The impedance of solar cells can be leveraged for a variety of innovative applications. However, for the continued advancement of such applications, it is crucial to understand how the impedance varies during practical operation. This work characterizes the impedance of modern crystalline silicon solar cells across different bias voltages and under varying illumination and temperature conditions. It is found that for a given bias voltage, variations in temperature have a notably stronger impact on PN junction impedance than changes in irradiance. However, during maximum power point (MPP) tracking, variations in irradiance have a larger influence on the PN junction impedance than temperature variations. This is related to the shifting operating voltage during operation. Furthermore, it is shown that the capacitance during practical operation can strongly vary for different solar cells. For instance, the areal MPP capacitance values of the two cells tested in this study at 0.1 sun irradiance and a temperature of 30 °C were 0.283 μF/cm2 and 20.2 μF/cm2, a 71-fold difference. Conversely, the range of the MPP diffusion resistance was found to be highly similar for different cells. The results of this study enhance the understanding of solar-cell impedance and have a broad applicability.@en

Positive Energy Districts (PEDs) are integral to achieving sustainable urban development by enhancing energy self-sufficiency and reducing carbon emissions. This paper explores energy balance calculations in four diverse case study districts within different climatic conditions—Fiat Village in Settimo Torinese (Italy), Großschönau (Austria), Beursplain in Amsterdam (Netherlands), and Lunca Pomostului in Reşiţa (Romania)—as part of the SIMPLY Positive project. Each district faces unique challenges, such as outdated infrastructure or heritage protection, which we address through tailored strategies including building renovations and the integration of renewable energy systems. Additionally, we employ advanced simulation methodologies to assess energy performance. Simulation results highlight the significance of innovative technologies like photovoltaic-thermal (PVT) systems, application of demand-side actions, and flexible grid usage. Furthermore, mobility assessments and resident-driven initiatives demonstrate the critical role of community engagement in reducing carbon footprints. This study underscores the adaptability of PED frameworks across varied urban contexts and provides actionable insights for scaling similar strategies globally, supporting net-zero energy targets.@en

A thorough understanding of the small-signal response of solar cells can reveal intrinsic device characteristics and pave the way for innovations. This study investigates the impedance of crystalline silicon PN junction devices using TCAD simulations, focusing on the impact of frequency, bias voltage, and the presence of a low–high (LH) junction. It is shown that the PN junction exhibits the behavior of a parallel resistor–capacitor circuit (RC-loop) with fixed element values at low frequencies, but undergoes relaxation in both resistance R_j and capacitance C_j as frequency increases. Moreover, it is revealed that the addition of a LH junction impacts the impedance by altering R_j, C_j, and the series resistance R_s. Finally, while various publications on solar-cell impedance model the LH junction using an RC-loop, the findings in this study indicate that such a model does not accurately represent the underlying physics. Instead, this approach is likely compensating for the frequency-dependent behavior of R_j and C_j.

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Polycrystalline silicon (poly-Si) carrier-selective passivating contacts (CSPCs), featuring high photoconversion efficiency (PCE) and cost-effectiveness, have emerged as a promising approach for high-efficiency crystalline silicon (c-Si) solar cells. To minimize parasitic absorption losses induced by doped poly-Si window layers, wide bandgap oxygen-alloyed poly-Si (poly-SiO_x) layers are developed. However, challenges persist in achieving excellent surface passivation for boron-doped poly-SiO_x contact stacks, likely caused by boron diffusion during annealing and the reduced doping concentration resulting from lower crystallinity as oxygen content increases. In this study, we investigate the impact on the passivating contact structure and solar cell performance of a 10-nm thick intrinsic hydrogenated amorphous silicon buffer layer with varying oxygen content (a-Si (O_x):H) deposited by plasma-enhanced chemical vapor deposition (PECVD), and placed between the tunneling silicon oxide (SiO_x) and the poly-SiO_x (p⁺). After the hydrogenation step, we obtain both high passivation quality with implied open circuit voltage (iV_oc) of 728.3 mV and low contact resistivity (ρ_c) of 59.18 mΩ cm² on polished surface for oxygen-free a-Si:H buffer layer. These improvements can be attributed to the appropriate thickness of the tunnel oxide and confirmed by transmission electron microscopy (TEM) images, to higher crystallinity of the buffer layer, which facilitates more efficient doping in the buffer layer. This is evidenced by energy dispersive X-ray spectroscopy (EDX), and X-ray photoelectron spectroscopy (XPS) results. At the device level, a front-side textured, rear-side flat, rear junction poly-SiO_x/poly-SiO_x solar cell on n-type c-Si wafer, an efficiency improvement can be observed from 3.55 % without a PECVD buffer layer to 18.9 % with an oxygen-free a-Si:H PECVD buffer layer. The impact of the buffer layer crystallinity on cell performance is further demonstrated by deploying a 10-nm thick LPCVD buffer layer, which facilitates an efficiency of 21.15 % for the same device structure.

