This study characterized the morphology, high-temperature property, rheological property, adhesion, cohesion, and chemical component of asphalt binder under aqueous solutions of different pH values. Then the physicochemical properties of asphalt binder were comprehensively evaluated by the improved radar chart. The properties of asphalt binder stripped layer-by-layer were explored to elucidate its gradient damage behaviors. The results indicate that the pH 3 solution reveals the greatest impact on the morphology of 90 asphalt (90 A) and styrene-butadiene-styrene modified asphalt (SBS MA), leading to the wide cracks on 90 A and the network cracks on SBS MA. The comprehensive assessment index of 90 A exposed to pH 3, pH 5, pH 7, pH 9, and pH 11 solutions can be reduced by 20.8%, 20.2%, 1.5%, 14.0%, and 25.5%, respectively. While for SBS MA, its corresponding values variation are 23.2%, 17.7%, 4.6%, 8.7%, and 13.0%, respectively. The acid solutions significantly affect the comprehensive properties of 90 A, but their pH value has little effect. 90 A exposure to the higher pH value of alkali solution reveals the worse comprehensive properties. Acid solute and alkali solute can aggravate the effect of aqueous solution on the comprehensive properties of SBS MA, and the degree of aggravation increases with the increase of solute concentration. The properties of asphalt binders exhibit varied gradient damage behaviors under different solute environments. The most serious damage occurs at 25–50 µm of 90 A and 0–50 µm of SBS MA. This study facilitates an accurate understanding of the mechanism of pavement distresses and composition design and construction utilization of asphalt binders.

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Generally, rejuvenators are used to supply missing components of aged asphalt, reverse the aging process, and are widely used in asphalt maintenance and recycling. However, compared with traditional rejuvenators, bio-oil rejuvenators are environmentally friendly, economical and efficient. This study looks into the effect of the three different bio-oils, namely sunflower oil, soybean oil, and palm oil, on the physical properties, rheological properties and chemical components of aged asphalt at different dosages. The asphalt physical properties and Dynamic Shear Rheological (DSR) test results show that with the increase in bio-oil, the physical properties and rheological properties of rejuvenated asphalt are close to those of virgin asphalt, but the high-temperature rutting resistance needs to be further improved. The results of Fourier Transform Infrared Spectroscopy (FTIR) show that the carbonyl and sulfoxide indices of rejuvenated asphalt are much lower than those of aged asphalt. Moreover, the rejuvenation efficiency of aged asphalt mixed with sunflower oil is better than that with soybean oil and palm oil at the same dosage. @en

9,10-Dihydro-9-oxa-10-phosphorophenanthrene-10-oxide (DOPO), recognized for its role as an efficacious fume suppressant, has been shown to mitigate the emission of noxious vapors emanating from asphalt. However, the comprehensive influence of DOPO on the composition and properties of asphalt had remained unexplored. This study embarked on an in-depth examination of the effects of various DOPO dosages on the chemical composition of asphalt, employing hydrogen nuclear magnetic resonance spectroscopy (¹H NMR) alongside an exhaustive analysis of asphalt components. Furthermore, the investigation elucidated the consequences of different DOPO dosages on the physical, rheological properties, and aging resistance of asphalt. The results of ¹H NMR and component analysis of asphalt disclosed that DOPO engaged in chemical reactions with the unsaturated groups within the asphalt, catalyzing a metamorphosis of saturates into aromatics and resins. Such chemical transformations were instrumental in augmenting the softening point, viscosity, and rutting propensity of the asphalt while imposing a minimal impact on its penetration and ductility. Post exposure to the thin film oven test (TFOT), pressure aging vessel (PAV), and ultraviolet (UV) aging, the DOPO modified asphalt (DMA) exhibited a diminution in the increment of softening point and viscosity aging index relative to the control asphalt. Furthermore, the DMA showcased enhanced retention rates of penetration and ductility, coupled with substantially reduced shifts in complex modulus and phase angle post-aging, underlining its superior aging resistance. Fourier transform infrared spectroscopy analysis revealed a comparatively slower rate of change in carbonyl and sulfoxide groups in DMA after aging, as opposed to the control asphalt. Notably, DMA exhibited enhanced resistance to UV aging relative to TFOT and PAV aging scenarios, a trait attributable to remarkable UV absorption capabilities of DOPO. Fundamentally, DOPO enhanced the high-temperature performance and aging resistance of asphalt while simultaneously diminishing the emission of noxious fumes.

