The elastic modulus of corrosion product (E_cp) has been reported with significant variations in the literature. This study aims to investigate the E_cp of naturally-generated chloride-induced corrosion products formed in different concrete mixes. Microstructural characterization was conducted through nano-indentation, electron microscopy and Raman spectroscopy. The corrosion products were mainly composed of a goethite matrix with portions of maghemite, independently of the concrete composition. Microscopic analysis suggest that layers of corrosion products grow at different times and under different physico-chemical conditions. Our measurements showed that E_cp varied between 80−100 GPa, which can be suggested for numerical models of corrosion induced cracking.

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The Service life evaluation of reinforced concrete structures is usually limited to initiation of corrosion, whilst in practice corrosion in many structures has already reached the propagation stage. To better understand the processes that lead to the cracking and detachment of concrete cover during this phase, knowledge of corrosion products’ development over time is required. This paper investigates corrosion products found in blast furnace slag cement concrete, in which natural carbonation acted upon original chloride-induced corrosion. The sample was cast in 1998, after curing subjected to wet-dry cycles to enhance chloride penetration, and later was exposed to unsheltered outdoor conditions. Corrosion products and textures at the concrete-steel interface and late carbonate veinlets within them have been characterized by a combination of optical microscopy, SEM, Raman spectroscopy and CT scanning.

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Although reinforcement corrosion is a well-known issue, which are the locations of the steel/concrete interface most sensitive to pitting corrosion is still an unclear issue. In this study, X-ray computed tomography is used to characterize eight 20-years-old reinforced concrete cores naturally deteriorated due to chloride-induced corrosion. The deepest and most frequent corrosion pits were observed at the portion of the reinforcement oriented to the outdoor environment and in proximity to interfacial air voids. Therefore, the presence of interfacial air voids should be considered as a relevant factor when assessing the risk of corrosion of reinforced concrete structures.

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The steel–concrete interface (SCI) is known to influence corrosion of steel in concrete. However, due to the numerous factors affecting the SCI—including steel properties, concrete properties, execution, and exposure conditions—it remains unclear which factors have the most dominant impact on the susceptibility of reinforced concrete to corrosion. In this literature review, prepared by members of RILEM technical committee 262-SCI, an attempt is made to elucidate the effect of numerous SCI characteristics on chloride-induced corrosion initiation of steel in concrete. We use a method to quantify and normalize the effect of individual SCI characteristics based on different literature results, which allows comparing them in a comprehensive context. It is found that the different SCI characteristics have received highly unbalanced research attention. Parameters such as w/b ratio and cement type have been studied most extensively. Interestingly, however, literature consistently indicates that those parameters have merely a moderate effect on the corrosion susceptibility of steel in concrete. Considerably more pronounced effects were identified for (1) steel properties, including metallurgy, presence of mill scale or rust layers, and surface roughness, and (2) the moisture state. Unfortunately, however, these aspects have received comparatively little research attention. Due to their apparently strong influence, future corrosion studies as well as developments towards predicting corrosion initiation in concrete would benefit from considering those aspects. Particularly the working mechanisms related to the moisture conditions in microscopic and macroscopic voids at the SCI is complex and presents major opportunities for further research in corrosion of steel in concrete.@en

Although corrosion of reinforcement is a well-known issue for the construction industry, there are still open questions about some fundamentals of corrosion in reinforced concrete. These points include, among others, which are the most sensitive locations of the steel/concrete interface for pitting corrosion to initiate and to propagate. In this study, X-ray computed tomography (CT-scan) is used to characterize eight 20-years-old reinforced concrete cores naturally deteriorated due to chloride-induced corrosion. The volume loss due to corrosion of the reinforcement was quantified through image analysis of CT-scans. The volume loss of the steel was found to be higher for steel rebars embedded in Portland cement specimens rather than in blended cement specimens. Furthermore, CT-scans revealed that the deepest and most frequent corrosion pits, as well as the consequent highest volume loss of steel, were present at the portion of the reinforcement closer to the outdoor environment and in proximity to air voids at the steel/concrete interface. As a consequence, the highest decrease of structural performance of the rebars would be likely localized at those locations. Therefore, the presence of interfacial air voids should be considered as relevant factor when assessing the risk of corrosion of reinforced concrete structures.

