Our aim with this work was to evaluate how the thermoplastic resin used in the composite adherends and on the energy director affected the static ultrasonic welding process in both parallel and misaligned configurations. Polyetheretherketone (PEEK) and low-melt polyaryletherketone (LMPAEK) were the resins used and their thermomechanical properties were characterized via dynamic-mechanical analysis and modulated differential scanning calorimetry. With parallel adherends, neither the welding time nor the through-thickness heating in the adherends vary significantly. This similarity was attributed to a larger heat capacity of the PEEK energy director counterbalancing its higher viscoelastic heating rate. With misaligned adherends, the welding time was larger for PEEK welds than for LMPAEK welds and LMPAEK adherends presented a larger though-thickness heating. These effects were attributed to the larger bulk viscoelastic heating rate of carbon fibre reinforced/LMPAEK adherends adding up to the lower heat capacity of LMPAEK.

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Accelerated laboratory testing is essential to understand the rain erosion behavior of coated samples applied to the leading edge surface of a wind turbine blade. This study investigates the impact of droplet impact frequencies and dry intervals on the incubation time for damage on polyurethane-coated samples using a Pulsating Jet Erosion Tester (PJET). A novel theoretical model for water slug volume is introduced, allowing for a more accurate comparison across different impact velocities and frequencies. The effect of dry intervals on coating performance is quantified, revealing that longer dry intervals and shorter pre-dry rain exposure can significantly increase the number of impacts a coating can withstand before damage. The study challenges the traditional continuous impingement testing by demonstrating that dry intervals can extend incubation time by a factor of three to five. Additionally, this paper proposes a recalibrated approach to PJET testing, which better mimics the cyclic nature of real-world rainfall, leading to improved predictive models for material degradation. The findings emphasize the importance of considering the visco-elastic behavior of coatings and the role of intermittent rain exposure in erosion testing, offering invaluable insights for designing future PJET test parameters.

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Structural reuse is a promising alternative to recycling of composite materials; it preserves material composition while liberating the materials for reuse in secondary applications. Thermoplastic reinforced composite materials have the potential to expand reuse opportunities by adapting their shape, or reversing them to a laminate blank. In this study, we evaluated reverse forming of glass fibre-polypropylene (GF-PP) laminates by developing a processing method, testing material properties and the effect of three design parameters: forming strain, laminate architecture and material type. Forming strain relates to the deformation mechanism of inter-ply slip, and is imposed through varying the contour depth and bending radius. Laminate architecture relates to resin redistribution, and is imposed by using an orthogonal as well as quasi isotropic layup. Finally, the material type affects both Inter-ply slip as well as resin redistribution, and is imposed by using plain and twill weaves. GF-PP blanks were prepared using a heated platen press and subsequently formed and flattened using convection heating (<165 °C) and vacuum pressure in a novel moulding process. The samples had typical values for flexural strength of 91 - 113 MPa and flexural modulus of 9–16 GPa. Using a Design of Experiments analysis the process was deemed robust for the given boundary conditions. These results demonstrate the feasibility of reverse forming for cases where inter-ply slip is the governing deformation mechanism. The presented reverse forming process and design parameters can be used to create new thermoplastic composite parts, anticipating for structural reuse through reverse forming.

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This article discusses results from an international contest, open for university student teams (bachelor and master), involving the design, construction, and testing of small wind turbines in a large wind tunnel. The wind tunnel has an outlet of 2.85 x 2.85 m allowing a maximum rotor swept area of 2 m2 without significant tunnel effects. Both horizontal and vertical axis wind turbines are part of the competition. The turbines are evaluated by an external jury of industry experts based on criteria such as Annual Energy Production, cut-in wind speed, innovations, design, and sustainability. Although the contest has been initiated in 2013 with an educational focus, it has also evolved into a valuable database for scientific purposes by providing a decade worth of performance measurements for roughly 9-10 various turbine concepts each year. The collected data may serve as a unique validation resource for assessing the accuracy of design codes in modelling diverse turbine concepts thanks to detailed design reports with model descriptions accompanying each turbine (such turbine descriptions are often considered confidential for field measurements). The paper aims to explore the scientific value of this database by comparing calculations with measurements, offering explanations where possible, and reporting intriguing findings on unconventional concepts' performance. Even though not all observations could be explained fully they provide food for thought. Recommendations are provided for both students to enhance their designs and for contest organizers to elevate the scientific value of the measurements in future contests.

