The use of non-destructive tests for assessing the material status of concrete structures in the Netherlands remains relatively uncommon, despite the growing demand for the preservation of existing structures under the VenR policy of Rijkswaterstaat. Skepticism towards NDTs is reflected in the scarcity of documented case studies in publicly available literature and in the absence of rules and guidelines.

In this research, following an extensive literature review on the current state of assessing the material status of reinforced concrete structures using NDTs, a large-scale non-destructive inspection was carried out on the Sluinerweg viaduct. The research aimed to address the practical challenges associated with these methods. These challenges serve to formulate a practical methodology to facilitate future inspections. Limitations include the use of specific NDTs: GPR, UPE, rebound hammer, UPV, half-cell potential, resistivity, and corrosion current density. Following the inspection, a data analysis was conducted, accompanied by a destructive verification of the methods.

The integration of GPR with UPE technology showed promise for tendon duct inspections. However, a 12 mm borehole used for destructive verification proved to be too small to make accurate judgments. Additionally, the absence of grouting defects made evaluation of the method challenging. GPR provided a more accurate estimation of the cover depth compared to previous measurements conducted on the Sluinerweg viaduct using a standard cover meter. However, it was impossible to measure through the cathodic protection coating. The data's correlation with the provided drawings is promising, especially given that drawings are often unavailable. The key finding regarding the estimation of compressive strength using the rebound hammer and UPV is the strong recommendation to avoid using SonReb models unless they are specifically calibrated for the structure under inspection. No active corrosion sites were found, which posed challenges to evaluating the methods. Resistivity values measured using the Proceq Resipod consistently showed lower readings than those obtained with the Gecor-10 Wenner probe. A laboratory investigation ruled out moisture content as the cause. Fortunately, the differences are less pronounced with corroded reinforcement; however, further investigation is necessary. The previous inspection regimes in the Liggerkoppen project were found to be suboptimal in some aspects but were deemed reasonable considering the complexity of the project.

This research demonstrated the effectiveness of several NDTs in-situ, which should help to build trust in the reliability of these methods for future inspections. Based on the findings of this research, it is strongly recommended to conduct further large-scale inspections to improve the practical methodology, gain further experience and develop improved codes and guidelines. While there is still much to accomplish, Rijkswaterstaat's support for investigations such as the one conducted for the Sluinerweg viaduct demonstrates their commitment to a better future.

A long standing research field in material science has been the trade-off between strength and ductility of steels. Advanced High Strength Steels (AHSS) aim to combine these two properties and provide steels that can increase safety and lower CO2 consumption in automotive applications, by decreasing weight. To further decrease the environmental impact, novel quenched and partioned (Q&P) martensitic stainless steel is considered to prevent corrosion. Quenching and partitioning is a heat treatment that aims for a martensite/retained austenite microstructure with specific phase fractions to optimize strength and ductility. While mechanical properties are well researched for Q&P treated martensitic stainless steel, the corrosion properties are not that widely documented. This thesis aims to discover the influence of the microstructural development in terms of phase fractions due to the Q&P treatment, and the manganese content on the corrosion properties of martensitic stainless steel. Two alloys with chemical composition 0.2C-12.5Cr-0.35Si-XMn, where X stands for 0.7 for the low manganese alloy, and 3 for high manganese alloy, are considered for this study, and are compared to a commercial AISI 420 martensitic stainless steel. The microstructure was investigated by the use of optical microscopy, energy dispersive X-ray spectroscopy (EDS), electron probe microanalysis (EPMA), scanning Kelvin probe force microscopy (SKPFM). This was combined with electrochemical experiments including Open-circuit potential measurements, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). When compared to commercially available AISI 420 martensitic stainless steel, the novel Q&P MSS showed improved corrosion properties. This can mainly be attributed to the lack of chromium rich carbides (Cr23C6 or Cr7C3) in the Q&P treated MSS. However, this improvement in corrosion properties was only observed for the samples with low manganese content. The increase of fraction retained austenite did show an increase in corrosion potential, making the steel more cathodic, but the improvements in terms of pitting potential and passive film properties are limited. Samples with high fresh martensite fractions also showed an increase in corrosion potential, but only marginally increased in terms of length of the passive region. EIS data shows that the addition of fresh martensite reduces the passivity properties of the material. Volta-potential measurements done by SKPFM showed a clear difference between primary martensite and fresh martensite of up to 20mV and were overlapping with the topography maps. This can be an indication of increased tendency to form micro-galvanic cells between martensite phases. Manganese was found to be detrimental for the corrosion properties of the Q&P treated MSS. A clear drop in the length of the passive region shows that the high manganese samples are more susceptible to pitting. EDS measurements and EPMA elemental distribution maps showed local zones of decreased chromium and increased manganese and silicon. This indicates that there are secondary phase particles present in the material in the form of manganese silicide or manganese sulfide. Volta-potential measurements done by SKPFM showed these particles behave more anodic in comparison to the matrix of the material. The number of particles per unit area was increased for the samples with high manganese content. These inclusions greatly reduce corrosion performance, showing that the addition of manganese is detrimental for corrosion performance. Several other microstructural features are discussed in terms of influence on the corrosion performance of the material. Which include prior austenite grain boundaries, elemental banding of chromium and manganese and Volta-potential differences between martensite laths.