Thin films of the high-temperature superconductor YBa₂Cu₃O(7-δ) exhibit both a large critical current (the superconducting current density generally lies between 10 and 10 A m^-2 at 4.2 K in zero magnetic field) and a decrease in such currents with magnetic field that point to the importance of strong vortex pinning along extended defects. But it has hitherto been unclear which types of defect - dislocations, grain boundaries, surface corrugations and anti-phase boundaries - are responsible. Here we make use of a sequential etching technique to address this question. We find that both edge and screw dislocations, which can be mapped quantitatively by this technique, are the linear defects that provide the strong pinning centres responsible for the high critical currents observed in these thin films. Moreover, we find that the superconducting current density is essentially independent of the density of linear defects at low magnetic fields. These natural linear defects, in contrast to artificially generated columnar defects, exhibit self-organized short-range order, suggesting that YBa₂Cu₃O(7-δ) thin films offer an attractive system for investigating the properties of vortex matter in a superconductor with a tailored defect structure.

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At low fluences, the [Sr]/[Ti] ratio of laser deposited SrTiO3 films appears to be a function of the laser fluence. The deviation from stoichiometry is remarkably constant in time. From an analysis of both the composition of the film and the irradiated target, we deduce a volume-diffusion-assisted preferential ablation process. At high fluences (above 1.3 J/cm2), stoichiometric SrTiO3 films are obtained. This is not due to a change in ablation mechanism, but follows from the fact that at 1.3 J/cm2 the calculated diffusion length of Sr within the irradiated target, becomes of the order of the ablation rate per shot.@en

High quality twin-free c-axis oriented YBa2Cu3O7-δ films were grown by pulsed laser deposition on NdGaO3. We find resistive anisotropies between 1 < ρa/ ρb < 1.6. The resistive anisotropy above Tc appears to be correlated to the anisotropy in the critical current below Tc. The normal state properties of the chains along b seem to have a significant influence on the superconducting properties of YBa2Cu3O7-δ.@en

YBa₂Cu₃O_7-δ films on SrTiO₃ are characterized by a network of anti-phase boundaries (APB's), protruding from the interface to the film surface. We propose that the island morphology of these films is to a large extent determined by this network. At APB-outcrops deep trenches form which separate the growth islands. At the cross-section of three APB's deep holes are formed. It is found that the growth island size can be increased by increasing the substrate temperature or the oxygen pressure during growth.

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A new method has been developed to synthesize compact yttriumtrihydride by making use of a thin film technique. For electrical measurements yttrium films of typically 500 nm thickness are covered under UHV conditions by a 5 nm thick palladium overlayer which consists of electrically disconnected islands. Loading of these films with hydrogen up to the trihydride phase can then be done ex-situ in a reasonably short time (around 20-40 h) by applying gas pressures of about 60 × 105 Pa. For a thicker Pd layer (above 20 nm) this time can be considerably shorter (t ∼ 125 s). The film morphology stays intact during the loading process although the film thickness increases by approximately 11% and the crystal structure changes from h.c.p. to f.c.c. and back to h.c.p. These samples are, therefore, very well suited for an investigation of the remarkable electrical and optical properties of trihydrides, as recently reported by Huiberts et al. (Nature, 380, 1996, 231). In this article we give evidence for the island structure of the palladium overlayer and make a comparison of a number of physical properties of yttrium and its related hydrides as thin films with literature values for the same material in bulk form. These properties include lattice parameters for the different hydride phases, electrical resistivity for yttrium and its dihydride and Hall coefficient for yttrium. The characteristics of the yttriumhydride thin films are very similar to those of bulk material. Furthermore, we performed concentration measurements and resistivity measurements during hydrogen loading. It is shown that the resistivity rises three orders of magnitude when yttrium is loaded up to the trihydride phase at 60 × 105 Pa.@en

We provide evidence that non-stoichiometric ablation of YBa₂Cu₃O_7-δ at low fluences is due to a phase separation of the target surface. On the other hand, in SrTiO₃ we find at low fluences evidence for preferential ablation which is assisted by volume-diffusion. As a result, the Sr/Ti ratio of the ablated films can be tuned by choosing the appropriate fluence.

