Lead halide perovskites have attracted significant attention for their wide-ranging applications in optoelectronic devices. A ubiquitous element in these applications is that charging of the perovskite is involved, which can trigger electrochemical degradation reactions. Understanding the underlying factors governing these degradation processes is crucial for improving the stability of perovskite-based devices. For bulk semiconductors, the electrochemical decomposition potentials depend on the stabilization of atoms in the lattice-a parameter linked to the material’s solubility. For perovskite nanocrystals (NCs), electrochemical surface reactions are strongly influenced by the binding equilibrium of passivating ligands. Here, we report a spectro-electrochemical study on CsPbBr₃ NCs and bulk thin films in contact with various electrolytes, aimed at understanding the factors that control cathodic degradation. These measurements reveal that the cathodic decomposition of NCs is primarily determined by the solubility of surface ligands, with diminished cathodic degradation for NCs in high-polarity electrolyte solvents where ligand solubilities are lower. However, the solubility of the surface ligands and bulk lattice of NCs are orthogonal, such that no electrolyte could be identified where both the surface and bulk are stabilized against cathodic decomposition. This poses inherent challenges for electrochemical applications: (i) The electrochemical stability window of CsPbBr₃ NCs is constrained by the reduction potential of dissolved Pb²⁺ complexes, and (ii) cathodic decomposition occurs well before the conduction band can be populated with electrons. Our findings provide insights to enhance the electrochemical stability of perovskite thin films and NCs, emphasizing the importance of a combined selection of surface passivation and electrolyte.

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The ever-increasing industry desire for improved performance makes linear controller design run into fundamental limitations. Nonlinear control methods such as Reset Control (RC) are needed to overcome these. RC is a promising candidate since, unlike other nonlinear methods, it easily integrates into the industry-preferred PID design framework. Thus far, RC has been analysed in the frequency domain either through describing function analysis or by direct closed-loop numerical computation. The former computes a simplified closed-loop RC response by assuming a sufficient low-pass behaviour. In doing so it ignores all harmonics, which literature has found to cause significant modelling prediction errors. The latter gives a precise solution, but by its direct closed-loop computation does not clearly show how open-loop RC design translates to closed-loop performance. The main contribution of this work is aimed at overcoming these limitations by considering an alternative approach for modelling RC using state-dependent impulse inputs. This permits accurately computing closed-loop RC behaviour starting from the underlying linear system, improving system understanding. A frequency-domain description for closed-loop RC is obtained, which is solved analytically by using several well-defined assumptions. This analytical solution is verified using a simulated high-precision stage, critically examining sources of modelling errors. The accuracy of the proposed method is further substantiated using controllers designed for various specifications.

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The authors regret for the typographical error in Eq. (13) and provide the corrected version below: The authors would like to apologize for any inconvenience caused.

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This article addresses nonlinearity in reset elements and its effects. Reset elements are known for having less phase lag based on describing function (DF) analysis compared to their linear counterparts; however, they are nonlinear elements and produce higher-order harmonics. This article investigates the steady-state higher-order harmonics for reset elements with one resetting state and proposes an architecture and a method of design that allows for band-passing the nonlinearity and its effects, namely, higher-order harmonics and phase advantage. The nonlinearity of reset elements is not entirely useful for all frequencies, for example, they are useful for reducing phase lag at crossover frequency regions; however, higher-order harmonics can compromise tracking and disturbance rejection performance at lower frequencies. Using the proposed “phase shaping” method, one can selectively suppress the nonlinearity of a single-state reset element in a desired range of frequencies and allow the nonlinearity to provide its phase benefit in a different desired range of frequencies. This can be especially useful for the reset elements in the framework of the “constant in gain, lead in phase” (CgLp) filter, which is a newly introduced nonlinear filter, bound to circumvent the well-known linear control limitation—the waterbed effect.@en

This article introduces a closed-loop frequency analysis tool for reset control systems. To begin with sufficient conditions for the existence of the steady-state response for a closed-loop system with a reset element and driven by periodic references are provided. It is then shown that, under specific conditions, such a steady-state response for periodic inputs is periodic with the same period as the input. Furthermore, a framework to obtain the steady-state response and to define a notion of closed-loop frequency response, including high order harmonics, is presented. Finally, pseudosensitivities for reset control systems are defined. These simplify the analysis of this class of systems and allow a direct software implementation of the analysis tool. This methods gives deeper insight into the performance of the system than that achieved with the describing function method.