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An asphalt joint is formed when a fresh mix is laid and compacted next to an existing layer, brings about temperature difference during compaction, and therefore requires extra care in quality control and expose to higher cracking risks. Self-healing asphalt aims to stimulate the healing capacity of asphalt mixture and prolong its service life. The main objective of this study is to develop and optimize a calcium alginate capsules healing system for an asphalt joint mix. Capsules following two different self-healing concepts were prepared, namely conventional alginate capsules and conductive alginate capsules. Microscopy, Computed Tomography (CT) and Thermogravimetry analysis (TGA) were used to investigate the performance of alginate capsules. The results show that both types of capsules have a porous structure and a stable performance under high temperature, and therefore potentially survive from the asphalt mixing and production process. These capsules will be implemented and evaluated in full asphalt mix in future research.

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As the main waste product of iron and steel industry, steel slag possesses considerable cementitious activity, making it a promising alternative to cement in Cement Stabilized Macadam (CSM). However, CSM was inevitably exposed to groundwater and rainwater when served as the pavement base course, leading to concerns over poor early strength and potential pollutant leakage, which are the main factors that may hinder the widespread utilization of steel slag in CSM base. To address these issues, this study investigated the feasibility of using steel slag powder to produce CSM. Steel Slag Powder-Cement Stabilized Macadam (SSCSM) samples were prepared and the hydration products, microstructure, mechanical properties, water damage resistance and heavy metal ions leaching behavior were investigated. The results show that the nucleation effect of steel slag powder accelerates the early hydration, but the C-S-H produced by hydration is not sufficient to form a stable hydration product network, so the microstructure of SSCSM is looser than that of CSM. The addition of steel slag powder improved the shrinkage performance of SSCSM, and the mechanical properties and heavy metal ion leaching concentration of SSCSM meet the engineering application requirements when the steel slag powder replacement level does not exceed 30 %. It was also found that the addition of steel slag powder promoted the development of pores in SSCSM samples after dry-wet cycles, resulting in the reduction of water damage resistance. Compared with conventional CSM, the use of SSCSM can not only reduce 4 % of raw material cost and 23.5 % of equivalent CO₂ emission, but also mitigate the heavy metal ions leaching risk associated with steel slag, making it an effective and sustainable solution for steel slag recycling.

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Layered double hydroxides (LDHs) can shield polymeric materials from UV light, which allows reducing material aging and erosion damage of bituminous pavement under physical and chemical action. In this study, the physicochemical properties, aging resistance, and erosion resistance to the aqueous solution of LDHs modified bitumen mastic (BM) were characterized by Fourier-transform infrared spectroscopy, basic physical tests, viscosity tests, a dynamic shear rheometer, and a bending beam rheometer. The results show that few chemical reactions occurred between LDHs and BM, indicating that a physical mechanism underlay the modification of BM by LDHs. Moreover, LDHs could increase the flow activation energy of BM by 0.12%, increase the high failure temperature from 69.07 °C to 71.07 °C, and decrease the low failure temperature from −10.50 °C to −12.39 °C. Therefore, LDHs could slightly reduce the temperature sensitivity of BM, while slightly enhancing the high and low-temperature rheological properties of BM. Compared with short-term aging and long-term aging, LDHs could significantly improve the UV aging resistance of BM. The above results are consistent with previous studies of LDHs-modified bitumen. Furthermore, water and pH 3 acidic solutions had the greatest degree of erosion to BM, and LDHs could improve the resistance to aqueous solutions. Overall, this study can help to investigate the effects of various environmental factors on the performance of LDHs modified bitumen pavements during long-term use.@en