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Low-electric-field E-js curves, normalized dynamical relaxation rate Q(T)=d ln(js)/d ln(E), and experimental critical current density js(E=Ec) were measured from 10 to 85 K with the magnetic sweeping method. By taking a general assumption for the activation energy U(js,T)=Uc(T)f[js(T)/jc(T)], with t=T/Tc, we obtained the U(j,T=0 K) relation by scaling all the E-js curves of different temperatures to one smooth curve with Uc(T) and jc(T) determined by the so-called generalized inversion scheme. It is shown that the important parameter c=ln(v0B), which was actually taken as a fitting parameter in the scaling process in previous work, can be predetermined. It is also found that the resulting U(j,T=0 K) relation based on the E-js curves for T 79 K can be well interpreted with the collective-pinning model. However, the data for T>79 K start to deviate from this interpretation, which may be attributed to the reverse hopping of vortices.

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Projection optics is a means to reduce the spatial energy density variations on the target during laser ablation. Using projection optics to study the interaction between a spatially uniform 248 nm excimer laser beam and a YBa2Cu3O6+x target we observe a well-defined threshold fluence of 1.0 J/cm2. Below this threshold non-stoichiometric ablation results in an dramatic change in target morphology and in a decay of the ablation rate. Above this threshold the stoichiometry of the target is conserved. The roughness of the deposited films increases along with the increase in roughness of the target above the threshold. Thus it is clear that in order to obtain flat stoichiometric films one should use a narrow fluence window just above the threshold.@en

Orientation dependent measurements of torque hysteresis loops on high quality laser-ablated YBa2Cu3O7-δ thin films were performed at a temperature of 30 K in magnetic fields up to 7 T. From these measurement we extract the field and orientation dependence of the in-plane critical current density Js(H,θ), where θ is the angle between the applied external magnetic field H and the plane of the film. Following the scaling arguments of Blatter, Geshkenbein and Larkin based on the anisotropic Ginzburg-Landau theory, we have been able to scale the measured Js(H, θ) into a form ∫(ε{lunate}(θ)H), where ε{lunate} (θ) = (sin2 θ + cos2 θ/gg2) 1 2 with γ = 3.4±0.3. The obtained value of the anisotropy parameter γ is much smaller than the values reported earlier for single crystals close to Tc.@en

Using projection optics we made a detailed study of the interaction of a spatially uniform 248 nm excimer laser beam and a 99% dense YBa 2Cu3O6+x target. Below a threshold fluence of 1 J/cm2 the roughness of the irradiated target increases dramatically due to non-stoichiometric ablation. The overall target surface composition becomes increasingly Y rich and Cu poor, while the opposite is found for the corresponding ablated thin films. Above the threshold fluence the composition of the ablated target surface is conserved. As a result of the energy homogeneity of the laser beam obtained by means of projection optics, the optimization of the deposition parameters has been improved leading to the reproducible fabrication of flat, stoichiometric YBa2Cu3O7 films with Tc0's over 91 K.@en

The dynamical relaxation rate Q dln js/dln(dB/dt) where js is the current induced in a superconductor when the external field is swept at a rate dB/dt, has been measured in YBa2Cu3O7 and Y2Ba4Cu8O16 films of 100 nm and 180 nm thickness as a function of magnetic field at temperatures between 2 K and Tc. The data show i) a non zero relaxation at low T due to quantum creep, ii) a plateau between 15 and ∼ 50 K and iii) a divergence when T approaches the irreversibility line. The data are analyzed within the collective pinning model. At low temperatures it is shown that both js and Q are influenced by quantum creep.@en