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This paper presents the development of a contactless sensing system and the dynamic evaluation of an air-bearing based precision wafer positioning system. The contactless positioning stage is a response to the trend seen in the high-tech industry, where the substrates are becoming thinner and larger to reduce the cost and increase the yield. Using contactless handling it is possible to avoid damage and contamination. The system works by floating the substrate on a thin film of air. A viscous traction force is created on the substrate by steering the airflow. A cascaded control design structure has been implemented to the contactless positioning system, where the Inner Loop Controller (ILC) controls the actuator which steers the airflow and the Outer Loop Controller (OLC) controls the position of the substrate by controlling the reference of the ILC. The dynamics of the ILC are evaluated and optimized for the performance of the positioning of the substrate. The vibration disturbances are also handled by the ILC. The bandwidth of the system has been improved to 300 Hz. For the OLC a linear charge-coupled device has been implemented as a contactless sensor. The performance of the sensing system has been analyzed. During control in steady state, this resulted in a position error of the substrate of 12.9 (Formula presented.) m RMS, which is a little more as two times the resolution. The bandwidth of the OLC is approaching 10 Hz.

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This paper proposes a fractional-order reset element whose architecture allows for the suppression of nonlinear effects for a range of frequencies. Suppressing the nonlinear effects of a reset element for the desired frequency range while maintaining it for the rest is beneficial, especially when it is used in the framework of a “Constant in gain, Lead in phase” (CgLp) filter. CgLp is a newly introduced nonlinear filter, bound to circumvent the well-known linear control limitation—the waterbed effect. The ideal behaviour of such a filter in the frequency domain is unity gain while providing a phase lead for a broad range of frequencies. However, CgLp’s ideal behaviour is based on the describing function, which is a first-order approximation that neglects the effects of the higher-order harmonics in the output of the filter. Although CgLp is fundamentally a nonlinear filter, its nonlinearity is not required for all frequencies. Thus, it is shown in this paper that using the proposed reset element architecture, CgLp gets closer to its ideal behaviour for a range of frequencies, and its performance will be improved accordingly.@en

This paper presents the development of a contactless sensing system and the dynamic evaluation of an air-bearing-based precision wafer positioning system. The contactless positioning stage is a response to the trend seen in the high-tech industry, where the substrates are becoming thinner and larger to reduce the cost and increase the yield. Using contactless handling it is possible to avoid damage and contamination. The system works by floating the substrate on a thin film of air. A viscous traction force is created on the substrate by steering the airflow. A cascaded control design structure has been implemented on the contactless positioning system, where the inner loop controller (ILC) controls the actuator which steers the airflow and the outer loop controller (OLC) controls the position of the substrate by controlling the reference of the ILC. The dynamics of the ILC are evaluated and optimized for the performance of the positioning of the substrate. The vibration disturbances are also handled by the ILC. The bandwidth of the system has been improved to 300 Hz. For the OLC, a linear charge-coupled device has been implemented as a contactless sensor. The performance of the sensing system has been analysed. During control in steady-state, this resulted in a position error of the substrate of 12.9 μm RMS, which is a little more than two times the resolution. The bandwidth of the OLC is approaching 10 Hz@en

Currently, the demand for a better alternative to linear PID controllers is increasing due to the rising expectations of the high-tech industry. In literature, it has been shown that Constant in gain Lead in phase (CgLp) compensators, which are a type of reset element, have high potential to improve the performance of systems. Although there are few works which investigate tuning of these compensators, the high order harmonics and steady-state performances have not yet been considered in these methods. Recently, a frequency-domain framework has been developed to analyze closed-loop performances of reset control systems which includes high order harmonics. In this paper, this frequency-domain framework is combined with loop-shaping constraints to provide a reliable frequency-domain tuning method for CgLp compensators. Finally, different performance metrics of a CgLp compensator are compared with those of a PID controller on a precision positioning stage. The results show that the presented tuning method is effective, and the system with the CgLp compensator achieves superior dynamic performance to that of the PID controller.@en