Asphalt fumes released during pavement construction posed a threat to human health and environment. In this study, 9,10-dihydro-9-oxa-10-phosphorophenanthrene-10-oxide (DOPO) was used as a reactive fumes suppressant to reduce the asphalt fumes emission. The volatilization behavior of DOPO modified asphalt (DOPO-Asphalt) was investigated through thermogravimetric analysis, volatility test and thermal destruction gas chromatography mass spectrometry, and effect of DOPO on the chemical structure and composition of asphalt was explored through nuclear magnetic resonance hydrogen spectroscopy, Fourier transform infrared spectroscopy, and asphalt component testing. The results indicated that 1.0 wt% DOPO reduced the fume content of control asphalt by 1.1% from 120 ℃ − 200 ℃ and the H₂S and VOC content by 96.9% and 84.2%, respectively, at 180 ℃. Moreover, 1.0 wt% DOPO reduced the content of aliphatic hydrocarbons, hydrocarbon derivatives, aromatics, and sulfides in control asphalt fumes by 86.8%, 89.7%, 90.7%, and 93.5%, respectively, which may be attributed to electrophilic and nucleophilic reactions between DOPO and volatile substances in asphalt. Chemical structure and composition changing of DOPO-Asphalt confirmed that P-H bond in DOPO was chemically reacted with components in asphalt, generating stable aromatic hydrocarbons and resins. The results provided a novel method for inhibiting the volatilization of harmful substances in asphalt.

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Self-healing is a biological phenomenon in which living organism responds to the suffered damage in a complex way. Inspired by the self-healing phenomenon in nature, various biomimetic healing methods rooted in intrinsic or extrinsic healing mechanisms have been explored. Research on novel self-healing asphalt materials with intelligent response is at the cutting-edge of materials science and offers a potential strategy for building long-life and low-carbon asphalt concrete infrastructure. This paper describes the progress of research on extrinsic self-healing asphalt materials and makes a clear distinction between intrinsic and extrinsic self-healing. The asphalt self-healing mechanism is interpreted by capillary flow theory, phase field theory, molecular diffusion theory and surface energy theory form various perspective. The extrinsic self-healing strategies including thermal induced healing and rejuvenator induced healing are proposed to enhance the healing level of cracked asphalt materials. A brief review of the methods including fracture-healing test and fatigue-healing test for assessing the efficacy of different extrinsic healing methods is presented. The thermal induced healing method bring high crack repair efficiency for asphalt concrete and the rejuvenator induced healing strategy not only improve the healing ratio of cracked asphalt concrete but also regenerate the ageing asphalt in situ. Important lessons for prospective research on the creation of novel self-healing asphalt materials are highlighted.

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Microwave heating is an effective method to achieve autonomic crack healing in asphalt mixtures, and the use of microwave-absorbing materials can largely improve this healing efficiency. As a solid waste, coal gangue contains metal oxides, which shows the possibility of microwave heating. In order to further promote the application of coal gangue in the microwave healing of asphalt mixtures, this study looks into the synergistic effect of basalt and coal gangue powder (CGP) on the microwave heating self-healing of an asphalt mixture. The mechanical performance, water stability, low-temperature crack resistance and microwave healing efficiency of the asphalt mixture were investigated using the immersion Marshall test, standard Marshall test, Cantabro test and semi-circular bending (SCB), and healing tests, respectively. The results indicated that the addition of CGP in asphalt mixture can improve the microwave heating speed, which also showed a significant advantage in water stability and fracture energy recovery. The research results will further promote the utilization rate of coal gangue.@en

Moisture erosion is one of the key factors leading to asphalt pavement damage, and the erosion depth indicates the moisture damage level but it is usually neglected. In order to study the moisture erosion and the erosion depth, this study characterized the chemical structure, rheological property and adhesion property of asphalt at different depths after immersion for different periods. To further explore the diffusion mechanism of eroded asphalt, a Log-log numerical model was established based on the Fick's second law to calculate the diffusion coefficient throughout the depth. The results indicate that it takes just four hours for water to penetrate a 25 μm asphalt film. The relation between erosion depth and immersion period presents three stages, and the process can be fitted with a polynomial model. At the macroscopic level, there is a lag between the changes in adhesion property with chemical structure and rheological property. Additionally, the periodicity of moisture erosion process was verified by the calculation of diffusion factor. In summary, the diffusion mechanism of eroded asphalt by moisture can provide a theoretical basis for the development of laboratory moisture erosion test specification, thus avoiding the waste of raw materials.