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Photovoltaic modules are typically not optimized for conditions of partial shading. One proposed approach to improve their shade tolerance is to implement maximum power point tracking on different strings of cells within the modules. However, this approach increases the demand for sub-module power converters, which poses a challenge. To address this, researchers have suggested integrating power electronic components directly into the module laminate, or even within the solar cells themselves. Despite these advancements, limited research has focused on integrating the most bulky component: the inductor. This study investigates through simulations whether planar air-core inductors can yield the required properties to support sub-module power conversion. The simulated inductors have an area that is as large as an industrial crystalline silicon solar cell. First, it is shown how the interplay between the different design parameters, such as track spacing, track width, number of turns, and middle gap size, plays an important role in the inductor properties at high frequency. The coil geometries that are simulated yield inductance values between 0.3 μH and 3.2 μH. Subsequently, the feasibility of implementing these inductors into an exemplary DC–DC boost converter is evaluated. To adequately reduce the ripple current, a significant switching frequency of at least several hundred kHz is required. Additionally, at 500 kHz, an inductor thickness of around 0.5 mm is necessary to keep the ohmic losses in the inductor below 2% of the total generated power in standard test conditions. While demonstrating feasible combinations, these findings also present significant challenges.@en

Reducing indium consumption in transparent conductive oxide (TCO) layers is crucial for mass production of silicon heterojunction (SHJ) solar cells. In this contribution, optical simulation-assisted design and optimization of SHJ solar cells featuring MoO_x hole collectors with ultra-thin TCO layers is performed. Firstly, bifacial SHJ solar cells with MoO_x as the hole transport layer (HTL) and three types of n-contact as electron transport layer (ETL) are fabricated with 50 nm thick ITO on both sides. It is found that bilayer (nc-Si:H/a-Si:H) and trilayer (nc-SiO_x:H/nc-Si:H/a-Si:H) as n-contacts performed electronically and optically better than monolayer (a-Si:H) in bifacial SHJ cells, respectively. Then, as suggested by optical simulations, the same stack of tungsten-doped indium oxide (IWO) and optimized MgF₂ layers are applied on both sides of front/back-contacted SHJ solar cells. Devices endowed with 10 nm thick IWO and bilayer n-contact exhibit a certified efficiency of 21.66% and 20.66% when measured from MoO_x and n-contact side, respectively. Specifically, when illuminating from the MoO_x side, the short-circuit current density and the fill factor remain well above 40 mA cm⁻² and 77%, respectively. Compared to standard front/rear TCO thicknesses (75 nm/150 nm) deployed in monofacial SHJ solar cells, this represents over 90% TCO reduction. As for bifacial cells featuring 50 nm thick IWO layers, a champion device with a bilayer n-contact as ETL is obtained, which exhibits certified conversion efficiency of 23.25% and 22.75% when characterized from the MoO_x side and the n-layer side, respectively, with a bifaciality factor of 0.98. In general, by utilizing a n-type bilayer stack, bifaciality factor is above 0.96 and it can be further enhanced up to 0.99 by switching to a n-type trilayer stack. Again, compared to the aforementioned standard front/rear TCO thicknesses, this translates to a TCO reduction of more than 67%.

