When serving in the marine environment, reinforced concrete structures are prone to be attacked by chloride ingress, which generally co-occurs with varying humidity and temperature changes. Therefore, considering the interaction between moisture transport and heat transfer, and their individual and coupling effects on chloride transport, this paper presents a novel numerical modelling framework for chloride penetration in concrete under different environmental conditions. In this framework, a novel thermal conductivity model and temperature-depended chloride binding isotherms are also developed, considering the heterogeneous characteristics of concrete. The proposed model is validated against a series of experimental data. By assuming the cyclic humidity and temperature boundary conditions as trigonometric type, this study further discusses the effect of average value, amplitude value and period length of cyclic environmental changes on the chloride transport in concrete. The results indicate that variation in humidity and temperature averages can alter the peak values of chloride content but have less effect on the chloride penetration depth. However, the increased humidity amplitude could significantly promote both the peaks and the penetration depths due to intensive chloride convection caused by moisture transport. This paper is supposed to provide a better understanding of chloride penetration in concrete under a realistic engineering environment.

@en

Circulating fluidized bed fly ash (CFBFA) is a by-product from the combustion in circulating fluidized bed boiler in power plants. Herein, to resourcefully utilize CFBFA and reduce cement consumption, the CFBFA was ground (GCFBFA) and used to prepare low-carbon lightweight foamed concrete (LFC) for subgrade filling. The effect of GCFBFA substitution ratio on the blended cement binder and LFC was investigated. It was found that incorporation of 30 wt% GCFBFA stimulated cement hydration and produced more hydration products including C-S-H and AFt, thus enhancing the performance of binder. For LFC, GCFBFA improved the stability of fresh LFC slurry and the air-void structure by increasing the rheological properties of binder, thus improving the mechanical properties and durability including water stability and freeze-thaw resistance. The extension of setting time and reduction in hydration heat due to GCFBFA can be beneficial for transportation and massive construction. For subgrade filling, the GCFBFA content is limited to 50 wt% for LFC with wet density of 600 kg/m3 (D600) and up to 70 wt% for D700 and D800. Life cycle assessment (LCA) showed that a reduction of 52.3% in global warming potential and 43.2% in total cumulative energy consumption for the production of LFC was achieved when GCFBFA replaced 70% of cement.@en

Herein, a three-dimensional numerical model based on computational fluid dynamics (CFD) for fresh concrete is developed to predict the slump and slump flow. Fresh concrete is considered as a non-Newtonian fluid, and its rheological behaviour is characterised by the Bingham and Herschel-Bulkley (H-B) models, respectively. Experiments are also conducted to validate the reliability and accuracy of this model. Through parametric investigations, the influence mechanisms of relevant factors on the flow characteristics of fresh concrete are analysed and discussed. The results show that the model predictions agree well with the experimental results. The predicted results obtained using the H-B rheological model are more accurate compared to the Bingham model, with average relative errors of 1.73 %, 2.03 % and 3.95 % for slump, slump flow and T₅₀₀, respectively. The flowability of fresh concrete is negatively correlated with power index, yield stress and consistency, while it is positively correlated with density. Grey relational analysis indicates that density has the greatest effect on the results of slump and slump flow, followed by yield stress and consistency, and finally the power index. The CFD-based numerical model presented in this study provides an important approach for better understanding the flow behaviour of fresh concrete from a rheological perspective.

@en

Engineered cementitious composite (ECC) is widely employed in engineering due to its high toughness and ductility. The Interfacial Transition Zone (ITZ) between the fibers and the matrix plays a vital role in influencing the strength and durability of ECC. This study introduces a numerical method to simulate fiber pull-out behaviors, specifically the fiber debonding and slipping. A birth-death method is proposed to account for the mechanical transition from fiber debonding stage to slipping stage. The contributions of various phases in the ITZ are explicitly considered. Furthermore, nanoindentation tests and Backscattered Electron (BSE) imaging were conducted to determine the microstructures of ITZ and local mechanical properties of each phase within the ITZ. A series of fiber pullout experiments with polyvinyl alcohol (PVA) fibers were conducted to calibrate and validate the model. Subsequently, the validated model was employed to explore the influence of w/c ratios, fiber orientations and bonding properties on the interfacial behavior. The microstructure-informed model proposed herein effectively predicts fiber pull-out behavior, facilitating a thorough exploration of fracture mechanisms throughout the pull-out process, and serves as the basis for multiscale modeling of ECC.