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Aimed to address the low utilization rate of steel slag (SS) and its challenge in resource utilization in China, this study developed ternary geopolymers made by high-content (50%) SS together with fly ash (FA) and granulated blast furnace slag (GBFS). The effects of GBFS content (0–40%) and curing methods (water curing, standard curing, sealed curing, and heat curing) on the working performance and microstructure of geopolymers were investigated. Microscopic analysis such as X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FTIR), thermogravimetric analysis (TG-DTG), and scanning electron microscopy (SEM) were utilized to investigate the hydration process and products of geopolymers under different curing conditions and GBFS content. The results indicated that when the GBFS content increased from 0% to 40%, the fluidity of the mixture decreased by 11.7%, the initial setting time of the geopolymer slurry decreased by 76%, and the geopolymer mortar's 28d compressive strength increased from 31.9 MPa to 60.6 MPa. At room temperature, the geopolymer mortar's 28d compressive strength was higher under standard curing (70.8 MPa) compared to water curing (57.5 MPa) and sealed curing (68 MPa). The geopolymer mortar cured at 60 °C for 24 h exhibited the highest 28d compressive strength (76.3 MPa). However, excessively high curing temperatures or prolonged durations led to more shrinkage cracks and reduced the compressive strength. The microscopic analysis revealed that the main gel products of ternary geopolymer were C-(A)-S-H gel. The amount of gel products is directly related to the strength of geopolymers. The developed ternary geopolymer has the potential to promote the large-scale utilization of SS in the concrete industry, making a significant contribution to sustainable development.

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As a kind of solid waste, using Prestressed High-Strength Concrete Pile Waste Concrete (PPWC) as the replacement for limestone filler in asphalt concrete can not only reduce the accumulation of PPWC and increase its utilization but also avoid the increased road construction costs and environmental degradation associated with limestone mining. This study aims to investigate the effect of using PPWC filler to replace limestone filler on the road performance of asphalt concrete. Firstly, PPWC was ground into filler particles with a diameter less than 0.075 mm. The particle characteristics such as surface morphology, particle size distribution and chemical composition of PPWC filler and limestone filler were compared. Then, PPWC filler was used to replace limestone filler with different volume fractions to prepare asphalt concrete, and the water damage resistance, high-temperature rutting resistance, low-temperature crack resistance, fatigue resistance and adhesion performance of asphalt concrete were tested. The results showed that PPWC filler has a smaller particle size and rougher surface than limestone filler, and it contains Ca(OH)₂ produced by hydration. The addition of PPWC filler can effectively improve the mechanical properties of asphalt concrete without reducing its water damage resistance. PPWC filler can improve the high-temperature rutting resistance and low-temperature crack resistance of asphalt concrete, but reduce its low-temperature fatigue resistance. The low content of PPWC filler will enhance the adhesion between asphalt mortar and aggregate. However, when the content of PPWC filler exceeds 50%, Ca (OH)₂ in PPWC will reduce the adhesion between acid asphalt mortar and alkaline basalt aggregate. Therefore, the use of PPWC as filler in asphalt mixtures provides a reliable solution for the sustainable development of road materials.

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Using solid waste to replace limestone filler in asphalt concrete can not only reduce the cost of road construction, but also improve the utilization rate of solid waste. In this study, PHC pile waste concrete (PPWC) was innovatively used to replace limestone filler in asphalt mixture and its effect on the physical and rheological properties of asphalt mastics was studied. Firstly, PPWC was ground into filler particles with a diameter less than 0.075 mm. The physical properties, particle characteristics and chemical composition of PPWC filler and limestone filler were compared. Asphalt mastics were prepared with different filler-asphalt volume ratios (20%, 30% and 40%) and the physical properties, high-temperature rheological properties and low-temperature cracking resistance of asphalt mastics were tested. The experimental results showed that the surface of PPWC filler is rougher and has lower density and smaller particle size than limestone filler. When the filler content is the same, PPWC filler asphalt mastics have lower penetration and ductility, higher softening point than limestone filler asphalt mastics, and the viscosity of PPWC filler asphalt mastics is more sensitive than limestone filler asphalt mastics. PPWC filler asphalt mastics demonstrated superior high-temperature stability, but poorer low-temperature cracking resistance compared to limestone filler asphalt mastics. In conclusion, PPWC fillers can be used to replace limestone fillers in asphalt mixtures. The finding of this study will provide a new solution for the construction of eco-friendly roads.