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This study considered adhesion between thermoplastic and thermoset laminates through interdiffusion at the interface. The influence of the degree of cure of the thermoset at the start of the process was investigated through mechanical testing and microscopy. Increasing the initial degree of cure decreased both interlaminar fracture toughness and interphase thickness. Fracture toughness decreased disproportionately to interphase thickness, attributed to changes in interphase morphology and decreasing surface contact at the interface. A simplified model was developed using gel layer thickness measurement data to predict the level of interdiffusion with increasing initial degree of cure. Compared to thermoset-thermoset co-curing, there was superior bond strength at low initial degrees of cure and a predicted increased sensitivity to the initial degree of cure, suggesting a greater influence of process variability. Hence, for specific property critical applications, the trade-off between the potential manufacturing efficiency gains from semi-curing and the reduced performance would be an important consideration.

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In this study, a gap filling methodology was used to evaluate the flow behaviour of carbon fibre reinforced polyphenylene sulphide (CF/PPS) tapes under various compaction conditions (force and time) and layups. At each side of the gap, a different layup was present: 0/0 and 0/90. It was observed that squeeze flow occurred under all compaction forces and times, increasing with them. The layup influenced the squeeze flow development significantly, particularly visible in the change of the 0° fibre angle of the substrate across the gap. This fibre angle increased from the 0/90 to the 0/0, as the latter showed more squeeze flow than the former due to the parallel layup. The change of fibre angle across the substrate’s width was indicative of the extent of the squeeze flow along its width. The percolation flow increased with compaction force and time, and both longitudinal and transverse flow were found. Longitudinal flow was visible at larger compaction forces, whereas transverse flow was the only flow found at lower ones. The development of transverse over longitudinal percolation flow is influenced by the layup, the sample configuration and the squeeze flow.@en

A common approach to toughen epoxy matrix systems is to dissolve a thermoplastic phase, in the uncured thermosetting monomers. These can interdiffuse within the thermoplastic, followed by reactioninduced phase separation, leading to intricate graded morphologies with a high fracture toughness. Here, we first architect the thermoplastic phase, made of poly(etherimide) films as a macroscopic layered scaffold, and infiltrate it by an epoxy system, leading to dual-scale morphologies with distinct spatial control of morphological feature at the microscopic and macroscopic scale. The fracture toughness of the modified epoxy system is investigated as a function of varying cure temperature (120–200 °C) for interphase formation and poly(etherimide) film thickness (50–120 μm). Results show that the fracture toughness of the heterogeneous system is mainly controlled by the macroscopic feature, the final PEI layer thickness. Remarkably, as the PEI layer thickness exceeds the plastic zone around the crack tip, around 60 μm, the fracture toughness of the dual scale morphology surpasses the property of bulk PEI. Additionally, decreasing the gradient microscale interphase morphology triggers higher crack tortuosity, which seems to be the dominating mechanism for the synergistic toughening. Ultimately, this knowledge will lead to novel toughening approaches to increase the damage tolerance of fibre reinforced composites by suppressing delamination damage modes.@en

This work studies the effect of compaction of tapes that have been heated using a laser during automated fibre placement. The deconsolidation has been shown to have a significant effect on the surface roughness, degree of effective intimate contact and void content. This work investigates whether after compaction the as-received (i.e., before heating) properties are obtained, or whether the deconsolidationcompaction cycle has an influence on the final tape quality. First, a lab test set-up is designed and manufactured to mimic the real manufacturing conditions. Next, the set-up is used to study the influence of the placement speed and pressure on the final quality. The results show that the effects of deconsolidation are mostly reversed, but the final tape still has slightly worse qualities. This effect will have to be taken into account for accurate modelling of the laser-assisted automated fibre placement process.@en

This paper presents the results of a collaborative project initiated by first year teaching staff and study counsellors within the Aerospace Engineering Bachelor’s programme at Delft University of Technology aimed at tackling the challenge of stimulating critical self-reflection and coping with failure. This project took the concept of a study planner and reflection journal and turned it into a symbol synonymous with learning from failure – the aircraft Flight Data Recorder. This symbol was combined with animated storytelling to introduce and explain the purpose and function of the Student Flight Data Recorder (SFDR), after which the usage of the resource was scaffolded by student mentors. Acknowledging that some students would not feel compelled to use a resource that was not required, a moment of intervention was offered at the completion of the first academic quarter after the first round of final exams. Overall, the project team has observed that the project has created more awareness and discussion about these topics within the student population. The next step in the project is to add an educational researcher to the project team with the intent of carrying out quantitative research into the effectiveness of the tool.

