This paper discusses axi-symmetric flow during CO₂ injection into a non-adiabatic reservoir accounting for Joule-Thomson cooling and steady-state heat exchange between the reservoir and the adjacent layers by Newton's law. An exact solution for this 1D problem is derived and a new method for model validation by comparison with quasi 2D analytical heat-conductivity solution is developed. The temperature profile obtained by the analytical solution shows a temperature decrease to a minimum value, followed by a sharp increase to initial reservoir temperature on the temperature front. The temperature distribution head of the front is determined by the initial reservoir temperature, while the solution behind the front is determined by the temperature of injected CO₂. The analytical model exhibits stabilisation of the temperature profile and the cooled zone. The explicit formula for temperature distributions allows determining the maximum injection rate that avoids hydrate formation.

We develop a method based on concept of exergy-return on exergy-investment (ERoEI) to determine the energy efficiency and CO₂ footprint of polymer and surfactant enhanced oil recovery (EOR). This integrated approach considers main surface and subsurface elements of the chemical EOR methods. The main energy investment in oil recovery by water injection is mainly related to circulation of water with respect to exergy of the oil produced. At large water cuts of >90%, more than 70% of the total invested energy is spent on pumping the fluids. Consequently, production of barrels of oil is associated with large amounts of CO₂ emission for mature oil fields with large water cuts. Our analysis shows that injection of polymer increases the energy efficiency of the oil recovery system. Because of additional oil (exergy gain) and less water circulation (exergy investment), the project-time averaged energy invested (and consequently CO₂ emitted) to produce one barrel of oil from polymer flooding is less than that of the water flooding at large water cuts. We conclude that polymer injection into reservoirs with high water cut can be a solution for two major challenges of the transition period: (1) meet the global energy demand via an increase in oil recovery and (2) reduce the CO₂ footprint of oil production (more and cleaner oil). For surfactant-polymer EOR, the extent of improvement in energy efficiency depends on the incremental gain and the simplicity of the formulations.

An understanding of how CO2 foam flows through a reservoir rock is useful for many subsurface applications, including enhanced oil recovery and CO2 storage. There are economic and environmental benefits in identifying surfactants that exhibit good foaming behavior with CO2 at both low concentrations and high foam qualities. Core flood experiments have been carried out to investigate the behavior of supercritical CO2 foams flowing through a high-permeability Indiana Limestone. The foaming behavior and concentration response of two surfactants, a betaine and a sultaine, were investigated. For the two surfactants, the transition foam quality and the maximum apparent foam viscosity both decreased with reducing surfactant concentration. A comparison between the foaming behaviors of these surfactants with CO2 and N2 was also carried out. It was found that the N2 generated stronger foam at low foam qualities, but the CO2 was better at maintaining good foaming behavior at high foam qualities.

A method based on the concept of exergy-return on exergy-investment is developed to determine the energy efficiency and CO₂ intensity of polymer and surfactant enhanced oil recovery techniques. Exergy is the useful work obtained from a system at a given thermodynamics state. The main exergy investment in oil recovery by water injection is related to the circulation of water required to produce oil. At water cuts (water fraction in the total liquid produced) greater than 90%, more than 70% of the total invested energy is spent on injection and lift pumps, resulting in large CO₂ intensity for the produced oil. It is shown that injection of polymer with or without surfactant can considerably reduce CO₂ intensity of the mature waterflood projects by decreasing the volume of produced water and the exergy investment associated with its circulation. In the field examples considered in this paper, a barrel of oil produced by injection of polymer has 2–5 times less CO₂ intensity compared to the baseline waterflood oil. Due to large manufacturing exergy of the synthetic polymers and surfactants, in some cases, the unit exergy investment for production of oil could be larger than that of the waterflooding. It is asserted that polymer injection into reservoirs with large water cut can be a solution for two major challenges of the energy transition period: (1) meet the global energy demand via an increase in oil recovery and (2) reduce the CO₂ intensity of oil production (more and cleaner energy).