Reset control has emerged as a viable alternative to popular PID, capable of outperforming and overcoming the linear limitations. However, in motion control systems, quantization can cause severe performance degradation. This paper investigates this degradation in practical systems and re-purposes the reset band condition to mitigate the same. Numerical simulations have been conducted on a mass-based positioning system to analyze the cause of the quantization induced performance degradation. Moreover, a performance and robustness analysis was performed with the proposed solution. Finally, novel tuning guidelines are provided for estimating the required reset band parameter. Additionally, practical experiments have been conducted on a high precision motion system for validation. The experiments show by example that the reset band can reduce the error in the problematic region by up to 285% and hence shows the need and effectiveness of the proposed solution.@en

Reset control is known to be able to outperform PID and the like linear controllers. However, in motion control systems, quantization can cause severe performance degradation. This paper shows the application of time regularization to mitigate this practical issue in reset control systems. Numerical simulations have been conducted to analyze the cause of the quantization induced performance degradation and the effectiveness of time regularization to mitigate this degradation; with tuning guidelines for the time regularization parameter also provided. Moreover, a robustness analysis is performed. The solution is also tested experimentally on a high precision motion system for validation. It is estimated by numerical simulations that time regularization can reduce quantization induced performance degradation by almost 10dB. Experiments have similarly shown a reduction of several dB for the high precision motion stage.@en

The ever-growing demands on speed and precision from the precision motion industry have pushed control requirements to reach the limitations of linear control theory. Nonlinear controllers like reset provide a viable alternative since they can be easily integrated into the existing linear controller structure and designed using industry-preferred loop-shaping techniques. However, currently, loop-shaping is achieved using the describing function (DF) and performance analysed using linear control sensitivity functions not applicable for reset control systems, resulting in a significant deviation between expected and practical results. This major bottleneck to the wider adaptation of reset control is overcome in this paper with two important contributions. First, an extension of frequency-domain tools for reset controllers in the form of higher-order sinusoidal-input describing functions (HOSIDFs) is presented, providing greater insight into their behaviour. Second, a novel method that uses the DF and HOSIDFs of the open-loop reset control system for the estimation of the closed-loop sensitivity functions is proposed, establishing for the first time — the relation between open-loop and closed-loop behaviour of reset control systems in the frequency domain. The accuracy of the proposed solution is verified in both simulation and practice on a precision positioning stage and these results are further analysed to obtain insights into the tuning considerations for reset controllers.

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This paper presents a novel adaptive feedforward controller design for reset control systems. The combination of feedforward and reset feedback control promises high performance as the feedforward guarantees reference tracking, while the non-linear feedback element rejects disturbances. To overcome inevitable model mismatches, the feedforward controller adapts to increase precision in reference tracking. Where linear existing adaptive feedforward controllers do not guarantee convergence in the presence of reset, this work presents a novel adaptive law based on converging and diverging regions of adaptation to achieve good tracking. Experimental results demonstrate the claimed advantage of the novel method.

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Linear control such as PID possesses fundamental limitations, seen through the Waterbed effect. Reset control has been found to be able to overcome these limitations, while still maintaining the simplicity and ease of use of PID control due to its compatibility with the loop shaping method. However, the resetting action also gives rise to higher order harmonics that hinders consistent realization of the aforementioned expected improvement. In this paper, a fractional-order augmented state analogue of the reset integrator is investigated. This analogue is composed of a series of augmented states that each possesses unique reset values, providing the same first order harmonic behavior but reduced higher order harmonics magnitude compared to the reset integrator. The optimal number of augmented states along with the corresponding tuning values are investigated. To validate the improvement, the reset integrator and the optimal fractional order analogue are tuned to equally improve disturbance rejection of a high precision 1 DOF positioning stage while maintaining the stability level, with both designed to overcome linear control. From simulation and experimental results, it was found that the novel fractional-order augmented state analogue gives rise to disturbance rejection performance that is closer to the desired and expected improvement, compared to using the traditional reset integrator.

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This paper addresses a phenomenon caused by resetting only one of the two states of a so-called second order 'Constant in gain Lead in phase' (CgLp) element. CgLp is a recently introduced reset-based nonlinear element, bound to circumvent the well-known linear control limitation - the waterbed effect. The ideal behaviour of such a filter in the frequency domain is unity gain while providing a phase lead for a broad range of frequencies, which clearly violates the linear Bode's gain phase relationship. However, CgLp's ideal behaviour is based on a describing function, which is a first order approximation that neglects the effects of higher order harmonics in the output of the filter. Consequently, achieving the ideal behaviour is challenging when higher order harmonics are relatively large. It is shown in this paper that by resetting only one of the two states of a second order CgLp, the nonlinear filter will act as a linear one at a certain frequency, provided that some conditions are met. This phenomenon can be used to the benefit of reducing higher order harmonics of CgLp's output and achieving the ideal behaviour and thus better performance in terms of precision.

