9,10-Dihydro-9-oxa-10-phosphorophenanthrene-10-oxide (DOPO), recognized for its role as an efficacious fume suppressant, has been shown to mitigate the emission of noxious vapors emanating from asphalt. However, the comprehensive influence of DOPO on the composition and properties of asphalt had remained unexplored. This study embarked on an in-depth examination of the effects of various DOPO dosages on the chemical composition of asphalt, employing hydrogen nuclear magnetic resonance spectroscopy (¹H NMR) alongside an exhaustive analysis of asphalt components. Furthermore, the investigation elucidated the consequences of different DOPO dosages on the physical, rheological properties, and aging resistance of asphalt. The results of ¹H NMR and component analysis of asphalt disclosed that DOPO engaged in chemical reactions with the unsaturated groups within the asphalt, catalyzing a metamorphosis of saturates into aromatics and resins. Such chemical transformations were instrumental in augmenting the softening point, viscosity, and rutting propensity of the asphalt while imposing a minimal impact on its penetration and ductility. Post exposure to the thin film oven test (TFOT), pressure aging vessel (PAV), and ultraviolet (UV) aging, the DOPO modified asphalt (DMA) exhibited a diminution in the increment of softening point and viscosity aging index relative to the control asphalt. Furthermore, the DMA showcased enhanced retention rates of penetration and ductility, coupled with substantially reduced shifts in complex modulus and phase angle post-aging, underlining its superior aging resistance. Fourier transform infrared spectroscopy analysis revealed a comparatively slower rate of change in carbonyl and sulfoxide groups in DMA after aging, as opposed to the control asphalt. Notably, DMA exhibited enhanced resistance to UV aging relative to TFOT and PAV aging scenarios, a trait attributable to remarkable UV absorption capabilities of DOPO. Fundamentally, DOPO enhanced the high-temperature performance and aging resistance of asphalt while simultaneously diminishing the emission of noxious fumes.

@en

Asphalt fumes released during pavement construction posed a threat to human health and environment. In this study, 9,10-dihydro-9-oxa-10-phosphorophenanthrene-10-oxide (DOPO) was used as a reactive fumes suppressant to reduce the asphalt fumes emission. The volatilization behavior of DOPO modified asphalt (DOPO-Asphalt) was investigated through thermogravimetric analysis, volatility test and thermal destruction gas chromatography mass spectrometry, and effect of DOPO on the chemical structure and composition of asphalt was explored through nuclear magnetic resonance hydrogen spectroscopy, Fourier transform infrared spectroscopy, and asphalt component testing. The results indicated that 1.0 wt% DOPO reduced the fume content of control asphalt by 1.1% from 120 ℃ − 200 ℃ and the H₂S and VOC content by 96.9% and 84.2%, respectively, at 180 ℃. Moreover, 1.0 wt% DOPO reduced the content of aliphatic hydrocarbons, hydrocarbon derivatives, aromatics, and sulfides in control asphalt fumes by 86.8%, 89.7%, 90.7%, and 93.5%, respectively, which may be attributed to electrophilic and nucleophilic reactions between DOPO and volatile substances in asphalt. Chemical structure and composition changing of DOPO-Asphalt confirmed that P-H bond in DOPO was chemically reacted with components in asphalt, generating stable aromatic hydrocarbons and resins. The results provided a novel method for inhibiting the volatilization of harmful substances in asphalt.

@en

This research aimed to explore the impact of aging on the molecular structure of asphalts from different crude oils. The elemental composition of five types of original asphalts was measured. The structure changes of the asphalts were analyzed with Fourier transform infrared spectroscopy (FTIR) and nuclear magnetic resonance (1H-NMR) before and after thin-film oven test, ultraviolet light (UV), and pressure aging vessel (PAV). The result of the elemental analysis showed that the hydrogen-carbon ratio (H/C) of asphalts ranges from 1.347 to 1.602 with different contents of sulfur, nitrogen, and oxygen. The FTIR indicated that asphalts with a low H/C had a low rate of change of carbonyl index after aging. Asphalts were more likely to produce an aromatic ring structure and sulfoxide group during the PAV aging process. The aliphatic structure was easier to reduce during the UV aging process. The 1H-NMR analysis showed that the content of aromatic hydrogen (Har) of asphalts is between 0.022 and 0.056, the content of Har decreased after aging, and the asphalt with a low Har content had a smaller change rate of hydrogen atom content. The outlined research results revealed that the asphalt with lower H/C and Har content was prone to have better aging resistance.@en

This research aims to investigate the aging resistance of asphalts from different crude oils based on molecular structure and rheological properties. The average molecular structure of five types of asphalt from different crude oils were analyzed with the element analyzer, nuclear magnetic resonance, gel permeation chromatograph, and the improved Brown–Ladner method. The rheological properties of the asphalts were tested by the dynamic shear rheometer before and after laboratory aging. The antiaging properties of the asphalts were evaluated by the rheological aging index (RAI). The findings indicate that there were significant differences in the molecular structures among the five types of asphalt. The asphalt with the least hydrogen–carbon ratio (H/C), the largest aromatic carbon ratio (f_A), and the largest condensation index (CI) had the lowest rate of decline in rheological properties and therefore, the best antiaging performance. The H/C, f_A, and CI had good correlations with RAI, which indicated that it was feasible to use these molecular structure parameters to evaluate the differences in the aging resistance of various asphalts.

@en