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This paper presents developments over 30 years in the field of cathodic protection of steel reinforcement in concrete in The Netherlands and elsewhere. From the late 1980s major developments have been: application to large numbers of precast elements corroding due to mixed-in chloride with drilled in titanium anodes and conductive coatings; analysis of working life of systems and components and end-of-life considerations; application to prestressed structures; new anode types including galvanic systems with associated life and design considerations; numerical modelling and preventative applications. Presently, CP has become a fully accepted method of securing safety and serviceability of buildings and infrastructure. Major successes and lessons learned will be presented. Technical and non-technical developments are highlighted and some recent innovative CP systems are discussed.

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This paper presents an overview of 30 years' experience with cathodic protection of steel in concrete in The Netherlands. Principles and practical aspects of CP and its design and installation are presented. Three phases have passed from the late 1980s until present: pioneering, development and maturity. In the first period CP was mainly applied to precast elements corroding due to mixedin chlorides. The parties involved worked together to draw up a Technical Guideline. In the second period, application to bridges came up, including post-tensioned structures, which was then innovative. Furthermore, galvanic anode systems were introduced. In the third period, CP became a fully accepted method of securing durability and safety. Renewed collaboration led to a database that allowed analysis of various aspects of CP system working life, including shortcomings in early systems. Major successes and lessons learned will be presented. Technical and non-technical developments are highlighted and some recent innovative CP components and systems are discussed.

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Electrochemical lithium migration has been suggested as repair technique for alkali-silica reaction affected concrete structure. In this method, an electric field is used to transport lithium into the material. Current studies have used anolyte solutions with various lithium salts at different concentrations. However, little has been said on the effect of the anolyte on lithium migration. In this paper, an experimental study on the influence of the type of lithium compound and its concentration in the anolyte is presented. Results point out that the concentration of the solution, rather than the type of lithium salt, affected migration. The anolytes with the highest concentrations provided the highest final levels of lithium in the specimens.@en

Asset managers would benefit from knowing when to expect corrosion initiation in a particular reinforced concrete structure. However, accepted approaches to test existing structures for the remaining time to corrosion initiation are lacking. This paper proposes such an approach, based on experience in the field and additional considerations. From say 20 years age, existing structures embody the concrete’s response to actual environmental loads, e.g. in chloride profiles. Based on measuring the actual cover depth, taking (at least six) chloride profiles, some assumed parameters and a simple model, the expected time to corrosion initiation for a particular test area can be predicted. Sampling frequencies are given. Uncertainties can be taken into account by applying a safety margin to the cover depth. Results of at least six tests are classified and suggestions for interpretation are given. Because the accuracy is limited, the results are classified in three broad ranges: 5 years or less, 5 to 15 years, or more than 15 years. The procedure is applied to a field case and results are discussed.@en

De commissie verwacht dat bij een correct gebruik dehiervoor beschreven procedure zijn waarde in de praktijk zal bewijzen. Enerzijds omdat de beste elementen van de huidige stand van techniek zijn gebruikt, anderzijds omdat de resultaten van onderzoek en inspecties (die leiden tot de bepaling van de ondergrens van de verwachte restlevensduur), onderling vergelijkbaar zijn. De procedure c.q. de hierin opgenomen bepalingsmethoden dienen met enige regelmaat verder te worden ontwikkeld op basis van de ervaring, opgedaan in de praktijk. Dit maakt het registreren van gegevens van de betonconstructie, te beginnen bij de oplevering, gedurende de gebruiksfase uiterst zinvol.@en

A descriptive strategy for concrete durability is utilised in the current version of concrete standard EN 206, whereby proof of durability is furnished through compliance with the limit values of the provisions regulating concrete properties and concrete composition. However, these do not sufficiently take the action of each type of cement or of the concrete additive into consideration. Furthers developments of the future EN 206 European concrete standard are envisaged with, amongst other things, the application of performance strategies for concrete, in which these as well as the development of actions and resistances over time are better taken into account. With these matters, the resistance of concrete against chloride penetration is one of the most important properties of concrete with great relevance for durability.@en

