Hydrogen carriers are attractive alternative fuels for the shipping sectors. They are zero-emission, have high energy densities, and are safe, available, and easy to handle. Sodium borohydride, potassium borohydride, dibenzyltoluene, n-ethylcarbazole, and ammoniaborane are interesting hydrogen carriers, with high theoretical energy densities. The exact energy density of these hydrogen carriers depends on the integration of heat and mass with the energy converters. This combination defines the energy efficiency and, thus, the energy density of the system. Using a 0D model, we combined the five carriers with two types of fuel cells (PEM and SOFC), an internal combustion engine and a gas turbine. This resulted in 20 combinations. Despite the limitations of the 0D model and the occasional difficulty of validating input values, this model still produces exciting findings, which are valuable for further research. For the dehydrogenation of both dibenzyltoluene and n-ethylcarbazole, an external hydrogen burner is required if no waste heat resources from the integrated system are available. For the borohydrides, on the other hand, energy integration is essential for reducing cooling power. Dehydrogenation produces substantial energy, but only a fraction of this energy can be used for internal preheating. Dehydrogenation of ammoniaborane produces less energy. Among all hydrogen carriers, both ammoniaborane and sodium borohydride provide energy densities comparable to that of marine diesel oil. In particular, ammoniaborane possesses a remarkably high energy density. Thus, we conclude, that hydrogen carriers are attractive alternative fuels that deserve more attention, including their potential performance for hydrogen imports. @en

Reducing the use of fossil fuels in shipping requires new, alternative maritime fuels. Hydrogen carriers offer a safe and energy-dense solution for storing hydrogen, a zero-emission alternative fuel. This research focuses on ammonia borane, NaBH4, n-ethylcarbazole and dibenzyltoluene. Applying hydrogen carriers influences ship design significantly, as they require additional specialised equipment to remove hydrogen from the hydrogen carrier. This research estimates the size of the equipment. As this equipment will need to be stored and maintained on the ship, the exact sizing and sequence of the additional equipment will likely influence ship design. Results show that the reactor size is significant for all hydrogen carriers. The mixing tank is considerably sized for NaBH4 and ammonia borane, while the heat exchangers are large for dibenzyltoluene and n-ethylcarbazole.@en

The marine industry must reduce emissions to comply with recent and future regulations. Solid oxide fuel cells (SOFCs) are seen as a promising option for efficient power generation on ships with reduced emissions. However, it is unclear how the devices can be integrated and how this affects the operation of the ship economically and environmentally. This paper reviews studies that consider SOFC for marine applications. First, this article discusses noteworthy developments in SOFC systems, including power plant options and fuel possibilities. Next, it presents the design drivers for a marine power plant and explores how an SOFC system performs. Hereafter, the possibilities for integrating the SOFC system with the ship are examined, also considering economic and environmental impact. The review shows unexplored potential to successfully integrate SOFC with thermal and electrical systems in marine vessels. Additionally, it is identified that there are still possibilities to improve marine SOFC systems, for which a holistic approach is needed for design at cell, stack, module, and system level. Nevertheless, it is expected that hybridisation is needed for a technically and economically feasible ship. Despite its high cost, SOFC systems could significantly reduce GHG, NOX, SOX, PM, and noise emissions in shipping.@en

The availability of supporting bunker infrastructure for zero-emission energy sources will be key to accommodate zero-emission inland waterway transport (IWT). However, it remains unclear which (mix of) zero-emission energy sources to prepare for, and how to plan the bunker infrastructure in relative positions and required capacity at corridor scale. To provide insight into the positioning and dimensions of bunkering infrastructure we propose a bottom-up energy consumption method combined with agent based network simulation. In the method, we first produce a two-way traffic energy consumption map, aggregated from the energy footprint of individual vessels on the transport network. Next we investigate the potential sailing range of the vessels on the network if they would sail the same routes, but with alternative energy carriers. Based on the sailing range of the vessels for different energy carriers, the maximum inter-distance between refuelling points can be estimated. By aggregating the energy consumptions of all the vessels on the network, we can estimate the required capacity of a given refuelling point. To demonstrate the basic functionality we implement the method to four representative corridor scale inland shipping examples using zero-emission energy sources including hydrogen, batteries, e-NH3, e-methanol and e-LNG. The application in this paper is limited to four abstract cases. A recommended next step is to apply this approach to a more realistic network.@en