@en

Self-healing concrete using encapsulated healing agent has shown great potential in enhancing concrete durability. However, the capsules are expensive to make and can lower the mechanical properties of concrete. In this study, a new type of manufactured aggregate that employs waste-derived fly ash cenosphere as a carrier of healing agent (SH-CS) was designed and produced. The effect of SH-CS incorporation on hydration, engineering properties and self-healing efficiency of cement mortar was systematically evaluated, with a special focus on self-healing mechanism through the analysis of the mineral composition of the healing product. The results indicate that the prepared SH-CS has good stability in and compatibility with cement mortar. The addition of SH-CS has small influence on the fresh properties of cement mortar and less negative effect on compressive strength at the hardened stage compared to the existing study. By replacing 3 wt.% of fine aggregate with SH-CS, up to 71% of the crack opening area of mortar specimens with a crack width of about 0.3 mm was self-healed after 28 days of water exposure. The self-healing behaviour of SH-CS led to a maximal 41% drop in water adsorption and contributed to the recovery of flexural strength. The healing products precipitated on the fracture surface were mainly composed of amorphous C-S-H and Calcite. It can be estimated that incorporating SH-CS in concrete would result in only a moderate (∼29%) rise in cost for C40 concrete.

@en

This study investigates the mechanical properties of cementitious composites with 3D-printed auxetic lattices, featuring negative Poisson's ratios (auxetic behavior) in multiple directions. These lattices were fabricated using vat photopolymerization 3D printing, and three base materials with varying stiffness and deformation capacities were analyzed to determine their impact on the composites’ mechanical behavior. To unravel the reinforcing mechanisms of multidirectional auxetic lattices, which exhibit auxetic behavior in both planar and out-of-plane directions, X-ray computed tomography (X-ray CT) was utilized to analyze composite damage evolutions under different strain levels. The micro-CT characterization reveals that auxetic lattices more effectively constrain crack growth and dissipate energy by distributing stress evenly within the cement matrix. In contrast, due to lack of lateral confinement, the non-auxetic lattice reinforced composites primarily dissipate energy through extensive crack propagation and interfacial damage, leading to lower peak strength. When strain exceeding 5%, although the confinement from the auxetic behavior diminished with crack propagation, the lattice can still maintain the composite's structural integrity, resulting in 1.7 times higher densification energy than conventional cement-based materials. These findings provide valuable insights for designing auxetic lattice-reinforced cementitious composites with enhanced load-bearing capacity and improved dissipation capabilities.

@en

Temperature Stress Testing Machine (TSTM) is a universal testing tool for many properties relevant to early-age cracking of cementitious materials. However, the complexity of TSTMs require heavy lab work and thus hinders a more thorough parametric study on a range of cementitious materials. This study presents the development and validation of a Mini-TSTM for efficiently testing the autogenous deformation (AD), viscoelastic properties, and their combined results, the early-age stress (EAS). The setup was validated through systematic tests of EAS, AD, elastic modulus, and creep. Besides, the heating/cooling capability of the setup was examined by tests of coefficient of thermal expansion by temperature cycles. The results of EAS correspond well to that of AD, which qualitatively validates the developed setup. To quantitatively validate the setup, a classical viscoelastic model was built, based on the scenario of a 1-D uniaxial restraint test, to predict the EAS results with the tested AD, elastic modulus, and creep of the same cementitious material as the input. The predicted EAS matched the testing results of Mini-TSTM with good accuracy in 6 different cases. The viscoelastic model also provided quantitative explanations for why variations in early AD do not influence the EAS results. The testing and modelling results together validate the developed Mini-TSTM setup as an efficient tool for studying early-age cracking of cementitious materials. At the end, the potential limitations of the Mini-TSTM are discussed and its applicability for concrete with aggregate size up to 22 mm is demonstrated.