Betonconstructies verouderen en hebben daarmee steeds meer last van wapeningscorrosie en betonschade. Kathodische bescherming is een oude bekende: sinds eind jaren ’80 zijn meer dan 300 constructies in infra en utiliteitsbouw beschermd. De corrosie en de verdere ontwikkeling van schade stoppen. Door de relatief gunstige markt is ruimte ontstaan voor nieuwe ontwikkelingen, zowel technisch als op het vlak van kennis en kunde bij steeds meer betrokken mensen en bedrijven. Een studiemiddag.van het KB-kenniscentrum op 31 mei geeft een overzicht.@en

In the Netherlands civil engineering structures, such as overpasses, bridges and tunnels are generally built using blast furnace slag cement (BFSC, CEM III/B) concrete, because of its high resistance against chloride penetration. Although the Dutch experience regarding durability performance of BFSC concrete has been remarkably good, its resistance to carbonation is known to be sensitive, especially when the used slag percentage is high. In a field investigation on a highway overpass damage was found in sheltered elements such as abutments and intermediate supports, which was attributed to chloride induced corrosion enhanced by carbonation that occurred prior to the chloride exposure. Many structures built using BFSC could be prone to this mechanism, i.e. carbonation enhanced chloride induced corrosion, negatively affecting their durability. Focus of the research was given on the influence of carbonation on the chloride penetration resistance of BFSC mortars with varying slag content. In light of the characteristics from the overpass case, it was assumed that first there is a period of carbonation during sheltered exposure, and subsequently joint leakage causes exposure to chlorides. In order to identify the influence of slag content on carbonation, chloride penetration resistance and their coupled effect, mortars with twelve cement blends in a range of 0–70% slag were evaluated based on chloride migration coefficient, accelerated carbonation and electrical resistivity. This study shows that carbonation of BFSC mortars increases the porosity, consequently decreasing the chloride penetration resistance. Binders with 50% or more slag were found to have a significantly lower resistance after carbonation. Consequently, the chloride penetration resistance of a given concrete cover strongly depends on the duration of carbonation and the resulting carbonation depth, hence influencing its lifespan. The service life was estimated using a simplified model for the chloride penetration time of a combined carbonated and uncarbonated layer. It was found that mortar with a slag content between 35 and 50% that was carbonated before chloride exposure show the lowest influence of carbonation on the chloride penetration resistance.@en

Owners of concrete structures would benefit from knowing when to expect corrosion initiation in a particular structure. Presently, no accepted procedures for testing existing structures for the remaining time to corrosion initiation are available. This paper proposes such a procedure, based on our experience and additional considerations. From about 20 years age, existing structures contain the concrete’s response to actual environmental loads, e.g. chloride ingress profiles. By measuring the actual cover depth, taking chloride profiles, assuming a few parameters and a simple model, the expected time to corrosion initiation for a particular test area can be predicted. Numbers of cores and samples per core are given. Uncertainties can be taken into account by applying a calculatory reduction of the cover depth. Results of at least six cores per test area are classified and suggested interpretations are given. Because of large variability, the results are classified in three ranges of time to corrosion initiation: five years or less, five to fifteen years, or more than 15 years. The procedure has been approved by the relevant national Standards committees and is issued early 2018. It was applied to a field case and the obtained results are discussed. @en