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Self-healing technology, such as encapsulated rejuvenator, induction heating or combination of the above two methods, has been demonstrated to be a promising autonomic crack healing mechanism for porous asphalt. With the advantage of low cost, environmentally friendly and excellent performance, the calcium alginate capsules encapsulating rejuvenator showed promising effect to promote the crack healing in asphalt concrete. However, the healing effect of the calcium alginate capsules on the damage from fatigue loadings is still unknown, therefore became the research focus of this study. To this aim, the calcium alginate capsules were produced and incorporated into the porous asphalt (PA). A laboratory ageing process was performed on the PA to simulate the situation when asphalt pavement prone to cracking and a healing needs to take place. Afterwards, the four-point bending fatigue test (4PBF) was employed to characterize the fatigue resistance of the PA specimens. A 24-hour-rest period was carried out to allow the healing of fatigue damages. Additionally, a 4PBF testing and healing programme was carried out to evaluate the fatigue damage healing efficiency of the calcium alginate capsules healing system. It was found that the capsule healing mix showed a higher fatigue life than the reference mix, but the results were a bit scattered which might be caused by the capsule distribution which determines whether the healing takes place on the damage site or not.

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In this study, a modified alkali activated slag system is designed by introducing additional calcium and aluminum containing phases in the binder, aiming at promote the formation of Friedel's salt (Fs) within the reaction products and therefore achieve a better chloride binding capacity. The effect of calcium and alumina contents on phase composition, chloride binding behavior, pore structure and mechanical properties of alkali activated slag are investigated. The results show that the addition of Ca(OH)₂ and nano γ-Al₂O₃ (CH and NA) results in the residual CH within the reaction products, but when in present of chloride, all residual CH transformed into Fs or other phases. The chloride binding capacity of the binder is obviously enhanced by CH and NA addition, owing to the increased ability to chemically bind chloride through Fs formation. There also exists an optimum Ca/Al ratio of the starting material regarding the chloride binding capacity. Adding CH coarsen the pore structure of the hydrated matrix by increase the amount of pores with the sizes larger than 200 nm, while NA exhibits a contrary effect. The chloride chemically binding behavior, namely the formation of Fs, slightly reduced the porosity of the binder. The strength results illustrate the negative effect of CH on compressive strength, and NA presents a positive effect, the modified binding system is able to provide a comparable mechanical property when compared with the reference alkali activated mixture.

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This research aimed to explore the impact of aging on the molecular structure of asphalts from different crude oils. The elemental composition of five types of original asphalts was measured. The structure changes of the asphalts were analyzed with Fourier transform infrared spectroscopy (FTIR) and nuclear magnetic resonance (1H-NMR) before and after thin-film oven test, ultraviolet light (UV), and pressure aging vessel (PAV). The result of the elemental analysis showed that the hydrogen-carbon ratio (H/C) of asphalts ranges from 1.347 to 1.602 with different contents of sulfur, nitrogen, and oxygen. The FTIR indicated that asphalts with a low H/C had a low rate of change of carbonyl index after aging. Asphalts were more likely to produce an aromatic ring structure and sulfoxide group during the PAV aging process. The aliphatic structure was easier to reduce during the UV aging process. The 1H-NMR analysis showed that the content of aromatic hydrogen (Har) of asphalts is between 0.022 and 0.056, the content of Har decreased after aging, and the asphalt with a low Har content had a smaller change rate of hydrogen atom content. The outlined research results revealed that the asphalt with lower H/C and Har content was prone to have better aging resistance.@en