@en

This review provides a comprehensive analysis of the fatigue behaviour of cementitious materials, focusing on the characterisation, modelling, and mechanisms underlying their fatigue properties. It begins with a detailed exploration of how material composition and loading conditions influence fatigue performance, along with the underlying mechanisms that govern fatigue fracture processes. The review also synthesises current advanced experimental methods for characterising fatigue damage evolution, highlighting significant achievements and methodological innovations. It also examines theoretical approaches, summarising prominent models and emerging theories that deepen the understanding of fatigue behaviour in cementitious materials. Meanwhile, the paper reviews computational techniques based on fracture mechanics, damage mechanics, statistical analysis, machine learning algorithms and multiscale modelling, assessing their potential to improve the accuracy of fatigue predictions. Lastly, the review identifies crucial research gaps and outlines future directions, particularly in understanding fatigue-related coupling mechanisms to enhance the fatigue resistance and durability of cementitious materials.

@en

This study investigates the size effect on the compressive strength of foamed concrete at the mesoscale level combining X-ray computed tomography (X-CT) and a discrete lattice model. Image segmentation techniques and X-CT were employed to obtain virtual specimens comprising hydrated cement paste and air voids. The lineal-path function and pore size distribution was used to characterise the air void structure. A two-dimensional lattice fracture model of foamed concrete considering different wet densities was established. The model was verified experimentally at a wet density of 700 kg/m³ and then used to predict the strengths of specimens with wet densities of 600 and 800 kg/m³. Square and rectangular specimens (slenderness ratio = 2) with widths of 10, 20, 40, 70.7, and 100 mm were investigated. Results show that the air void structure significantly influences the observed size effect on the compressive strength in the investigated size range. A random forest regressor was used to predict the compressive strength of the foamed concrete; the regressor yielded satisfactory results. Finally, existing analytical size effect models were used to fit the simulated strength. Although good fitting was achieved, special attention should be given to the applicable range and physical meaning of fitted empirical parameters.

@en

3D printed concrete (3DPC) creates opportunities, including a reduction in construction waste and time and increased design freedom. However, because of the differences in the construction technique compared to traditional concrete casting, the structures also perform differently; namely, the micro- and meso-structure and durability are shown to be different. For the 3DP technology to find its way to the market, one needs to be aware of these differences and needs to know how to quantify the above-mentioned properties, as differences in the testing methodologies impose themselves when characterizing printed instead of cast concrete. In this paper, we elaborate on the test methods to investigate the micro- and meso-structure and the durability of 3DPC. We start with a discussion on the micro- and meso-structure of the 3D printed concrete and how it is different from conventional mold-cast concrete. An in-depth discussion of the test methods to assess the durability of 3D printed concrete is outlined. Reported findings related to the two aforementioned properties are discussed. In addition, we report on the technologies proposed to improve the durability performance of 3DPC, and we highlight the remaining challenges and opportunities related to 3DPC.@en

Cenospheres are low-density and hollow microspheres derived from coal-fired power plant fly ash waste. This study aims to prepare ultra-light-weight (<1000 kg/m³ wet density) concrete using fly ash cenospheres (FAC). To begin with, FAC's shell thickness and the water absorption and desorption were characterized. A mixing procedure was designed to avoid the segregation between the FAC and cement slurry. FAC can affect the rheological properties of fresh mixture over time through absorption and desorption of free water. The presented ultra-light-weight concrete has several advantages compared to the ones prepared using foaming methods. First, shrinkage is significantly reduced due to FAC's internal restraint and curing effects. Secondly, it has good mechanical performance, especially in bending and is more environmentally friendly due to use of less cement. X-ray computed tomography illustrates that FAC ultra-light-weight concrete has smaller pores of more uniform size compared with those prepared using foaming methods. X-Ray diffraction, thermal gravimetry-derivative thermal gravimetry, fourier-transform infrared spectroscopy and scanning electron microscopy are employed for the hydration products and microstructure characterization. Outcomes prove that FAC can combine well with the cement matrix, and react with calcium hydroxide to produce C-A-S-H through pozzolanic reaction.

