Synergy of phosphate recovery from sludge-incinerated ash and coagulant production by desalinated brine

Abstract

Wet-chemical approach is widely applied for phosphate recovery from incinerated ash of waste activated sludge (WAS), along with metals removed/recovered. The high contents of both aluminum (Al) and iron (Fe) in WAS-incinerated ash should be suitable for producing coagulants with some waste anions like Cl⁻ and SO₄²⁻ With acid (HCl) leaching and metals’ removing, approximately 88 wt% of phosphorus (P) in the ash could be recovered as hydroxylapatite (HAP: Ca₅(PO₄)₃OH); Fe³⁺ in the acidic leachate could be selectively removed/recovered by extraction with an organic solvent of tributyl phosphate (TBP), and thus a FeCl₃-based coagulant could be synthesized by stripping the raffinate with the original brine (containing abundant Cl⁻ and SO₄²⁻). Furthermore, a liquid poly-aluminum chloride (PAC)-based coagulant could also be synthesized with Al³⁺ removed from the ash and the brine, which behaved almost the same in the coagulation performance as a commercial coagulant on both phosphate and turbidity removals. Both P-recovery from the ash and coagulant production associated with the brine would enlarge the markets of both ‘blue’ phosphate and ‘green’ coagulants.