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Due to development of technology, linear controllers cannot satisfy requirements of high-tech industry. One solution is using nonlinear controllers such as reset elements to overcome this big barrier. In literature, the Constant in gain Lead in phase (CgLp) compensator is a novel reset element developed to overcome the inherent linear controller limitations. However, a tuning guideline for these controllers has not been proposed so far. In this paper, a recently developed method named higher-order sinusoidal input describing function (HOSIDF), which gives deeper insight into the frequency behaviour of non-linear controllers compared to sinusoidal input describing function (DF), is used to obtain a straight-forward tuning method for CgLp compensators. In this respect, comparative analyses on tracking performance of these compensators are carried out. Based on these analyses, tuning guidelines for CgLp compensators are developed and validated on a high-tech precision positioning stage. The results show the effectiveness of the developed tuning method.

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This paper presents the tuning of a reset-based element called “Constant in gain and Lead in phase” (CgLp) in order to achieve desired precision performance in tracking and steady state. CgLp has been recently introduced to overcome the inherent linear control limitation - the waterbed effect. The analysis of reset controllers including ones based on CgLp is mainly carried out in the frequency domain using describing function with the assumption that the relatively large magnitude of the first harmonic provides a good approximation. While this is true for several cases, the existence of higher-order harmonics in the output of these elements complicates their analysis and tuning in the control design process for high precision motion applications, where they cannot be neglected. While some numerical observation-based approaches have been considered in literature for the tuning of CgLp elements, a systematic approach based on the analysis of higher-order harmonics is found to be lacking. This paper analyzes the CgLp behaviour from the perspective of first as well as higher-order harmonics and presents simple relations between the tuning parameters and the gain-phase behaviour of all the harmonics, which can be used for better tuning of these elements. The presented relations are used for tuning a controller for a high-precision positioning stage and results used for validation.@en

PID controllers cannot satisfy the high-performance requirements since they are restricted by the water-bed effect. Thus, the need for a better alternative to linear PID controllers increases due to the rising demands of the high-tech industry. This has led many researchers to explore nonlinear controllers like reset control. Although reset controllers have been widely used to overcome the limitations of linear controllers in literature, the performance of the system varies depending on the relative sequence of controller linear and nonlinear parts. In this paper, the optimal sequence is found using high order sinusoidal input describing functions (HOSIDF). By arranging controller parts according to this strategy, better performance in the sense of precision and control input is achieved. The performance of the proposed sequence is validated on a precision positioning setup. The experimental results demonstrate that the optimal sequence found in theory outperforms other sequences.

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A controller with the frequency response of a complex order derivative may have a gain that decreases with frequency, while the phase increases. This behaviour may be desirable to ensure simultaneous rejection of high-frequency noise and robustness to variations of the open-loop gain. Implementations of such complex order controllers found in the literature are unsatisfactory for several reasons: the desired behaviour of the gain may be difficult or impossible to obtain, or non-minimum phase zeros may appear, or even unstable open-loop poles. We propose an alternative nonlinear approximation, combining a CRONE approximation of a fractional derivative with reset control, which does not suffer from these problems. An experimental proof of concept confirms the good results of this approximation and shows that nonlinear effects do not preclude the desired performance.

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The high tech industry which requires fast stable motion with nanometer precision continues to mainly use PID which is limited by fundamental linear control limitations. Floor vibrations as disturbance significantly affect performance and their rejection is particularly affected by these limitations. Reset control has provided a promising alternative to surpass these, while simultaneously allowing the use of industry standard loop-shaping during design. However, the reset action introduced higher order harmonics can induce unwanted dynamics and negatively influence performance. This paper investigates two reset control strategies namely (1) band-pass phase lag reduction and (2) phase compensation to reduce the negative effects of higher order harmonics. The strategies are tested on a precision positioning stage for vibration rejection and the results show that phase compensation provides better performance compared to other tested strategies.

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