@en

Vascular self-healing concrete (SHC) has great potential to mitigate the environmental impact of the construction industry by increasing the durability of structures. Designing concrete with high initial mechanical properties by searching a specific arrangement of vascular structure is of great importance. Herein, an automatic optimization method is proposed to arrange vascular configuration for minimizing the adverse influence of vascular system through a reinforcement learning (RL) approach. A case study is carried out to optimize a concrete beam with 3 pores (representing a vascular network) positioned in the beam midspan within a design space of 40 possibilities. The optimization is performed by the interaction between RL agent and Abaqus simulation environment with the change of target properties as a reward signal. The results illustrates that the RL approach is able to automatically enhance the vascular arrangement of SHC given the fact that the 3-pore structures that have the maximum target mechanical property (i.e., peak load or fracture energy) are accessed for all of the independent runs. The RL optimization method is capable of identifying the structure with high fracture energy in the new optimization task for 4-pore concrete structure.

@en

3D printed polymeric reinforcement has been found able to improve the ductility of cementitious materials. However, due to the hydrophobic nature of commonly used 3D printing polymers, the bonding strength between the 3D printed polymers and cementitious matrix is extremely weak, which potentially hinders the mechanical performance of the reinforced composites. This work aims to improve the bonding properties by applying surface modifications on the 3D printed reinforcement, and eventually enhance the mechanical performance of the reinforced cementitious composites. Three types of surface coatings ingredients: epoxy resin (EP), sand sprinkled epoxy (SA) and short steel fibers sprinkled epoxy (SF) were used. Pull-out experiments are performed to study the bonding properties of the 3D printed reinforcement with different coatings. Then, uniaxial tensile and four-point-bending experiments are used to investigate the mechanical performance of the reinforced cementitious composites. A lattice type numerical model is applied to simulate the pull-out and tensile tests. The pull-out experiments indicate that the SA and SF reinforcement achieved approximately two times higher bonding strength than the uncoated and EP reinforcement. The tensile and flexural results suggest that the cementitious composites with SA and SF reinforcement achieved significantly better ductility (manifested by strain-hardening and deflection-hardening behavior) than the composites with uncoated and EP reinforcement. The numerical simulation results highly agree with the experimental findings, and further confirmed that the improved reinforcement-mortar bonding strength is the determinative factor that enhanced the composites mechanical performance. The findings of this work suggest that the sand and steel fiber surface coatings can effectively enhance the ductility of cementitious composites reinforced by 3D printed polymers.@en

Auxetic cementitious cellular composites (ACCCs) exhibit desirable mechanical properties (e.g., high fracture resistance and energy dissipation), due to their unique deformation characteristics. In this study, a new type of cementitious auxetic material, referred to as peanut shaped ACCC, has been designed and subsequently architected using additive manufacturing techniques. Two peanut shaped ACCCs specimens with different pseudo-minor axes have been tested under uniaxial compression with Digital Image Correlation (DIC) to assess their compressive behavior, peak strength, Poisson's ratio, and energy dissipation capacity. Additionally, cyclic tests were conducted to investigate their compressive resilience properties, further elucidated through microstructural analysis using a digital optical microscope. The mechanical test results were also compared with those of previously developed elliptical-shaped ACCCs. Furthermore, a numerical model was used to simulate the mechanical behavior of peanut shaped ACCCs under uniaxial compression, and showed a good agreement with the experimental data. The auxetic behavior observed in peanut shaped ACCCs arises from the rotation of sections facilitated by fiber bridging at the ligament of adjacent holes within the cementitious unit cell. In comparison to elliptical-shaped ACCCs, peanut shaped ACCCs can exhibit a slightly more negative Poisson's ratio and mitigate stress concentration. The reduction of stress concentration enables peanut shaped ACCCs to dissipate substantial energy, showcasing enhanced ductility and toughness. In cyclic tests, peanut shaped ACCCs exhibit superior recoverable deformation elasticity, attributed to robust fiber bridging capacity. The exceptional mechanical properties exhibited by peanut shaped ACCCs offer a scalable solution for developing energy-absorbent and multifunctional cementitious materials for smart infrastructure.