During the service period, asphalt materials are affected by various natural factors, including heat, ultraviolet light, oxygen and moisture, etc., resulting in the reduction of pavement performance, the increase of pavement distress and shortening of service life. This study aims to investigate the aging performance of asphalt under multiple aging conditions of heat, UV and aqueous solution. Thermal-oxygen aging, UV aging and hydrostatic erosion tests were carried out sequentially on asphalt. The rheological properties, chemical structure and element composition of asphalt were characterized before and after aging, and the effect mechanism of multiple conditions was discussed. The results show that the multiple conditions of heat and UV can increase the rutting resistance and weaken the cracking resistance of asphalt. However, the effect degree of UV decreases gradually with the deepening of aging degree. Additionally, the effect of water on the physicochemical properties is less than that of UV; however, water can increase the sensitivity of physicochemical properties to UV. In summary, this study explored the short-term cycling effect of heat, light and water on asphalt and provided an idea for simulation test of asphalt under multiple aging condition.

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This research aims to investigate the aging resistance of asphalts from different crude oils based on molecular structure and rheological properties. The average molecular structure of five types of asphalt from different crude oils were analyzed with the element analyzer, nuclear magnetic resonance, gel permeation chromatograph, and the improved Brown–Ladner method. The rheological properties of the asphalts were tested by the dynamic shear rheometer before and after laboratory aging. The antiaging properties of the asphalts were evaluated by the rheological aging index (RAI). The findings indicate that there were significant differences in the molecular structures among the five types of asphalt. The asphalt with the least hydrogen–carbon ratio (H/C), the largest aromatic carbon ratio (f_A), and the largest condensation index (CI) had the lowest rate of decline in rheological properties and therefore, the best antiaging performance. The H/C, f_A, and CI had good correlations with RAI, which indicated that it was feasible to use these molecular structure parameters to evaluate the differences in the aging resistance of various asphalts.

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Rejuvenator encapsulation technique showed great potential for extrinsic asphalt pavement damage healing. Once the capsules are embedded within asphalt pavement, the healing is activated on-demand via progressing microcrack. When the microcrack encounters the capsule, the fracture energy at the tip opens the capsule and releases the rejuvenator. Then the released rejuvenator wets the crack surfaces, diffuses into and softens the aged bitumen, allowing two broken edges to come in the contact, preventing further asphalt pavement deterioration. The quality and speed of the damage repair process strongly depend on the quality of rejuvenator, thus it is important to choose a proper rejuvenator with good abilities to restore the lost properties of bitumen from ageing and show a sustainable performance after healing. To this aim, three different rejuvenators were studied and ranked based on the performance of their rejuvenated bitumen, including physical properties, rheological properties, chemical properties and the performance after re-ageing. Furthermore, these rejuvenators were encapsulated in calcium alginate capsules and the tests on these capsules indicate the diameter, mechanical resistance and thermal stability of the capsules are influenced by the encapsulated rejuvenator. The findings will benefit the development of rejuvenator encapsulation technique and the optimization of the capsule healing system towards a better healing effect in asphalt pavement.

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In this paper, a method to predict the healing effect of induction heating asphalt concrete at vertical depths was proposed and verified. At first, AH-70 asphalt concrete and SBS modified asphalt concrete of AC-13 gradation were designed and prepared. R-DT (Relationship of Depth and Temperature) was quantified through induction heating test. R-HT (Relationship of Healing rate and Temperature) was quantified through fracture-healing–fracture test and X-ray micro computed tomography test with oven heating. Then, linear regression was used to verify the rationality of R-HT compared with the pre-relationship in previous studies. Finally, R-DH (Relationship of Depth and Healing rate) was predicted by fitting approach. It was found that R-DT and R-HT presented significant linearity, the existence of which was independent from the type of asphalt materials. While, more sensitive of SBS modified asphalt concrete showed that the response to gradient characteristics of R-DT was related to the higher overall temperature. Additionally, R Square-values = 0.963 of linear regression proved the oven heating method was suitable for the quantification and prediction of gradient characteristics. Furthermore, the prediction of R-DH was obtained successfully, which established the continuous distribution of the healing effect at vertical depths and revealed the linear relationship of the continuous distribution.

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