Summary Microfluidic two-phase flows are increasingly being used in many mass transfer applications because of the numerous advantages of operating in the microscale such as stability of the interface and low cost. Such two-phase flows have multiple applications in various fields such as medicine, metal extraction, chemistry, oil and gas, and handling of industrial effluents. It is particularly important in both the transport and extraction of substances from one fluid to another fluid. The main reasons for this are the short diffusion distances and large surface-volume ratios when using multiple chips in parallel.

Among the various flow regimes, parallel flow in the microscale is considered to be advantageous for extraction applications, especially radioisotope transfer. In this regime, the two fluids move parallel to each other in a microfluidic channel. If the fluid-fluid interface remains stable throughout, efficient transfer is possible without necessitating a step to separate the two fluids. This benefit offered by microfluidics is very important for radioisotopes with short half-lives, as the absence of a separation step ensures that radioisotopes can be transferred efficiently in a quick time, thereby maximizing their utility for different applications such as pharmaceuticals.

However, stable parallel flow is hard to achieve as it is contingent on several factors. In a microfluidic channel with two inlets, a rectangular main channel and outlets, the ideal scenario for efficient mass transfer involves a stable fluid-fluid interface to be located exactly in the middle of the rectangular channel, followed by the two fluids flowing to their respective outlets without any fluid leaking to another outlet. Considering the utility of such a regime, it is important to study the underlying flow phenomena which govern the regime and leakage. This thesis, therefore, focuses on using simulations and experiments to study parallel flow in microfluidic channels, followed by an analysis of the mass transfer when using such a regime for radioisotope extraction...@en

Over the next couple of decades, the world will face the challenge of drastically reducing carbon emissions. Innovative Generation-IV nuclear reactor designs can play an important role in driving this energy transition. One of these designs is the Molten Salt Fast Reactor (MSFR), characterized by a fast neutron spectrum and the use of a liquid fuel. Because of the liquid fuel, melting and solidification phenomena need to be considered. To this end, this thesis presents a combined experimental and numerical investigation of melting and solidification phenomena in the MSFR. The experimental part was primarily motivated by the lack of suitable experimental data for the transient development of an ice-layer in internal flow, which is a relevant case for the analysis of accident scenarios in a MSFR where solidification may pose a risk. The main focus of the numerical part was to improve the computational efficiency of current state-of-the-art melting and solidification models.

As part of the experimental investigation, a new experimental facility (ESPRESSO) was designed and built. The ESPRESSO facility consists of a water tunnel capable of reaching both laminar and turbulent flow rates, in which ice is grown from a cold plate at the bottom of a square channel. The ESPRESSO facility was designed to have well-described experimental boundary conditions, through careful consideration of the inflow and cold-plate specifications. Subsequently, experimental data was generated for the transient development of an ice layer in laminar internal flow using particle image velocimetry (PIV), which may be used for numerical validation. The onset of ice formation was found to coincide with a sudden increase of the cold-plate temperature, which was therefore used to identify the zero time instant in our experiments. This was attributed to subcooling effects prior to nucleation, of which evidence was obtained using laser induced fluorescence (LIF) temperature measurements.

In addition, non-intrusive temperature measurements have been performed for the transient development of an ice layer in laminar channel flow using LIF, which is so far only the second application of LIF as a non-intrusive temperature measurement technique in solid-liquid phase change experiments. The LIF method presented in this thesis is a novel approach for solid-liquid phase change experiments because of the use of a two color (instead of a one color) technique, the use of a post-processing algorithm to remove top to bottom striations and reduce other measurement noise, and a detailed analysis of the uncertainty in the temperature fields. Good results were obtained for sufficiently large temperature differences of approximately C with an uncertainty of σ=0.3-0.5 °C, however further improvements are needed to remove artefacts as a result of laser light scattering from the solid-liquid interface, and to obtain a sufficiently high accuracy for numerical validation purposes, especially for smaller temperature differences.

The numerical work performed as part of this thesis aims to address the need for more efficient melting and solidification models, which can accurately capture the solid-liquid interface and resolve the recirculation zones in the fluid region at a lower computational cost. To this end, an energy-conservative DG-FEM approach based on the `linearized enthalpy melting/solidification model' was developed and validated. Although certain solid-liquid phase change problems with strong gradients in the flowfield can benefit from the use of the higher order DG-FEM method, overall a suboptimal O(h) mesh convergence rate was obtained due to an inaccurate numerical solution of the discontinuities at the solid-liquid interface. Therefore, further development of the DG-FEM solid-liquid phase change solver is needed to fully benefit from the arbitrarily high order of accuracy of the hierarchical polynomial basis function set.