@en

A novel highly compressible auxetic cementitious composite (ACC) is developed in this work. Contrary to conventional cementitious materials, such as plain concrete and fiber reinforced concrete, the ACC shows strain-hardening behavior under uniaxial compression: the stress continuously increases with strain up to approximately 40 % strain. On one hand, in the early compression stage, the ACC exhibit highly recoverable deformability of 10 % strain under cyclic loading (20 times higher than the constituent cementitious material). In addition, the ACC shows fatigue damage until the stiffness/strength and energy dissipation plateau values are reached after 500 cycles. At 2.5 % strain amplitude, the plateau stiffness/strength is approximately 120 MPa/3 MPa, while these values are only 25 MPa/1.2 MPa at 5 % strain amplitude. In contrast, the energy dissipation plateau of the ACC is independent from the amplitude and remains at 0.05 J/cm3. On the other hand, due to the strain-hardening behavior, the ACC exhibits significantly improved energy dissipation capacity compared to both the conventional cementitious materials and the auxetic frame. This behavior is achieved by a tailored composite action: integrating cementitious mortar with 3D printed thermoplastic polyurethane (TPU) auxetic frame. A rotating-square auxetic mechanism was designed for the TPU frame for the ACC to achieve the tailored cracking behavior. The horizontal ACC cells enable large deformability by enlarging the crack width under the confinement of the auxetic frame, while the vertical cells work as stiffening phase to ensure load resistance. Owing to the outstanding mechanical properties, the ACC shows great potential to be applied in engineering practice where high compressive deformability is required, for instance yielding elements for squeezing tunnel linings.

@en

This paper presents a state-of-the-art review on the application of additive manufacturing (AM) in self-healing cementitious materials. AM has been utilized in self-healing cementitious materials in three ways: (1) concrete with 3D-printed capsules/vasculatures; (2) 3D concrete printing (3DCP) with fibers or supplementary cementitious materials (SCMs); and (3) a combination of (1) and (2). 3D-printed capsules/vascular systems are the most extensively investigated, which are capable of housing larger volumes of healing agents. However, due to the dimension restraints of printers, most of the printed vasculatures/capsules are in small scale, making them difficult for upscaling. Meanwhile, 3DCP shows great potential to lower the environmental footprint of concrete construction. Incorporation of fibers and SCMs helps improve the autogenous healing performance of 3DCP. Besides, 3D-printed concrete with hollow channels as the vasculature could further improve the autonomous healing and scalability of self-healing cementitious materials. Finally, possible directions for future research are discussed.

@en

One particularly interesting class of mechanical metamaterials are those having a negative Poisson's ratio, which are referred to as ‘auxetics’. Because of their geometrical complexity, auxetic designs cannot always be easily created. However, Additive Manufacturing (AM) methods like material extrusion in 3D printing present the opportunity to construct auxetic structures. Nevertheless, extruded 3D printed material can be highly anisotropic. Before 3D printed auxetics manufactured through material extrusion can be used in engineering applications, it is important to generate powerful simulation tools that can reliably reproduce and foretell their mechanical characteristics irrespective of their form and intricacy. In view of this, the current work proposes printing path-dependent models based on an experimentally validated multi-scale modelling scheme using the Lattice Beam Model (LBM). This is done by first representing idealized microstructures of extruded 3D printed polymers through geometric models and simulating these on the material scale. The aim is to explicitly model the inter-layer and intra-layer bonds that exist in material extruded 3D printed parts by assigning experimentally obtained interface properties that significantly differ from the bulk material. On the auxetic structure scale, two planar auxetic designs are modelled using the determined material scale relationships as input: Re-Entrant (RE) and Rotating Square (RS). In terms of mechanical response, the experimentally and numerically obtained force displacement curves agree reasonably well: the stiffness of the modelled auxetic designs fit well with the experimentally measured ones while the LBM simulations generally provide a good estimation in strength. Finally, it has been shown on both the material and auxetic structure scales that incorporation of the interfacial bond strengths in simulations of extruded 3D printed polymers is important, because neglecting these results in significant overestimation of the strength.

