Nitrate concentrations exceed standards in many drinking water sources. Solid carbon source (SCS) is usually used to increase the biological denitrification in waters with a low carbon‑nitrogen ratio. However, there is a lack of research on the enhanced denitrification in drinking water sources with nitrate exceeding limits by the introduction of SCS. In this study, a SCS composite was prepared using agricultural waste corncob and polybutylene succinate and the SCS carbon release performance, denitrification effect and potential chemical and biological risks were investigated via a series of batch and column experiments. The SCS composite presented a long-term, stable carbon release performance and good microbial utilization capability for denitrification: SCS composite has a sustained release capacity for over 28 days in dynamic waters. Short-chain fatty acids accounted for over 60 % of the released carbon, and predominant fluorescence compounds were protein organic compounds and soluble microbial metabolites. The introduction of SCS composite evidently improved bio-rope biomass and its denitrification effect. The removal percentage of NO₃⁻ by SCS reactor pretreatment reached 90.9 %, remaining stable within 28 days. The SCS pretreatment increased formation potentials of trihalomethanes, but formation potentials of haloacetonitriles with higher toxicity were effectively reduced, so the comprehensive toxicity risk of disinfection by-products was reduced. The SCS pretreatment has slight negative impact on drinking water biological stability only during the first 10 days, which needs attention. This study demonstrated that the prepared SCS composite has excellent carbon release performance and denitrification effect, and its chemical and biological risks were controllable.

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Information on crop yield is important for food security, in particular under the conditions of climate change and growing population worldwide. We developed a new fully distributed, high spatial resolution, model of biomass accumulation and crop yield applicable to a highly heterogeneous desert-oasis agroecosystem. The bulk of required input data is obtained by retrieving pixel-wise biogeophysical variables from a suite of very diverse satellite data. Both temperature and water stress conditions at field-scale are given full consideration, while the model was designed to strike a balance between model applicability and satisfactory characterization of the heterogeneous desert-oasis system to estimate field-scale yield. The development of this model relies on three main innovations. First, the start and end of the growing season were estimated for each pixel by calibrating the high spatial and temporal resolution observations of Normalized Difference Vegetation Index (NDVI) by Sentinal-2 (S2) MSI (Multi-Spectral Instrument) against limited local phenological information. Second, to monitor crop water stress, account taken of irrigation, a process-based water and energy balance model was applied to estimate the actual evapotranspiration (ET). This requires knowledge of soil water availability, which is characterized by downscaling the ASCAT (Advanced SCATterrometer) soil moisture data product. To capture the dominant features of the eco-hydrological conditions in the desert and oasis agroecosystem, ET was further downscaled from the 1 km resolution. Third, likewise the water stress indicator, the air temperature stress indicator was mapped after characterizing the thermal contrast and heterogeneity of the desert-oasis system, by generating time series of air temperature at 1 km spatial resolution using the MODIS (Moderate Resolution Imaging Spectroradiometer) Land Surface Temperature (LST) data product. In the temporal dimension, gaps were mitigated by applying time series analysis techniques to reconstruct cloud-free time series of LST, NDVI, fAPAR and albedo. These innovations add up to a high resolution characterization of crop response to the geospatial variability of weather and climate forcing in the desert-oasis agroecosystem. The model was applied to the dominant crops, i.e., spring wheat, maize, sunflower, and melon, in the oases of the Shiyang River Basin (northwestern China) characterized by a rather fragmented land use. The high resolution of pixel-wise ecohydrological parameters, i.e., crop phenology, temperature stress and water stress factors successfully reflect differences of crops with different phenology and location in the oases. The relative errors for wheat and maize yields compared to the census data are less than 5% at district level. At the county level, the relative errors of wheat yields of Liangzhou, Minqin, Gulang, Jinchuan, and Yongchang equal to 0.87%, 24.2%, 9.7%, 12.5%, and 7.2%. For maize, the dominant crop, the error on estimated yields was less than 5%, except in Gulang. The relative error on estimated yield for sunflower was less than 10% compared to agricultural census data. The relative error on estimated melon yield was 16%. This performance highlights the applicability of the model to estimate field-scale yields in agroecosystems characterized by fragmented land use.

