We measured the double sideband (DSB) receiver noise temperature (TrecDSB) of an NbN hot electron bolometer (HEB) mixer at three local oscillator frequencies of 1.6, 2.5, and 5.3 THz. The HEB has cleaned contact interfaces with a 200 nm thick Au layer. The measuredTrecDSB values are 530 ± 11 K, 640 ±18 K, and 2190 ±150 K at 1.6, 2.5, and 5.3 THz, respectively, using an air setup with total optical losses of 2.60 ± 0.04, 2.63 ± 0.16, and 4.70 ± 0.24 dB, respectively. We derived low mixer noise temperatures (TmixerDSB) of 240 ± 6 K at 1.6 THz and 290 ± 13 K at 2.5 THz, achieving over 30% improvement compared to published NbN HEB mixers. This enhancement can reduce the integration time of a heterodyne instrument by roughly a factor of 2. At 5.3 THz,TmixerDSB is 620 ± 55 K, showing limited improvement due to non-optimized antenna geometry. These results also contribute to understanding the device physics of a wide HEB (4 μm) at high frequencies.

Achieving both high redox activity and rapid ion transport is a critical and pervasive challenge in electrochemical energy storage applications. This challenge is significantly magnified when using large-sized charge carriers, such as the sustainable ammonium ion (NH₄⁺). A self-assembled MXene/n-type conjugated polyelectrolyte (CPE) superlattice-like heterostructure that enables redox-active, fast, and reversible ammonium storage is reported. The superlattice-like structure persists as the CPE:MXene ratio increases, accompanied by a linear increase in the interlayer spacing of MXene flakes and a greater overlap of CPEs. Concurrently, the redox activity per unit of CPE unexpectedly intensifies, a phenomenon that can be explained by the enhanced de-solvation of ammonium due to the increased volume of 3 Å-sized pores, as indicated by molecular dynamic simulations. At the maximum CPE mass loading (MXene:CPE ratio = 2:1), the heterostructure demonstrates the strongest polymeric redox activity with a high ammonium storage capacity of 126.1 C g⁻¹ and a superior rate capability at 10 A g⁻¹. This work unveils an effective strategy for designing tunable superlattice-like heterostructures to enhance redox activity and achieve rapid charge transfer for ions beyond lithium.