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This paper presents dynamic air-based models of a hybrid photovoltaic-thermal (PVT) collector. The models are developed with the aim of estimating the temperature of the collector components and therefore of estimating the annual generation of electrical energy and thermal energy outputs, by using actual climate data of six different cities based on Köppen-Geiger-Photovoltaic (KGPV) climate zones. The results show that the unglazed type collector has the best PV cooling while the dual channel collector has the best air heating among air-based PVT collectors. The results also indicate that the use of additional fluid enhances both electrical and thermal performance. The dynamic models are validated by comparison with results found in the literature. The paper also discusses a novel bi-fluid PVT system combined with a storage tank and an H-infinity based robust controller that can handle uncertainties. The results of the bi-fluid system show that the fraction of energy demand covered by the system is highly dependent on climate conditions and the collector's surface area. It was found that for a small-scale house (standard for four people), the proposed system can cover more than 70% annual domestic hot water demand for cities with high solar irradiance and 32% for a city with low solar irradiance.

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Nowadays, an increasing share of photovoltaic (PV) systems makes use of module- or submodule-level power electronics (PE). Furthermore, PE is used in stand-alone devices powered by PV-storage solutions. One way to facilitate further implementation of PE in PV applications is to integrate PE components into crystalline silicon PV cells. Herein, the COSMOS device is introduced, denoting COmbined Solar cell and metal-oxide-semiconductor field-effect transistor (MOSFET). Specifically, the combined manufacturing of lateral power MOSFETs and interdigitated back contact solar cells with tunnel-oxide passivated contacts (TOPCon) on a single wafer is reported. Many steps of the proposed process flow are used for the fabrication of both devices, enabling cost-effective integration of the MOSFET. Both n-type solar cells with integrated p-channel MOSFETs (PMOS) and p-type solar cells with integrated n-channel MOSFETs (NMOS) are successfully manufactured. NMOS devices perform better in achieving low on-resistance, while PMOS devices exhibit lower leakage currents. Furthermore, the study reveals integration challenges where off-state leakage currents of the MOSFET can increase due to illumination and specific configurations of monolithic interconnections between the MOSFET and the solar cell. Nevertheless, for both n-type and p-type solar cells, efficiencies exceeding 20% are achieved, highlighting the potential of the proposed process for COSMOS devices.

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Solar photovoltaic (PV) energy is variable. The output power can change considerably in a matter of minutes, imposing challenges on the control of systems connected downstream. The power from these systems can be smoothed using electric storage, potentially increasing the system cost. An alternative is to deliberately curtail the power before it starts to change. This strategy relies on ultra-short-term forecasting to determine the curtailment point. Unfortunately, forecasting is prone to errors and high uncertainty even in the very short-term, leading to control errors. We propose an active power curtailment control strategy for a stand-alone solar photovoltaic system powering an electrolyzer. Our work's novelty relies on the controller's ability to deal with large forecasting errors and high uncertainty, combining artificial intelligence for predicting the power ramps and fuzzy logic to account for imperfect prediction. We validated our approach using a hardware emulator of the photovoltaic system, power converter and electrolyzer. Under clear sky conditions, the curtailment results in unnecessary energy loss, while under variable irradiance, the controller successfully smooths the power ramps within 10% of the PV system's nominal power. Although our approach was designed for a stand-alone system, its concept can be directly applied to grid-connected systems as well.

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This work presents a practical approach to designing an optical filter for thermal management for photovoltaic modules. The approach emphasizes the practicality of manufacturing over optical performance. Simulation work demonstrates that, for an interdigitated back contact solar cell architecture, complete rejection of infrared radiation offers limited thermal benefits requiring highly complex optical filter designs. An alternative approach consists of reducing thermalization losses by providing reflectance at lower wavelength values. An optical filter design that fulfills this requirement is possible using simple structures based on two materials and taking advantage of the harmonics present in quarter wavelength optical thickness designs. The filter is later optimized for angular performance via second-order algorithms, resulting in a device consisting of only 15 thin-film layers. Performance simulations on two locations, Delft (the Netherlands) and Singapore, estimate a temperature reduction of 2.20°C and 2.45°C, respectively. In a single year, the optical loss produced by the filter is not compensated via temperature reduction. However, improvements in the annual degradation rate show that in Singapore, the overall effect of the filter on the lifetime DC energy yield is positive.