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This paper evaluates the potential of changing the welding force and the compliance of the energy director (ED) to reduce the effects caused by misaligned adherends, which were: increased through-thickness heating, reduced size of welded area and increased heating time. In the methodology that was followed, we welded adherends misaligned by approximately 4.5° in different scenarios: with higher welding force; with increased ED compliance by the use of a thicker ED and; with increased ED compliance by the use of a discontinuous ED. The most significant reduction of the effects caused by misaligned adherends was obtained when combining the use of both increased welding force and discontinuous ED. Such improvement derives from the imposed parallelism caused by the use of a higher welding force and from a more efficient concentration of heat generation at the weld line that occurs when a discontinuous ED is used.

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A fiber-reinforced composite wind turbine blade (WTB) is exposed to numerous impact threats during its service life causing damages that can be detrimental to its structural integrity. Currently, impact loads are not considered during blade design, so high safety factors are introduced, which result in a conservative design. However, as wind turbine blades become stiffer and lighter and health monitoring systems become more sophisticated, the design process is shifting toward damage-tolerant approaches. The design philosophy accepts damages to the structure, but it also requires that the damaged blade still meet structural and functional requirements. This design procedure requires a comprehensive understanding of different impact threats and their characteristics, which is currently unavailable in the public domain. This paper is a first attempt to review the impact loads on composite wind turbine blades. The aim of the current paper is to (a) identify different sources of impact threats on wind turbine blades during different stages of their service life, (b) describe their qualitative (causes and vulnerable regions) as well as quantitative characteristics (size, mass, and velocity of impactor), and to (c) provide modeling guidelines by comparing these impact threats using five different criteria - (i) relative deformability of projectile and wind turbine blade, (ii) impact velocity, (iii) kinetic energy of impact, (iv) repeatability of impacts and (v) nature of the impact. The review paper will be of special interest to researchers working on wind turbine blades and will serve as a baseline report for designing damage-tolerant blades. Recommendations are also provided for future research.

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Continuous ultrasonic welding is an attractive welding technique for thermoplastic composite structures. In this process, a metallic sonotrode connected to a piezoelectric transducer and to a press moves along the parts to be welded applying ultrasonic vibrations and a static welding force on the welding overlap. Thus far, the research carried out on this topic makes use of sonotrodes featuring a flat contact surface with the parts to be welded, which limits the use of the process to the welding of overlaps with no curvature in the welding direction. With the final aim of assessing whether this process can also be applied to curved structures, this paper explores the feasibility of using a rounded sonotrode for continuous ultrasonic welding of thermoplastic composites. The main conclusions drawn from the results obtained in this research is that it is indeed possible to continuously weld thermoplastic composite panels with a rounded sonotrode and that high-quality welds can be obtained from such a process. Furthermore, the use of a rounded sonotrode has the positive effect of lowering the temperatures at the welding interface as well as the temperatures within the adherends. On the other hand, the use of such sonotrode leads to a decreased, although still competitive, welding speed and, potentially, an increased welding force, thereby setting boundary conditions that need to be considered for each specific application.@en

Toughness of epoxies is commonly improved by adding thermoplastic phases, which is achieved through dissolution and phase separation at the microscale. However, little is known about the synergistic effects of toughening phases on multiple scales. Therefore, here, we study the toughening of epoxies with layered poly(ether imide) (PEI) structures at the meso- to macroscale combined with gradient morphologies at the microscale originating from reaction-induced phase separation. Characteristic features of the gradient morphology were controlled by the curing temperature (120–200 °C), while the layered macro structure originates from facile scaffold manufacturing techniques with varying poly(ether imide) layer thicknesses (50–120 μm). The fracture toughness of the modified epoxy system is investigated as a function of varying cure temperature (120–200 °C) and PEI film thickness (50–120 μm). Interestingly, the result shows that the fracture toughness of modified epoxy was mainly controlled by the macroscopic feature, being the final PEI layer thickness, i.e., film thickness remaining after partial dissolution and curing. Remarkably, as the PEI layer thickness exceeds the plastic zone around the crack tip, around 62 μm, the fracture toughness of the dual scale morphology exceeds the property of bulk PEI in addition to a 3 times increase in the property of pure epoxy. On the other hand, when the final PEI thickness was smaller than 62 μm, the fracture toughness of the modified epoxy was lower than pure PEI but still higher than pure epoxy (1.5–2 times) and “bulk toughened” system with the same volume percentage, which indicates the governing mechanism relating to microscale interphase morphology. Interestingly, decreasing the gradient microscale interphase morphology can be used to trigger an alternative failure mode with a higher crack tortuosity. By combining facile scaffold assemblies with reaction-induced phase separation, dual-scale morphologies can be tailored over a wide range, leading to intricate control of fracture mechanisms with a hybrid material exceeding the toughness of the tougher phase.@en