An increasing demand in the marine industry to reduce emissions led to investigations into more efficient power conversion using fuels with sustainable production pathways. Solid Oxide Fuel Cells (SOFCs) are under consideration for long-range shipping, because of its high efficiency, low pollutant emissions, and fuel flexibility. SOFC systems also have great potential to cater for the heat demand in ships, but the heat integration is not often considered when assessing its feasibility. This study evaluates the electrical and heat efficiency of a 100 kW SOFC system for marine applications fuelled with methane, methanol, diesel, ammonia, or hydrogen. In addition, cathode off-gas recirculation (COGR) is investigated to tackle low oxygen utilisation and thus improve heat regeneration. The software Cycle Tempo is used to simulate the power plant, which uses a 1D model for the SOFCs. At nominal conditions, the highest net electrical efficiency (LHV) was found for methane (58.1%), followed by diesel (57.6%), and ammonia (55.1%). The highest heat efficiency was found for ammonia (27.4%), followed by hydrogen (25.6%). COGR resulted in similar electrical efficiencies, but increased the heat efficiency by 11.9% to 105.0% for the different fuels. The model was verified with a sensitivity analysis and validated by comparison with similar studies. It is concluded that COGR is a promising method to increase the heat efficiency of marine SOFC systems.

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Solid Oxide Fuel Cell (SOFC) systems have the potential to reduce emissions from seagoing vessels. However, it is unknown whether ship motions influence the system's operation. In this research, a 1.5 kW SOFC module is operated on an inclination platform that emulates ship motions, to evaluate the influence of static and dynamic inclinations on the system's safety, operation, and lifetime. The test campaign consists of a static inclination test, a dynamic test, a degradation test, and a high acceleration test. There were no interruptions in the power supply during the different tests, and no detectable gas leakages or safety hazards. Although the SOFC does not fail in any test condition, dynamic inclinations result in forced oscillations in the fuel regulation, which propagate through the system by different feedback loops in the control architecture, leading to significant deviations in the operational parameters of the system. Additionally, for motion periods from 16 to 26 s, reoccurring exceedance of the fuel utilisation results in a gradual reduction of the power supply. Several enhancements are recommended to improve the design of SOFCs and marine fuel cell regulations to ensure their safe operation on ships.

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Green hydrogen combined with PEM fuel cell systems is a viable option to meet the demand for alternative maritime fuels. However, hydrogen storage faces challenges, including low volumetric density, fire and explosion risks and transport challenges. We assessed over fifteen hydrogen carriers based on their maritime performance characteristics to determine their suitability for shipboard use. Evaluation criteria included energy density, locally zero-emission, circularity of process, safety, dehydrogenation process, logistic availability and handling. Thus, excluding ammonia and methanol because of these constraints, we found that borohydrides, liquid organic hydrogen carriers and ammoniaborane are the most promising hydrogen carriers to use on ships with PEM fuel cells. Borohydrides, specifically sodium borohydride, have high energy densities but face regeneration issues. The liquid organic hydrogen carrier dibenzyltoluene has a lower energy density but exhibits easy hydrogenation and good handling. Given varying operational demands, we developed a framework to assess the suitability of hydrogen carriers for use in different ship categories. Evaluating the three types of hydrogen carriers, using our framework and considering current practices, shows that these are viable options for almost all ship types. Thus, we have identified three types of hydrogen carriers, which should be the focus of future research.

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It is essential to use alternative fuels if we are to reach the emission reduction targets set by the IMO. Hydrogen carriers are classified as zero-emission, while having a higher energy density (including packing factor) than pure hydrogen. They are often considered as safe alternative fuels. The exact definition of what safety entails is often lacking, both for hydrogen carriers as well as for ship safety. The aim of this study is to review the safety of hydrogen carriers from two perspectives, investigating potential connections between the chemical and maritime approaches to safety. This enables a reasoned consideration between safety aspects and other design drivers in ship design and operation. The hydrogen carriers AB, NaBH4, KBH4 and two LOHCs (NEC and DBT) are taken into consideration, together with a couple reference fuels (ammonia, methanol and MDO). After the evaluation of chemical properties related to safety and the scope of the current IMO safety framework, it can be concluded that safety remains a vague and non-explicit concept from both perspectives. Therefore, further research is required to prove the safe application of hydrogen carriers onboard ships.@en