Testing for the chloride threshold (also called critical chloride content) for corrosion initiation of steel in concrete has been found difficult and, at best, time consuming. Nevertheless, the chloride threshold is an important parameter in service life design of new structures and for evaluation of the remaining service life of existing structures. This paper reports on an accelerated test on mortar specimens that produces results within one week to a few weeks. It is based on accelerating chloride penetration by a mild electrical field while the steel potential is monitored. Upon corrosion initiation, specimens are sampled to obtain the chloride content that initiates corrosion. Results are reported of testing in CEM I (OPC) mortar on multiple specimens. Results for reference mortar are compared to specimens with application of a hydrophobic surface treatment. The results show that in reference CEM I mortar values for the critical threshold were obtained that agree well with previous experiments using the same method. This is taken as a validation of the method. The method is thought to be suitable for comparative chloride threshold studies of different binders, without or with corrosion inhibiting additions. Results for mortar with surface applied hydrophobic treatment, however, are unexpectedly low, which is taken to suggest that the method is not suitable for (e.g. surface treated) material with inhomogeneous electrolytic conduction.@en

Although the steel–concrete interface (SCI) is widely recognized to influence the durability of reinforced concrete, a systematic overview and detailed documentation of the various aspects of the SCI are lacking. In this paper, we compiled a comprehensive list of possible local characteristics at the SCI and reviewed available information regarding their properties as well as their occurrence in engineering structures and in the laboratory. Given the complexity of the SCI, we suggested a systematic approach to describe it in terms of local characteristics and their physical and chemical properties. It was found that the SCI exhibits significant spatial inhomogeneity along and around as well as perpendicular to the reinforcing steel. The SCI can differ strongly between different engineering structures and also between different members within a structure; particular differences are expected between structures built before and after the 1970/1980s. A single SCI representing all on-site conditions does not exist. Additionally, SCIs in common laboratory-made specimens exhibit significant differences compared to engineering structures. Thus, results from laboratory studies and from practical experience should be applied to engineering structures with caution. Finally, recommendations for further research are made.

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Alkali–silica reaction (ASR) affects numerous concrete structures worldwide. However, the intervention options for ASR in existing structures are limited. Lithium is proposed to suppress expansion. In this paper, an investigation on two-chamber lithium migration as treatment against ASR is presented. First, the influence of different levels of ASR development on lithium migration is studied. Results show that ASR development, if not followed by enough crack formation, hinders migration due to increase in resistivity. Second, the effects of different treatments, such as sodium and potassium removal, lithium migration (combined with the associated sodium and potassium removal) and lithium diffusion, on ASR expansion were evaluated. Lithium migration led to the lowest post-treatment expansion levels.

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The currently available treatment techniques for concrete structures affected by alkali-silica reaction (ASR) are limited and electrochemical lithium migration has been proposed as an alternative. Lithium compounds have shown to have beneficial effects on ASR expansion when used as admixtures to fresh concrete. During the electrochemical treatment, lithium ions area transported into concrete (or mortar) by the action of an electrical field. The same principle is behind well-established techniques such as electrochemical chloride extraction (ECE). Like during ECE treatments, the reinforcement may be used as cathode during electrochemical lithium migration. In this paper, an investigation of the use of an embedded cathode during electrochemical lithium migration is presented. Mortar specimens were cast with embedded titanium meshes, which worked as cathodes. Results showed that potassium and sodium ions accumulated in the region around the embedded mesh and, under the tested conditions, few lithium ions reached that area. The accumulation of sodium and potassium is an undesirable side effect that increases the pH, which may possibly induce further ASR development, if not enough lithium ions reach the area.@en

Two modified Mg-Al hydrotalcites (MHTs), (MHT-pAB and MHT-NO₂) were incorporated into mortar (with different w/c ratios) in two different ways: (1) as one of the mixing components in bulk mortar; (2) as part of cement paste coating of the reinforcing steel. Accelerated chloride migration, cyclic wetting-drying and diffusion tests were performed to investigate their effect on reinforcement corrosion. The results indicated that MHTs could be promising alternatives for preventing chloride-induced corrosion when an appropriate dosage is adopted and applied in a proper way, particularly, replacing 5% mass of cement by MHT-pAB in bulk mortar or as a coating of reinforcing steel (MHT-pAB/MHT-NO₂ to replace 20% mass of cement). The effect of MHT-pAB on time-to-corrosion initiation (TTC) of reinforcing steel was estimated using the DuraCrete model. It was found that the incorporation of 5% MHT-pAB in bulk mortar led to a more than double TTC relative to reference mortar without MHTs.

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