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Transition metal oxide (TMO) thin films exhibit large bandgap and hold great potential for enhancing the performance of silicon heterojunction (SHJ) solar cells by increasing the short-circuit current density significantly. On the other hand, achieving precise control over the electrical properties of TMO layers is crucial for optimizing their function as efficient carrier-selective layer. This study demonstrates a general and feasible approach for manipulating the quality of several TMO films, aimed at enhancing their applicability in silicon heterojunction (SHJ) solar cells. The core of our method involves precise engineering of the interface between the TMO film and the underlying hydrogenated intrinsic amorphous silicon passivation layer by managing the reaction of the TMO on the surface. X-ray photoelectron spectroscopy spectra demonstrate that our methods can modify the oxygen content in TMO films, thereby adjusting their electronic properties. By applying this method, we have successfully fabricated WO_x-based SHJ solar cells with 23.30 % conversion efficiency and V₂O_x-based SHJ solar cells with 22.04 % conversion efficiency, while keeping n-type silicon-based electron-transport layer at the rear side. This research paves the way for extending such interface engineering methods to other TMO materials used as hole-transport layers in SHJ solar cells.

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Clouds moving in front or away from the sun are the leading cause of irradiance variability. These variations have a repercussion on the electricity production of photovoltaic systems. Predicting such changes is essential for proper control of these systems and for maintaining grid stability. Images from the sky have proven to help with short-term solar irradiance forecasting, especially when combined with artificial intelligence. Nevertheless, these models tend to smooth the irradiance fluctuations. We propose a forecasting model to predict the clear-sky index in a forecast horizon of 20 min with a 1-minute resolution. Our model, based on a classifier to determine the sky conditions and, on an optical flow, applies an artificial intelligence model explicitly trained on each class of sky conditions. This strategy has an equivalent performance to an unclassified model and a forecast skill between 5 and 20% with respect to the smart persistence model for most classes of sky conditions while requiring considerably less training data. Although our model reduces the overall predicting error, it still has difficulties predicting irradiance changes and mainly overcast days. Our classifying strategy can be applied to other models targeting different objectives to predict sudden changes in either irradiance or power related to photovoltaic systems.

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This work is a long-term, interannual, and experimental study conducted in multiple locations. It studies the effects of phase change materials (PCMs) on photovoltaic modules’ performance by reducing their operational temperature. Two PV modules were manufactured so that PCM slabs could be mechanically attached to their backside, ensuring contact with the related photovoltaic active area. Experiments were conducted in Delft, Netherlands, from 2019 until 2021 and in Catania, Italy, during the winter and start of spring of 2023. The experiment also considered two installation layouts: building integrated (Delft) and standard rack-mounted (Catania). The measurements showed that the PCM provides significant cooling under both locations, with a temperature reduction of up to 15 °C. In Delft, thermal control could be obtained for most of the sunny hours of the day, even during the summer months. In Catania, the module with PCM presented, on occasion, higher temperatures than its standard counterpart, primarily due to winter-time environmental conditions. However, the PCM provided sufficient thermal control on all conditions, ensuring increased energy yield. This increase ranged from 2.1 to 2.5 % in Delft and 1.3–1.6 % in Italy.