Marine actors are showing an increased interest in the application of Solid Oxide Fuel Cells (SOFCs) for deep sea shipping, because of their high conversion efficiency, low pollutant emissions, and fuel flexibility. However, it is unknown how the operation of SOFC systems is affected by large inclinations and motions, which can be present in ships for instance by seawaves. The goal of this research is to evaluate the influence of static and dynamic inclinations on the operation and safety of SOFC systems. Ship motions are emulated using a one-axial oscillation platform up to 30 degrees of inclination. The SOFC system was successfully operated on the platform and demonstrated stable power production under a variety of test conditions without any noticeable safety hazards. The results of the experiments are used to propose design improvements for marine SOFC systems, ultimately contributing to reduce the emissions of the shipping industry.@en

Analysis of ship propulsion system performance is often performed using detailed hydrodynamic models to assess load changes, which are subsequently compared to static engine limits, or by detailed engine models that are rarely integrated with sufficiently detailed propulsion models for load change estimation. To investigate the dynamic engine (overloading) behaviour and ship propulsion performance under various heavy operating conditions, a Mean Value First Principle Parametric (MVFPP) engine model is integrated into a ship propulsion system model in this paper. An upgraded thermodynamic-based MVFPP model for two-stroke marine diesel engines is presented, in particular a newly developed MVFPP gas exchange model. Based on the integrated propulsion system model of a benchmark ocean-going chemical tanker, the engine dynamic behaviour during ship acceleration, deceleration and crash stop has been investigated. Results show that, during dynamic processes, the engine could be thermally overloaded even if the engine power trajectory is inside the static engine operating envelope. The paper contributes to finding proper indicators for thermal overloading of modern two-stroke marine diesel engines. It is demonstrated that when matching the engine with the propeller and designing the ship propulsion control system, not only the static engine operating envelope, but also the dynamic engine behaviour should be considered.

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This paper introduces a machine learning approach for optimizing propellers. The method aims to improve the computational cost of optimization by reducing the number of evaluations required to find solutions. This is achieved by directing the search towards design clusters with good performance, i.e. high propulsive efficiency and low cavitation. Three types of clusters are expected. The first cluster constitutes designs with performance of interest, i.e. high efficiency and low cavitation. The second cluster constitutes designs with performance not of interest, i.e. low efficiency and high cavitation. The third cluster constitutes designs whose performance cannot be estimated with the Boundary Element Methods (BEM) that we use in this study. In simple cases with single objective optimization to maximize efficiency, these clusters can be identified a-priori with unsupervised classifiers provided that orthogonally independent parameters are used as demonstrated in this paper. For multi-objective constrained optimization, to maximize efficiency and minimize cavitation, for example, supervised classifiers may be required to learn the clusters. Classical design variables such as chordlength, pitch, skew, rake, thickness distribution and camber of hydrofoils cannot be used to identify these clusters because of multicollinearity. Thus, a new orthogonal parametric model is proposed where the parameters are directly derived from the propeller blade mesh. As the blade surface mesh is used as boundary conditions to solve the governing equations, the orthogonal parameters are expected to have a stronger correlation with performance predictions of BEM or Computational Fluid Dynamics (CFD) than classical design variables. We demonstrate that design clusters with good performance can be identified with few BEM evaluations. Furthermore, the method synergizes explainable supervised and unsupervised learning to advice search algorithms and quickly guide them to lucrative regions in the design space. However, reducing the cost of optimization results in a trade-off with completeness of the search; this is also investigated in this paper. The method is demonstrated on a simple fully wetted flow case of the benchmark Wageningen B-4 70 propeller with P/D=1.0, as the geometry and open-water curves are readily accessible allowing back of the envelope verification and validation of our results.

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As shipping is setting sail for a sustainable future, the application of fuel cells is increasingly regarded as a promising technology to reduce or fully eliminate emissions. Fuel cells convert the chemical energy in fuels directly into electricity, achieving high efficiencies while emitting no hazardous compounds and producing little noise and vibrations. This chapter provides an overview of different fuel cell systems and discusses the various fuel cell types, working principles and characteristics. Particular attention is given to the low and high temperature polymer electrolyte membrane fuel cell and solid oxide fuel cell, as these are often considered to hold most potential for application in ships. The application of fuel cells is not restricted to the use of pure hydrogen, thus an overview of relevant fuel processing and purification technologies is provided as well. Operational aspects including electrical efficiency, part load performance, load transients, system start-up, heat recovery and combined cycle operation are introduced and subsequently discussed in the context of maritime application. Aspects related to ship design and operation, emission regulation compliance, reliability, availability, maintenance, safety and economics are briefly considered. Finally, an overview of relevant maritime experience and a future outlook are provided.