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Land Use/Land Cover (LULC) change is a major global concern and a topic of scientific debate. In West Africa, the key trend among the changes of the past few years is the loss of natural vegetation related to changes in different LULC categories, e.g., water bodies, wetland, and bare soil. However, not all detected changes in these LULC categories are relevant for LULC change management intervention in a resource-constrained continent, as a massive change in the dominant LULC types may be due to errors in the LULC maps. Previous LULC change analysis detected large discrepancies in the existing LULC maps in Africa. Here, we applied an open and synergistic framework to update and improve the existing LULC maps for West Africa at five-year intervals from 1990 to 2020—updating them to a finer spatial resolution of 30 m. Next, we detected spatial–temporal patterns in past and present LULC changes with the intensity analysis framework, focusing on the following periods: 1990–2000, 2000–2010, and 2010–2020. A faster annual rate of overall transition was detected in 1990–2000 and 2010–2020 than in 2000–2010. We observed consistent increases in shrubland and grassland in all of the periods, which confirms the observed re-greening of rangeland in West Africa. By contrast, forestland areas experienced consistent decreases over the entire period, indicating deforestation and degradation. We observed a net loss for cropland in the drought period and net gains in the subsequent periods. The settlement category also gained actively in all periods. Net losses of wetland and bare land categories were also observed in all of the periods. We observed net gains in water bodies in the 1990–2000 period and net losses in the 2010–2020 period. We highlighted the active forestland losses as systematic and issued a clarion call for an intervention. The simultaneous active gross loss and gain intensity of cropland raises food security concerns and should act as an early warning sign to policy makers that the food security of marginal geographic locations is under threat, despite the massive expansion of cropland observed in this study area. Instead of focusing on the dynamics of all the LULC categories that may be irrelevant, the intensity analysis framework was vital in identifying the settlement category relevant for LULC change management intervention in West Africa, as well as a cost-effective LULC change management approach.

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Biological activated carbon (BAC) filtration is usually considered to be able to decrease formation potentials (FPs) of disinfection by-products (DBPs) in drinking water treatment plant (DWTP). However, BAC filters with long running time may release microbial metabolites to effluents and therefore increase FPs of nitrogenous DBPs with high toxicity. To verify this hypothesis, this study continuously tracked BAC filters in a DWTP for one year, and assessed effects of old (running time 8–9 years) and new (running time 0–13 months) BAC filters on FPs of 15 regulated and unregulated DBPs. Results revealed that dissolved organic carbon (DOC) removal was slightly higher in the new BAC than the old one. All fluorescent components of dissolved organic matter evidently declined after new BAC filtration, but fulvic acid-like and soluble microbial product-like substances increased after old BAC filtration, which could be caused by microbial leakage. Correspondingly, new BAC filter generally removed more DBP FPs than the old one. 46.5% HAA7 FPs from chlorination and 44.3% THM4 FPs from chloramination were removed by new BAC filter. However, some DBP FPs, especially HAN FPs, were poorly removed or even increased by the old BAC filter. Proteobacteria could be a main contributor for DBP precursor removal in BAC filters. Herminiimonas, most abundant genera in new BAC filter, may explain its better DOC and UV254 removal performance and lower DBP FPs, while Bradyrhizobium, most abundant genera in old BAC filter, might produce more extracellular polymeric substances and therefore increased N-DBP FPs in old BAC effluent. This study provided insight into variations of DBP FPs and microbial communities in the new and old BAC filters, and will be helpful for the optimization of DWTP design and operation for public health.@en

