce dependence on anticipated technological advances and improve cost management. Awareness of this underexposed prospect of biofuel may positively affect the assessment on its role in a low-carbon fuel economy, potentially influencing the current decision-making process on biofuels.

The resistive particulate matter sensor is a simple device that transduces the presence of soot through impedance change across inter-digital electrodes (IDEs). We investigate the information provided by impedance spectroscopy over the frequency range from 100 Hz to 10 kHz for two purposes. The first is to investigate the opportunities for an improved sensor response to particulate matter (PM), based on the additional information provided by the measurement of both the in-phase (resistive) and out-of-phase (capacitive) components of the change in impedance over this frequency range as compared to DC resistance measurement only. Secondly, the origin of the capacitive response of the device is investigated from the perspective that soot on the device is in the form of bendable dendrites that grow in three dimensions. An IDE structure with the housing acting as an additional suspended electrode for introducing a controllable vertical electric field component has been used for this purpose. The formation of dipoles, due to bending of the charged dendrites, is found to be the source of the capacitive response. Simulation of electrostatic soot deposition reinforces dendritic self-assembly mechanisms, driven by charged particle trajectories along electric field lines. Optical microscopy confirms that dendrites growing out of the substrate plane are sensitive to electric and flow forces, bending when force balances are appropriate. We also apply impedance spectroscopy under varying electric field strengths, showing that capacitive response is only observed when conditions are conducive to dendrite bending in response to the applied AC electric fields.

Exhaust gas measurement in the harsh environment of the tailpipe by optical techniques is a highly robust technique, provided that optical access is maintained in the presence of soot. The design, fabrication, and testing of membranes in SiC-on-Si with integrated heaters to serve as a regenerable MEMS optical window into the tailpipe are presented. Membranes at slightly elevated temperatures are demonstrated to keep the surface transparent by thermophoresis, while surface regeneration is achieved at pulsed high temperatures, which allows long-term optical measurement in the exhaust.

Ensuring optical transparency over a wide spectral range of a window with a view into the tailpipe of the combustion engine, while it is exposed to the harsh environment of sootcontaining exhaust gas, is an essential pre-requisite for introducing optical techniques for long-term monitoring of automotive emissions. Therefore, a regenerable window composed of an optically transparent polysilicon-carbide membrane with a diameter ranging from 100 µm up to 2000 µm has been fabricated in microelectromechanical systems (MEMS) technology. In the first operating mode, window transparency is periodically restored by pulsed heating of the membrane using an integrated resistor for heating to temperatures that result in oxidation of deposited soot (600–700 °C). In the second mode, the membrane is kept transparent by repelling soot particles using thermophoresis. The same integrated resistor is used to yield a temperature gradient by continuous moderate-temperature heating. Realized devices have been subjected to laboratory soot exposure experiments. Membrane temperatures exceeding 500 °C have been achieved without damage to the membrane. Moreover, heating of membranes to ΔT = 40 °C above gas temperature provides sufficient thermophoretic repulsion to prevent particle deposition and maintain transparency at high soot exposure, while non-heated identical membranes on the same die and at the same exposure are heavily contaminated.

This work focusses on the design and fabrication of surface micromachined pressure sensors, designed in a modular way for the integration with analog front-end read-out electronics. Polycrystalline 3C silicon carbide (SiC) was used to fabricate free-standing high topography cavities exploiting surface micromaching. The poly-SiC was in-situ doped and the membrane itself is used as piezoresistive element, thereby forming a so-called self-sensing membrane, easing fabrication. After sacrificial release, the cavity is sealed by conformal deposition of poly-SiC whereby the reference pressure of the absolute pressure sensor is determined. Aluminum and titanium metallizations were used and ohmic contacts were confirmed by wafer-scale measurements. Measurements were carried out on different devices ranging from 100 kPa down to 10 Pa at room temperature. The Wheatstone bridge yields a logarithmic response of 1.1 mVbar-1 V-1. A square 300 μ m device exhibits a logarithmic impedance behavior yielding a response of Δ R/R of 1.6× 10-3 bar-1. The realized pressure devices are a first step toward a SiC ASIC + MEMS platform for intended operation in harsh environments, such as industrial process monitoring, combustion control or structural health monitoring. The future outlook of the integration concept implies extended functionality by front-end transducer read-out, signal amplification and communication.

This work describes the design, modelling and realisation of the mechanical part of a non-linear MEMS accelerometer intended for large displacement behaviour. For this, a mass/spring system was designed with an extremely low resonance frequency. In this work the mechanical behaviour was verified by measurements done using an optical setup, including a laser and photodiode. The results are a resonance frequency of 12.6 Hz, which can be further tuned depending on the application by varying the mass, beam thickness and tilt of the structure. This results in a mechanical sensitivity of 0.16 [mm/ms-2]. The future goal of this work is to integrate a read-out scheme on wafer level, for example electrostatically.

The mechanical part of inertial sensors can be designed to have a large mechanical sensitivity, but also requires the transduction mechanism which translates this displacement. The overall system resolution in mechanical inertial sensors is dictated by the noise contribution of each stage and the magnitude of each sensitivity, see also Figure 1. Maximizing the capacitive sensitivity, results in suppression of noise in the electronics domain. This work focuses on the design and realization of a mechanical to electrical transduction using a capacitive readout scheme. Design considerations and measures are taken to maximize the latter are considered and illustrated using FEM simulations. A capacitive transducer showing a sensitivity of 100 [aF/nm] was designed and realized, by exploiting the large displacement behavior of the inertial sensor which was considered.

In this work a method is described to investigate process variations across a wafer. Through wafer MEMS spiral resonators were designed, simulated, fabricated and characterized by measuring the eigenfrequency and corresponding mode shapes. Measuring the eigenfrequency and resulting spectral behavior of resonators on different locations on the wafer was performed by using an optical measurement setup. Two laser beams were used where one is modulated by the periodic movement of the center mass of the resonator. One of the beams is reflected back from the modulated resonator and this beam hits a photo diode. Variations in light intensity due to movement of the resonator is providing a measurement signal correlated to movement. Preliminary measurements showed that measured eigenfrequencies are in correspondence with the simulations within a range of 0-10% deviation.

A capacitive probe is generally used in a flex-fuel engine for measuring the ethanol content in biofuel. However, the water content in biofuel of high ethanol content cannot be disregarded or considered constant and the full composition measurement of ethanol, gasoline and water in biofuel is required. Electrical impedance spectroscopy with a customized capacitive probe operating in the 10 kHz to 1 MHz frequency range is combined with optical absorption spectroscopy in the UV spectral range between 230 and 300 nm for a full composition measurement. This approach is experimentally validated using actual fuels and the results demonstrate that electrical impedance spectroscopy when supplemented with optical impedance spectroscopy can be used to fully determine the composition of the biofuel and applied for a more effective engine management. A concept for a low-cost combined measurement system in the fuel line is presented.