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Current EEDI (Energy Efficiency Design Index) regulations striving to reduce the installed engine power on new ships for a low EEDI may lead to underpowered ships having insufficient power when operating in adverse sea conditions. In this paper, the operational safety of a low-powered ocean-going cargo ship operating in adverse sea conditions has been investigated using an integrated ship propulsion, manoeuvring and sea state model. The ship propulsion and manoeuvring performance, especially the dynamic engine behaviour, when the ship is sailing in heavy weather and turning into head sea, have been studied. According to the results, the dynamic engine behaviour should be considered when assessing the ship operational safety, as the static engine operating envelope is inadequate for the safety assessment. The impact of PTO/PTI (power-take-off/in) operation and changing propeller pitch on the ship thrust availability in adverse sea conditions have also been investigated. To protect the engine from mechanical and thermal overloading, compressor surge and over-speeding during dynamic ship operations and/or in high sea states, the engine and propeller should be carefully controlled. The paper shows that if in (heavy) adverse weather the propeller pitch can be reduced or if the shaft generator can work as a motor (PTI), more thrust can be developed which can significantly improve the operational safety of the ship.

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In this paper a Concept Exploration Tool (CET) for naval ship power plants is presented. The ideas behind the CET are introduced as well as the inner workings of the tool. Objective functions for different relevant design criteria (energy efficiency, emissions, signatures, etc.) are shortly discussed, after which the results for a Frigate case study will be shown. Interesting solutions that are outside the well-known zone of conventional configurations, that may lead to new insights and innovative designs, are amongst the results of the CET; demonstrating the advantages of Design Space Exploration. The main development of this CET compared to earlier versions is however in the computational effectiveness of the tool, which is amongst others made possible by so-called Intermediate Design Algorithms (IDeAs). The major improvement in computational time provides additional room for further development of the objective functions used.@en

To continue its operations, the marine industry needs to comply with emission regulations. Solid Oxide Fuel Cells (SOFCs) are considered a promising solution, since it can generate energy athigh efficiency and low NOX, SOX and particulate matter emissions. Another advantage of SOFCsis fuel flexibility, meaning several fuels can be applied in SOFC systems. This brings up the question which fuel is most effective for a marine SOFC system. In this research, marine gas oil (benchmark), liquefied hydrogen, biodiesel, Fischer-Tropsch diesel, natural gas, methanol, dimethyl ether, and hydrogenare compared as bunker fuel. A comparison framework is proposed specialised for marine applications. The following decision criteria are selected: production capacity, volumetric/ gravimetric energy density, technological readiness, safety, fuel cost, cost of the fuel storage system, and emissions. The performance indicators are quantified for every fuel based on literature and supplier information.In the end, five alternative fuels are selected for marine SOFC systems on the selected criteria, which wille be used in further research.@en

Ship designers hardly ever receive feedback from the actual operation of their designs apart from sea acceptance trials. Similarly, crews operating the vessels do not receive a clear picture of the energy performance and environmental footprint of different options. This paper proposes a methodology based on operational data from continuous monitoring, and applies it to an ocean patrol vessel of the Royal Netherlands Navy in order to identify the impact of diverse operational conditions on energy performance over the whole operating range, but also to examine the decision to equip the vessel with hybrid propulsion. Specifically, it introduces mean energy effectiveness indicator and mean total energy efficiency over discretised vessel speed, as the main tool in quantifying the energy gains and losses to assist in making better-advised design and operational decisions. Moreover, it demonstrates a dataset enrichment procedure, using manufacturers' information, in case not all needed sensors are available. Results suggest that electrical propulsion was 15–25% less efficient than the best mechanical propulsion mode, and on the overall energy performance of the vessel, increasing speed by 1 knot caused a 7% and 14% increase over the minimum (Formula presented.) /mile emissions between 8 and 14, and above 14 knots respectively.

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We propose and analyse an optimization method that uses a machine learning approach to solve multi-objective, constrained propeller optimization problems. The method uses an online learning strategy where explainable supervised classifiers learn the location of the Pareto front and advise search strategies. The classifiers are trained with orthogonal features that capture geometric variation in radial distribution of pitch, skew, camber and chordlength. Based on orthogonal features, the classifiers predict whether or not a design lies on the Pareto front. If the design is predicted to lie on the Pareto front, the method verifies this with an evaluation. If the design is predicted to not lie on the Pareto front with a high confidence level, then the design is ignored. This skipped evaluation reduces the computational effort of optimization. The method is demonstrated on a cavitating, unsteady flow case of the Wageningen B-4 70 propeller with P/D = 1.0 operating in the Seiun-Maru wake. Compared to the classical Non-dominated Sorting Genetic Algorithm — III (NSGA-III) the optimization method is able to reduce 30% of evaluations per generation while reproducing a comparable Pareto front. Trade-offs between suction side, pressure side, tip-vortex cavitation and efficiency are identified from the Pareto front. The non-elitist NSGA-III search algorithm in conjunction with the explainable supervised classifiers also find very diverse solutions. Among the solutions, a design with no pressure side cavitation, low suction side cavitation and reasonable tip-vortex cavitation is found.