A drought-induced water storage deficit index (D-WSDI) is proposed to quantify the response of GRACE-based terrestrial water storage change to meteorological drought and the impact of drought on water storage deficit. D-WSDI is defined as the normalized residual component of GRACE time-series data after removing the long-term trend and seasonal components. The evaluation based on the Emergency Events Database (EM-DAT) showed that more than 90% of global drought events from 2002 to 2019 led to a water storage deficit, which can be detected by the proposed D-WSDI. The severity of the water storage deficit caused by drought increases with the extending drought duration. An average of 73% of water storage deficit months at the global scale is related to precipitation shortages. The cumulative precipitation deficit in relatively short periods of less than 9 months can lead to the water storage deficit in low-latitude regions, whereas a longer time scale is required to lead to a water storage deficit in high-latitude regions. The negative monthly precipitation anomaly of about -20% can lead to a water storage deficit in high rainfall regions, whereas the negative precipitation anomaly can reach -80% in arid and semiarid areas. D-WSDI holds the capability to quantify the water storage deficit caused by drought, especially in the regions with terrestrial water storage change influenced by the long-term trends in climate and anthropogenic activities, and can be used as an index of drought monitoring with similar or superior performance compared to some traditional drought indices.

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Past Land Use Land Cover (LULC) transitions analysis at the sub-continental scale of West Africa revealed spatial reallocation, i.e., simultaneous losses and gains of the LULC categories at different locations. We applied the component analysis approach to separate the total change into three major components, i.e., quantity (net change), exchange and shift (allocation change) as a way to analyse such spatial reallocation and identify the paired categories that accounted for the largest exchange and shift through time. Quantity change is the absolute value of the category's gross gains minus the category's gross losses. An exchange occurs when for example, a natural vegetation patch evolves to cropland at a location concurrently with an equal extent of cropland evolving into natural vegetation at a different location. A shift occurs when the LULC categories involved in the exchange are more than two. The amount of exchange and shift and locations that these exchanges occurred are very useful information for land policies appraisal and the long term contested re-greening of Africa as it may signal simultaneous regrowth and degradation of natural vegetation at different locations in the same landscape and also possible misclassification errors. The results revealed large exchanges in the landscape of West Africa between 1975 and 2000 for arid and humid eco-regions in West Africa. Overall, the exchange and shift components between wetland, water bodies and some other LULC categories such as forestland, other vegetation and cropland were the highest. The exchange between natural vegetation and cropland was considerable, which confirms regrowth despite the massive degradation revealed by the previous studies. Here, the large exchange in 1975–2000 highlighted large spatial reallocation of the LULC categories. The highest net change was experienced in the period between 2000 and 2013 at all spatial aggregations. Settlement and cropland experienced the highest positive net change whilst forestland and other vegetation experienced the highest negative net change. Shift was absent in the category of settlements indicating persistence over time. This analysis provided useful information on the contested re-greening of West Africa.

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Glacier and snow are sensitive indicators of regional climate variability. In the early 21st century, glaciers in the West Kunlun and Pamir regions showed stable or even slightly positive mass budgets, and this is anomalous in a worldwide context of glacier recession. We studied the evolution of snow cover to understand whether it could explain the evolution of glacier area. In this study, we used the thresholding of the NDSI (Normalized Difference Snow Index) retrieved with MODIS data to extract annual glacier area and snow cover. We evaluated how the glacier trends related to snow cover area in five subregions in the Tarim Basin. The uncertainty in our retrievals was assessed by comparing MODIS results with the Landsat-5 TM in 2000 and Landsat-8 OLI in 2020 glacier delineation in five subregions. The glacier area in the Tarim Basin decreased by 1.32%/a during 2000–2020. The fastest reductions were in the East Tien Shan region, while the slowest relative reduction rate was observed in the West Tien Shan and Pamir, i.e., 0.69%/a and 1.08%/a, respectively, during 2000–2020. The relative glacier stability in Pamir may be related to the westerlies weather system, which dominates climate in this region. We studied the temporal variability of snow cover on different temporal scales. The analysis of the monthly snow cover showed that permanent snow can be reliably delineated in the months from July to September. During the summer months, the sequence of multiple snowfall and snowmelt events leads to intermittent snow cover, which was the key feature applied to discriminate snow and glacier.

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