This paper presents the results of a collaborative project initiated by first year teaching staff and study counsellors within the Aerospace Engineering Bachelor’s programme at Delft University of Technology aimed at tackling the challenge of stimulating critical self-reflection and coping with failure. This project took the concept of a study planner and reflection journal and turned it into a symbol synonymous with learning from failure – the aircraft Flight Data Recorder. This symbol was combined with animated storytelling to introduce and explain the purpose and function of the Student Flight Data Recorder (SFDR), after which the usage of the resource was scaffolded by student mentors. Acknowledging that some students would not feel compelled to use a resource that was not required, a moment of intervention was offered at the completion of the first academic quarter after the first round of final exams. Overall, the project team has observed that the project has created more awareness and discussion about these topics within the student population. The next step in the project is to add an educational researcher to the project team with the intent of carrying out quantitative research into the effectiveness of the tool.@en

Laser-assisted tape placement (LATP) and thermoplastic composites (TPCs) pre-impregnated (prepreg) tapes are a promising combination of technologies; given the in-situ capabilities of the TPCs and the high degree of automation achievable with LATP. However, laminate quality, measured as final void content, tends to decrease when increasing placement speed. Heating and consolidation windows in LATP of TPCs are very short, especially when increasing the placement speed. For TPCs, resin flow is heavily influenced by melt viscosity above melting temperature (Tm). Therefore, the degree of intimate contact (Dic) resulting from the compaction phase can be significantly influenced by the tape’s degree of melt at the end of the heating phase. Due to melting being a kinetically controlled process[1,2], both temperatures and times above Tm need to be considered. The relationship between the degree of melt, both through thickness and in time, prior to compaction and the final Dic has not been explored yet. In this study, the final Dic and degree of melt of a CF/PEEK tape as a function of heating power, heating length and placement speed will be evaluated and correlated. The experimental investigation will consist of calorimetric data on melting kinetics of the polymer, and LATP experiment runs with different process parameters. Simulations of the thermal history (see Figure 1) and melting in the heating phase will be performed and validated with experiments. The research aims to understand the melting behaviour of the tapes during the heating stage in LATP, its dependence on the process parameters, and how it affects the final Dic and laminate quality. @en

Epoxies with high cross-linking densities are brittle and hence have a low fracture toughness. However, different methods are known to increase fracture toughness. Numerous approaches are known to incorporate a second phase into the epoxy matrix, such as rubber, inorganic nanoparticles or thermoplastics, referred to as bulk resin modification. These tougheners usually form specific morphologies during the curing phase of epoxy, resulting in improved fracture toughness of the system. Unfortunately, for some tougheners, the addition of second phase into the epoxy system also results in a reduction in overall modulus and limitation in end-use temperature of the system. In the case of thermoplastic tougheners, the second phase is created by diffusion and dissolution, followed by reaction induced phase separation, leading to a morphology in the micrometer range. However, the influence of the curing history beyond phase separation, using two dwell cure cycles with varying dwell time/degree of cure, on the interphase dimension and final morphology for PEI having a contrasting phase behaviour (UCST), is not well understood. The research presented in this work aims to understand the interphase formation, to later attain the desired droplet size and interphase morphology for improved material toughness. This aim is achieved by analyzing the influence of dwell time by considering two main cases for each selected 1st dwell temperature (120-180˚C): (i) wait until the onset of phase separation (OPS) before increasing the temperature to 200°C (second dwell), (ii) wait until 80% degree of cure (80% DOC) before the second dwell. At all processing temperatures, a distinct gradient morphology (Fig. 1a ) was clearly observed for both cases (OPS and 80% DOC). The SEM micrographs revealed the formation of a larger interphase region (71 μm) for the OPS case as compared to the 80% DOC case (56 μm). Figure 1b shows the interphase thickness as a function of 1st dwell temperature for both OPS and 80% DOC cases. It can be seen that the interphase thickness increased with 1st dwell temperature for both cases, until 160˚C after which it slightly decreased for a 1st dwell temperature of 180˚C. This work highlights, i) the importance of the curing process beyond phase separation to control interphase dimension and final morphology and, ii) the influence of both these parameters on the toughness enhancement. @en