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Single junction crystalline silicon (c-Si) solar cells are reaching their practical efficiency limit whereas perovskite/c-Si tandem solar cells have achieved efficiencies above the theoretical limit of single junction c-Si solar cells. Next to low-thermal budget silicon heterojunction architecture, high-thermal budget carrier-selective passivating contacts (CSPCs) based on polycrystalline-SiO_x (poly-SiO_x) also constitute a promising architecture for high efficiency perovskite/c-Si tandem solar cells. In this work, we present the development of c-Si bottom cells based on high temperature poly-SiO_x CSPCs and demonstrate novel high efficiency four-terminal (4T) and two-terminal (2T) perovskite/c-Si tandem solar cells. First, we tuned the ultra-thin, thermally grown SiO_x. Then we optimized the passivation properties of p-type and n-type doped poly-SiO_x CSPCs. Here, we have optimized the p-type doped poly-SiO_x CSPC on textured interfaces via a two-step annealing process. Finally, we integrated such bottom solar cells in both 4T and 2T tandems, achieving 28.1% and 23.2% conversion efficiency, respectively.

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Even though interdigitated back contact (IBC) architecture produces the most efficient solar cells, it is difficult to make them cost-effective and industrially viable. Therefore, single-sided atmospheric pressure chemical vapor deposition (APCVD) is investigated for the fabrication of IBC solar cells because it reduces the overall thermal budget, simplifies wet bench processing, and requires no additional masking layer. For the fabrication of a full APCVD IBC solar cell, a very lightly doped front surface field (FSF) of 650 Ω/sq, a heavier doped back surface field (BSF) of 100 Ω/sq and a moderately doped emitter of 250 Ω/sq was used. The high-temperature annealing step is partially done in an oxygen (O₂) environment to (i) drive in dopants, (ii) prevent the formation of a boron-rich layer in case of p⁺ doped c-Si, and (iii) grow an in-situ SiO₂ at the Si/dopant glass interface. The etch rate difference between the in-situ grown SiO₂ and the doped glass layer is utilized to etch the doped glass completely. The retained in-situ SiO₂ after etching is capped with plasma-enhanced chemical vapor deposited (PECVD) SiN_x for the passivation of both polarities of IBC solar cells. A full APCVD IBC solar cell precursors (i.e. before metallization) obtained implied open-circuit voltage (iV_oc) of 714 mV and emitter saturation current density (J_0s) of 17 fA/cm². At the device level, a full APCVD IBC solar cell achieved a conversion efficiency of 22.8% with V_oc of 696 mV and short-circuit current density J_SC of 41.3 mA/cm². These parameters are comparable to the commercially available full-tube diffused ZEBRA® IBC solar cells.

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Passivating contacts based on poly-Si have enabled record-high c-Si solar cell efficiencies due to their excellent surface passivation quality and carrier selectivity. The eventual existence of pinholes within the ultra-thin SiOx layer is one of the key factors for carrier collection, beside the tunneling mechanism. However, pinholes are usually believed to have negative impact on the passivation quality of poly-Si passivating contacts. This work studied the influence of the pinhole density on the passivation quality of ion-implanted poly-Si passivating contacts by decoupling the pinhole generation from the dopants diffusion process by means of two annealing steps: (1) a pre-annealing step at high temperature after the intrinsic poly-Si deposition to visualize the formation of pinholes and (2) a post-annealing step for dopants activation/diffusion after ion-implantation. The pinhole density is quantified in the range of 1✕106 to 3✕108 cm2 by the TMAH selective etching approach. The passivation quality is discussed with respect to the pinhole density and the post-annealing thermal budget (TB) for dopants diffusion. The study shows that a moderate pinhole density does not induce doping profile variations that can be detectable by the coarse spatial resolution of ECV measurements. It is surprising that the existence of pinholes in a moderate density within our thickness fixed SiOx layer can effectively enhance the passivation qualities for both n+ and p+ poly-Si passivating contacts. We speculate the reason is due to the enhanced field-effect passivation at the pinhole surrounding. In fact, the variation of the passivation quality depends on the balance between a strengthened field-effect passivation and an excessive local Auger recombination, being both effects induced by the higher and deeper level of dopants diffused into the c-Si surface through the pinholes.@en

