In this work, a medium Mn-Ni steel was treated through Quenching and Partitioning (Q&P) with a partitioning temperature (PT) of 650 °C, which corresponded to the start of the austenite reverse transformation (ART) phenomenon. The influence of the quenching temperature (QT) and partitioning time (Pt) on austenite stabilization and mechanical properties was investigated. A strong influence of the quenching temperature was observed. Results were compared with those obtained after a Q&P treatment with 400 °C partitioning temperature. The Q&P cycle with quenching to room temperature and a high partitioning temperature produced a steel with a high retained austenite (RA) volume fraction and exceptional strength–ductility balance. The analysis of the mechanical stability of the retained austenite revealed a significant stress-induced transformation. Nevertheless, the austenite, which was stable at stresses above the yield stress, provided significant TRIP-assisted ductility. Bending, hole expansion and post-stamping properties were also evaluated for the most promising conditions. @en

An effective way for the automotive industry to tackle the growing concern of CO2 emissions from automobiles is to reduce the overall weight of the vehicle, without compromising its performance and passenger safety. With the increasing demand of steels with enhanced properties in the last decade, the development of advanced high strength steels (AHSSs) has been focused on the design of complex microstructures leading to exceptional combinations of strength and ductility. One such steel is Quenching and Partitioning (Q&P) steel, which is typically composed of a high strength phase, martensite, and a softer phase, austenite, which contributes to the ductility of the material. The main strategy in developing Q&P steels involves partitioning of carbon, an interstitial alloying element, from supersaturated martensite (α׀, formed in an initial quenching step from the austenitisation temperature) into austenite (γ) during an isothermal holding (partitioning stage) to enhance the thermal and mechanical stability of austenite. If the partitioning step is subjected at higher temperatures, substitutional austenite-stabilising alloying elements, such as manganese, may partition to the austenite and significantly enhance the stability of austenite in the final microstructure. Keeping this in mind, experimental and modelling approaches are employed in this Ph.D. thesis to investigate the microstructural evolution and the mechanisms involved during the quenching and high-temperature partitioning process in five different medium manganese steels. @en

Austenite stabilization through carbon partitioning from martensite into austenite is an essential aspect of the quenching and partitioning (Q&P) process. Substitutional alloying elements are often included in the chemical composition of Q&P steels to further control the microstructure development by inhibiting carbide precipitation (silicon) and further stabilize austenite (manganese and nickel). However, these elements can interfere in the microstructure development, especially when high partitioning temperatures are considered. In this study, the microstructural development during the Q&P process of four low-carbon, medium-manganese steels with varying contents of silicon and nickel is investigated. During partitioning at 400 °C, silicon hinders cementite precipitation in primary martensite thereby assisting carbon partitioning from martensite to austenite. During partitioning at temperatures of 500 °C and 600 °C, presence of nickel inhibits pearlite formation and promotes austenite reversion, respectively. It is observed that the stabilization of austenite is significantly enhanced through the addition of nickel by slowing down the kinetics of competitive reactions that are stimulated during the partitioning stage. Results of this study provide an understanding of the interplay among carbon, silicon and nickel during Q&P processing that will allow the development of new design strategies to tailor the microstructure of this family of alloys.

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In this work, four low carbon steels with different contents of Mn and Ni were heat treated by quenching and partitioning (Q&P) cycles where high partitioning temperatures, in the range of 550 °C–650 °C, were applied. In order to elucidate the effect of applying these high partitioning temperatures with respect to more common Q&P cycles, the materials were also heat treated considering a partitioning temperature of 400 °C. The microstructure evolution during the Q&P cycles was studied by means of dilatometry tests. The microstructural characterization of the treated materials revealed that austenite retention strongly depended on the alloy content and partitioning conditions. It was shown that the occurrence of austenite reverse transformation (ART) in the partitioning stage in some of the alloys and conditions was a very effective mechanism to increase the austenite content in the final microstructure. However, the enhancement of tensile properties achieved by the application of high partitioning temperature cycles was not significant. @en

Medium-Mn Quenching & Partitioning (Q&P) steels have been recently considered as potential candidates for the 3rd generation advanced high-strength steels. The processing of these steels aims to induce the partitioning of substitutional alloying elements from martensite to austenite during an isothermal treatment at high temperature, where the diffusivity of substitutional alloying elements is sufficiently high. In this way, austenite increases its concentration of austenite-stabilising elements and thus its thermal stability. The present study aims to investigate the microstructural evolution during high temperature partitioning treatments in a medium-Mn steel and the possible occurrence of additional phase transformations that may compete with the process of atomic partitioning between martensite and austenite. Q&P routes in which the partitioning steps take place in the range of 400 °C–600 °C for times up to 3600 s were investigated. The final microstructures display an increased fraction of retained austenite with increasing holding times during partitioning at 400 °C, while at higher partitioning temperatures, 450 °C–600 °C, leads to cementite precipitation in austenite films and pearlite formation in blocky austenite, resulting in a decrease of the fraction of retained austenite with the holding time. This observation is supported with theoretical calculations of the volume change, suggesting that for maximising the fraction of retained austenite, short holding times are preferred during partitioning at high temperatures. Observations from the current study reveal that the successful application of high-temperature partitioning treatments in medium-Mn steels requires microstructure design strategies to minimize or suppress competitive reactions.

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