Continuous ultrasonic welding is a promising high-speed and energy-efficient joining technique for thermoplastic composite structures. However, in the current state-of-the-art research on the topic numerous deconsolidation voids could be identified at the welding interface, which results in a strength knock-down. The aim of this study is, therefore, to improve the quality of continuous ultrasonically welded joints by adding a consolidation shoe to the welding setup. To determine the required consolidation pressure, the size of the shoe, and its distance from the sonotrode a stepwise approach was followed based on the static ultrasonic welding process. The closest consolidation distance, best representing the static welding conditions, did not improve the weld quality as significant porosity was still found in the weld line and in the adherends. However, for the furthest consolidation distance high-quality continuous welds were obtained with almost no porosity and a high strength.@en

Ultrasonic welding is a promising joining technique for thermoplastic composite parts. On the way towards upscaling and industrialisation of this technology, it is crucial to understanding how it is affected by manufacturing tolerances. The objective of the research presented in this paper was to investigate the influence that misaligned adherends have on static ultrasonic welding of thermoplastic composites. Different angles were created by changing the clamping configuration. The results showed that increasing the angle between adherends decreases the power consumed and increases the process time while decreasing the weld uniformity and increasing the risk of overheating. These effects were associated to the impact of the different clamping configurations on the cyclic strain in the energy director and adherends during the welding process. Decreasing the top adherends bending stiffness by increasing the clamping distance was found to significantly reduce the adverse effects of adherend misalignment on weld quality.

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This study presents two novel methods for in situ characterization of the reaction-diffusion process during the co-curing of a polyetherimide thermoplastic interlayer with an epoxy-amine thermoset. The first method was based on hot stage experiments using a computer vision point tracker algorithm to detect and trace diffusion fronts, and the second method used space-and time-resolved Raman spectroscopy. Both approaches provided essential information, e.g., type of transport phenomena and diffusion rate. They can also be combined and serve to elucidate phenomena occurring during diffusion up to phase separation of the gradient interphase between the epoxy system and the thermoplastic. Accordingly, it was possible to distinguish reaction-diffusion mechanisms, describe the diffusivity of the present system and evaluate the usability of the above-mentioned methods.

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In the immediate future, wind power will provide more electricity than any other technology based on renewable and low-emission energy sources. As a result, the size of offshore wind turbines has increased to harvest more wind energy in order to achieve the 2050 EU carbon neutral targets. The use of composites opens great prospects in the design and manufacture of the wind turbine blades due to their optimization versatility but composites perform poorly under impact and are sensitive to environmental factors. To combat this, blade manufacturers employ polymer-based surface coatings, caps or tapes to protect the composite structure. However, it is the repeated impact of rain droplets combined with the high blade tip speed, which are mostly contributing to the erosion of wind turbine blades [1]. The hindering of leading-edge erosion could be obtained through its multilayer material optimization i.e. Leading Edge Protection LEP [2]. Both the surface erosion and the intra-layer adhesion are affected by the shock wave propagation through the thickness of the LEP system produced from the collapsing water droplet after impact [3]. It is necessary to increase the interfacial fracture toughness resistance of the multy-layered system from the surface to the interface boundaries to damp the surface damage and avoid subsurface delamination [4]. Therefore, validated models considering the developed multicomplex stress states and the material degradation due to environmental loads are required for design purposes toward anti-erosion protection performance. This investigation summarizes the review of the current literature conducted in the framework of the IEA Wind TCP (International Energy Agency Wind Technology Collaboration Programme) - Task 46 Erosion of wind turbine blades [5]. It focuses on two main issues: firstly, the LEP material configuration used in industry considering the blade integration technology and, secondly, the modelling techniques and numerical procedures currently used to predict both wear surface damage and interface delamination failure. This work will allow for the identification of gaps within the research that can be explored during IEA Wind Task 46. @en