Very promising results were obtained with a parallel finite volume adaptive mesh refinement method for solid-liquid phase. Cells were refined based on the maximum difference in the liquid fraction over the cell faces and the estimated numerical discretization error in the flow and temperature fields, using the cell residual method. With this approach, a very good agreement was obtained between the adaptive mesh results and the reference solutions on a uniformly refined grid with significantly less degrees of freedom. This demonstrates the potential of the proposed finite volume adaptive mesh refinement approach as a more computationally efficient numerical method for solid-liquid phase change problems.

The final part of this thesis details a five-stage benchmark for modelling phase change in molten salt reactors, modelled after the MS(F)R freeze-valve design. With each stage, an additional layer of complexity is added, which enabled the identification of potential sources of discrepancy between different numerical modelling approaches. Results were obtained with three different codes: STAR-CCM+, OpenFOAM and DGFlows (inhouse DG-FEM based code for computational fluid dynamics). The results from the benchmark showed an overall good agreement between the three codes, although some discrepancies were observed when adding conjugate heat transfer effects. Therefore, we recommend some caution when coupling different solid-liquid phase change and conjugate heat transfer modelling approaches.

To summarize, this thesis presents new experimental data for the transient ice-growth in laminar internal flow, driven by a general lack hereof. In addition, this thesis illustrates the potential of LIF as a non-intrusive temperature measurement technique for solid-liquid phase change experiments. Two new numerical methods were developed and validated for solid-liquid phase change problems, and especially the finite volume adaptive mesh refinement approach showed promising results in terms of enhanced computational efficiency. On a final note: solid-liquid phase change is a vast and ongoing field of research. We believe this thesis is a substantial addition to the field, yet there are still a lot of opportunities for future work. Some suggestions are given in the concluding chapter.
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Dredging is an energy-intensive operation and, due to the nature of the process, there are large and rapid fluctuations in the power requirement. With the signing of the Paris Agreement, implementation of IMO 2020 and expansion of ECAs, the external pressures for the reduction of different emissions(CO2, SO_x, PM, and/or NO_x) in dredging are rising. Additional motivating factors are the rise in the fuel expenses which form a major component of dredging project costs and the incentives from regulatory authorities to reduce the carbon intensity in dredging operations. Often, the achievement of one objective leads to deterioration of another, for example, the use of IMO-compliant fuel can increase the overall carbon emissions. In recent years, alternative fuels like LNG and biofuels have been explored. However, they suffer from their own set of issues and with the predicted trends, the usage of these alternative fuels would imply lower production and earnings, especially in large dredging projects. In this work, a marine power plant concept that has been rarely discussed in the context of dredging is explored and forwarded: a nuclear-based system. Fundamentally, such a power plant addresses the issues related to the emissions and essentially eliminates bunkering stops. This was the first study focused on nuclear-powered Trailing Suction Hopper Dredgers (TSHD), the most common type of dredging vessel. In this work, a system-level study was carried out to ascertain the retrofittability of a nuclear-based system on four existing TSHDs. The feasibility of retrofitting the nuclear-based system has been studied by comparison of mass and volume requirements of the nuclear power plant, with the mass and volume of the engine and fuel storage system of current dredging vessels. No re-design of the vessel was considered here.The ”inherently safe” High Temperature Gas-cooled Reactor (HTGR) with Nuclear Air-Brayton Cycle (NABC) was determined as the nuclear power system of choice. It appeared that for such a system,the TSHD sizes that are interesting for the deployment starts around 12000 m³ hopper capacities.The bigger the hopper capacities than this baseline, the better the nuclear system performed. It was found that despite the satisfaction of the mass and volume constraints, a redesign of the TSHD is required for the placement of the reactor and for the compliance with the nuclear related regulations.In addition to the nuclear power plant, the retrofitting of the TSHDs with Proton Exchange Membrane Fuel Cell (PEMFC) in combination with solid, compressed and liquid H₂ storage and batteries was considered. With the current commercially available offerings, PEMFC with liquid or 500 bar compressed H₂ storage were found to be suitable for maintenance dredging or capital dredging for a short duration(couple of days). However, it was established that the realisation of endurance level of current dredgers is not possible without a reduction of hopper capacities or factorial increase in energy density of storage. Further, the smaller TSHDs were found to be better suited to use PEMFC or battery-based systems.A part of this work also tried to answer the pertinent question of the third party liability insurance premiums for a nuclear-powered vessel and the regulations such a ship would be subjected to. Further, a preliminary business case was developed and the sustainability of the concept was evaluated. It was realised that the technological forces and trends like the development of Small Modular Reactors, deep-sea mining and autonomous ships, could favour the development of a fleet of nuclear-powered dredging vessels in the future. However, the regulations and the support for these vessels would be highly dependent on the flag country and operational location.