Herein, the application of a comprehensive modeling framework that can help optimize the design of multilayered optical filters for coloring photovoltaic (PV) modules is presented based on crystalline silicon solar cells. To overcome technical issues related to the implementation of color filters (CFs) on PV modules, like glare and color instability, colorimetry metrics, such as the hue, chroma, luminance color space, and the quantitative concept of difference between two colors are extensively deployed. It is showcased in this work that designing colored modules with high hue and chroma stability is possible by using a front-side texturing with edged geometry, like V-shaped grooves and inverted pyramids, while obtaining colors with relatively high luminance values, indicating good brightness. Furthermore, it is argued that adapting the rear surface of the front glass with a random textured layout where the CF is applied can improve color and luminance stability without significant loss of chroma while eliminating glare. Finally, the models can be used to optimize the number of layers for a given CF, reducing unnecessary optical losses. Compared to a standard PV module, performance simulation of optimized, bright-colored PV modules predicts relative energy yield losses ranging from 7% to 25%.

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To achieve a high performance in sub-module power conditioning circuits, it is important that power converters are designed in accordance with the photovoltaic (PV) cell impedance at the input. Taking this one step further, exploiting the impedance of cell strings could even support novel power conditioning approaches in PV modules. In this work, we characterize the impedance of eight single-cell laminates based on different industrial c-Si PV cell architectures. This characterization is carried out by impedance spectroscopy in dark conditions at room temperature, and the capacitive and inductive effects are evaluated through equivalent model fitting. By comparing the results for the different laminates, it is revealed how the cell design affects its impedance. Our experiments show that the PN junction capacitance at maximum power point varies for the different cells between 0.30 and 45.6 μF/cm². The two main factors contributing to a high PV cell capacitance at maximum power point are (i) a low wafer dopant concentration and (ii) a high maximum power point voltage. In high-efficiency c-Si PV cells that will be fabricated in the coming years, increasing capacitances are expected for operation near the maximum power point. Furthermore, the single-cell laminates exhibit inductances between 63 and 130 nH, and our results indicate that the inductance is mostly affected by the number of busbars and the geometry of the metal contacts.

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Reconfigurable photovoltaic modules are a promising approach to improve the energy yield of partially shaded systems. So far, the feasibility of this concept has been evaluated through simulations or simplified experiments. In this work, we analyse the outdoor performance of a full-scale prototype of a series-parallel photovoltaic module with six reconfigurable blocks. Over a 4-month-long period, its performance was compared to a reference photovoltaic module with static interconnections and six bypass diodes. The results show that under partial shading, the reconfigurable module produced 10.2% more energy than the reference module. In contrast, under uniform illumination the energy yield of the reconfigurable PV module was 1.9% lower due to the additional losses introduced by its switching matrix. Finally, a modification in the reconfiguration algorithm is proposed to reduce the output current–voltage range of the module and simplify the design of module-level power converters while limiting the shading tolerance loss.

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Integration of photovoltaics (PV) into the urban environment will play a major role in the energy transition. However, installing PV systems on building roofs can be challenging, particularly for monumental buildings with strict architectural and social value restrictions. Assessing roof surface visibility is, therefore, key to finding as much permitted roof surface area as possible that may be used for PV installation. In this study, a GIS-based large-scale visibility assessment tool is developed that can assist in evaluating roof visibility, using LiDAR, road networks, and cadastral data as inputs. The tool delivers multi-level outputs, including maps of roof binary visibility, roof visual amplitude, roof PV system layout, roof PV system AC yield, and roof PV module visibility. After optimization, an average speed of 0.12 s/m² is achieved. For each roof surface, an additional sensitivity analysis has been conducted. This step determines the optimal values for two visibility analysis parameters: assessment range and observer spacing, balancing the computational demand and result accuracy. Application of this workflow to the monumental buildings on the TU Delft campus revealed that approximately 2.68 GWh/year of electricity could be harvested from imperceptible PV modules, while an additional 0.42 GWh/year of energy is attributed to PV modules with medium visibility, and 0.37 GWh/year of energy is associated with PV modules with high visibility. This modeling workflow supports the multi-criteria decision-making process for urban roof PV planning.

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