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Increasing pressure on the reduction or elimination of the use of fossil fuels in shipping requires the application of new maritime fuel alternatives. Green and circular produced hydrogen as a maritime fuel in fuel cell systems offers a great solution for these concerns. A fuel cell system has a zero emission performance, solid state silent process cycle, graceful degradation and no single point of failure. From a naval perspective, these characteristics very much support operational requirements like a silent propulsion and very low thermal and acoustic signatures as well as the possibility of an air independent system. Storage of hydrogen, however, is an issue. Traditional hydrogen storage in gas or liquefied aggregation has low volumetric density, low flame point, fire and explosion risks and transport challenges. The aim of this literature review is to investigate several hydrogen carriers and evaluate their characteristics on maritime and naval performance. This includes their volumetric and gravimetric density, dehydrogenation process, safety, logistic availability and handling. Over 15 different (types of) hydrogen carriers have been researched. Borohydrides, specifically sodium borohydride appeared to have several advantages, but still has issues with its hydrogenation process and handling due to it being a solid. The liquid organic hydrogen carrier dibenzyl toluene, on the other hand, does not meet the required energy density, but does have favourable additional properties, such as easy hydrogenation and good handling. Both of these are also subject of current research and development: For example, Hydrogenious LOHC Maritime AS, in combination with �stensj? Rederi, is working on a megawatt application for maritime, which should be finished in 2025. The Dutch government funds the SH2IPDRIVE project and the European Interreg North West Europe organization funds the H2SHIPS research project to analyse the shipboard use of these hydrogen carriers and to establish the design and engineering optimization opportunities.@en

The current literature on solid oxide fuel cell and internal combustion engine (SOFC-ICE) integration is focused on the application of advanced combustion technologies operating as bottoming cycles to generate a small load share. This integration approach can pose challenges for ships such as restricted dynamic capabilities and large space and weight requirements. Furthermore, the potential of SOFC-ICE integration for marine power generation has not been explored. Consequently, the current work proposes a novel approach of SOFC-ICE integration for maritime applications, which allows for high-efficiency power generation while the SOFC anode-off gas (AOG) is blended with natural gas (NG) and combusted in a marine spark-ignited (SI) engine for combined power generation. The objective of this paper is to investigate the potential of the proposed SOFC-ICE integration approach with respect to system efficiency, emissions, load sharing, space and weight considerations and load response. In this work, a verified zero-dimensional (0-D) SOFC model, engine experiments and a validated AOG-NG mean value engine model is used. The study found that the SOFC-ICE integration, with a 67–33 power split at 750 kWe power output, yielded the highest efficiency improvement of 8.3% over a conventional marine natural gas engine. Simulation results showed that promising improvements in efficiency of 5.2%, UHC and NOx reductions of about 30% and CO₂ reductions of about 12% can be achieved from a 33–67 SOFC-ICE power split with comparatively much smaller increments in size and weight of 1.7 times. Furthermore, the study concluded that in the proposed SOFC-ICE system for maritime applications, a power split that favours the ICE would significantly improve the dynamic capabilities of the combined system and that the possible sudden and large load changes can be met by the ICE.

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This paper proposes an advanced shipboard energy management strategy (EMS) based on model predictive control (MPC). This EMS aims to reduce mission-scale fuel consumption of ship hybrid power plants, taking into account constraints introduced by the shipboard battery system. Such constraints are present due to the boundaries on the battery capacity and state of charge (SoC) values, aiming to ensure safe seagoing operation and long-lasting battery life. The proposed EMS can be used earlier in the propulsion design process and requires no tuning of parameters for a specific operating profile. The novelties of the study reside in (i) studying the impact of mission-scale effects and integral constraints on optimal fuel consumption and controller robustness, (ii) benchmarking the performance of the proposed MPC framework. A case study carried out on a naval vessel demonstrates near-optimal and robust behaviour of the controller for several loading sequences. The application of the proposed MPC framework can lead to up to 3.5% consumption reduction due to utilisation of long term information, considering specific loading sequences and charge depleting (CD) battery operation@en