@en

Crystalline admixture (CA) is an effective self-healing agent for mortar. However, the effects of crack parameters (i.e. crack width and cracking age) and the service environment on the self-healing behavior of CA-containing mortar are not well understood. Herein, the self-healing behavior of mortar containing a self-developed CA was assessed by testing strength recovery, impermeability recovery, and crack closure in pre-cracked specimens. Three initial crack widths (0.2, 0.3, and 0.4 mm), five cracking ages (3, 7, 14, 28, and 56 days), and four external exposure conditions (humidity chamber, air exposure, water immersion, and wet-dry cycles) are investigated. Furthermore, the influence of different external conditions on the healing products at the region of crack and the pore structure of hardened paste containing CA are studied. The results show that adding 4.54% CA into mortar allows rapid healing of 300 μm-wide cracks. Although wider cracks (400 μm) are more difficult to heal, the sorptivity coefficients of the mortars with 400 μm-wide cracks after healing decrease. When the cracks are produced at an earlier age, the pre-cracked specimens have higher recovery ratios of strength and impermeability after healing, and the specimens pe-cracked at a later age still have acceptable compressive strengths after healing. The analysis shows that the strengths and impermeabilities of pre-cracked mortars containing CA exposed to the four external conditions are all recovered. The best self-healing performance is observed for the specimens exposed to water immersion and wet-dry cycles conditions. Somewhat less good self-healing was observed in the specimens exposed to humid chamber condition, while the worst self-healing performance was in the specimens exposed to air exposure condition. This study provides a theoretical basis for the application of novel CAs in cement-based materials.

@en

A compounded system of fly ash (FA) and carbide slag (CS) was proposed for CO₂ mineralization using the aqueous approach to prepare supplementary cementitious material. Influence of CS dosage on the morphology, particle size distribution, and chemical phases of the carbonation products were characterized. It is found that the mineralization products (calcite) cover on the surface of FA leading to a remarkable synergistic effect in which the CO₂ uptake is improved by about 50%. Furthermore, FA with calcite attached effectively mitigates the set retardation in OPC/FA blends by about 30% and improved the 3- and 28-day compressive strengths by 37.2% and 24.3% respectively due to combined physical and chemical effects. The results indicate that a high-volume cement replacement can be achieved using the carbonated FA produced by the proposed synergy CO₂ mineralization.

@en

This study presents comprehensive numerical modeling methods for simulating early-age stress (EAS) relaxation in cementitious materials, based on the autogenous deformation (AD), elastic modulus, creep, and stress continuously tested by a mini temperature stress testing machine (Mini-TSTM) and a mini AD testing machine from a very early age (i.e., from a few hours to a week). Four methods for converting creep compliance to relaxation modulus were discussed in detail and used for the one-dimensional (1D) and three-dimensional (3D) simulation of stress evolution in the Mini-TSTM test. Furthermore, virtual creep and relaxation tests were conducted using an exponential algorithm with either the Kelvin or Maxwell chains to show their applicability in simulating the viscoelastic behavior of early-age cementitious materials. The results showed that the exponential algorithm with the Maxwell chain using an exponential conversion function from creep to relaxation obtains good prediction accuracy of EAS in 3D analysis. The numerical solutions of the Volterra integral of creep compliance can lead to a negative relaxation modulus, thus introducing stress calculation errors in both 1D and 3D analysis.

@en