The effectiveness of bank filtration (BF) is highly dependent on the source water quality (e.g., organic matter composition, pH, and concentration of heavy metals (HMs)). In this study, the impact of dissolved organic matter (DOM) on the removal of selected metals (Cu, Zn, Pb, Se, and Ni) during BF was investigated. Column studies were conducted at 30 °C with feed water sources of different organic matter composition. Excitation–emission matrix fluorescence coupled with parallel factor analysis (PARAFAC–EEM) was used to characterise the organic composition of the feed waters. Moreover, another series of column studies was conducted to assess the impact of natural organic matter type (humic, protein) and concentration on the HMs removals. The experimental results revealed a high Pb(II) removal efficiency during filtration, which depends only slightly on the organic matter content of the feed water. In comparison, the removals of Cu, Zn and Ni ranged between 65 and 95 %; and relied significantly on the organic concentration and composition in the raw waters. Humic compounds (terrestrial or microbial) demonstrated adequate ability to reduce the removal efficiencies of these HMs during the infiltration. Conversely, biodegradable matter was found to be effective in enhancing the sorption of HMs onto the sand grains. The Se-removal was enhanced when the feed water contained a higher concentration of biodegradable matter. In general, it can be concluded that the organic composition of the source water affects profoundly the removal of HMs during the BF, and should be considered in the design of BF systems.

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Bank filtration (BF) has been used for many years as an economical technique for providing high-quality drinking water. However, under anaerobic conditions, the aquifer release of undesirable metal(loid)s, such as iron manganese, and arsenic, reduces the bank filtrate quality and thus restricts the application of this technique. This study investigates the impact of the organic-matter composition of source water on the mobilisation of Fe, Mn, and As during the anaerobic BF process. A laboratory-scale column study was conducted at a controlled-temperature (30 ± 2 °C) using different feed water sources. The organic matter characteristics of the feed water were elucidated using excitation-emission spectroscopy techniques integrated with parallel factor framework clustering analysis (PFFCA) model. The experiment was performed at redox conditions between 66 mv and −185 mv. Moreover, batch studies were implemented to study the effect of natural organic matter type (humic, fulvic and tyrosine) and concentration on the mobilisation of the selected metal(loids). The laboratory experiments demonstrated that the mobilisation of Fe, Mn and As during the BF are varied with the organic water concentration and composition of the source water. The fluorescence results revealed that terrestrial and condensed structure humic compounds are more capable to release Fe into the filtrate water. In contrast, Mn exhibited an equal tendency of mobilisation towards all the humic compounds regardless of its origin and structure. However, at a humic concentration higher than 5 mg-C/L, Mn showed more affinity towards lower molecular weight humic compounds. Arsenic was found to be the least impacted by the alteration in the source water organic matter composition; its mobilisation was highly correlated with iron releasing process. On the other hand, the biodegradable organic matter at high concentration (>10 mg-C/L) was found to be highly effective to turn the infiltration area into Fe-reducing environment and thereby elevating Fe and As concentrations in the pumped water. In conclusion, this study revealed that the DOM composition and concentration of the raw water could play an important role in the mobilisation of metal(loids) during the BF processes.

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Bank filtration (BF) is acknowledged as a sustainable and effective technique to provide drinking water of adequate quality; it has been known for a long time in Europe. However, this technique is site-specific and therefore its application in developing countries with different hydrologic and environment conditions remains limited. In this research, a 3-discipline study was performed to evaluate the feasibility of the application of this technique in Aswan City (Egypt). Firstly, a hydrological model was developed to identify key environmental factors that influence the effectiveness of BF, and to formulate plans for the design and management of the BF system. Secondly, water samples were collected for one year (January 2017 to December 2017) from the water sources and monitoring wells to characterize the bank-filtrate quality. Lastly, an economic study was conducted to compare the capital and operating costs of BF and the existing treatment techniques. The results demonstrated that there is high potential for application of BF under such hydrological and environmental conditions. However, there are some aspects that could restrict the BF efficacy and must therefore be considered during the design process. These include the following: (i) Over-pumping practices can reduce travel time, and thus decrease the efficiency of treatment; (ii) Locating the wells near the surface water systems (<50 m) decreases the travel time to the limit (<10 days), and thus could restrict the treatment capacity. In such case, a low pumping rate must be applied; (iii) the consequences of lowering the surface water level can be regulated through the continuous operation of the wells. Furthermore, laboratory analysis indicated that BF is capable of producing high quality drinking water. However, an increase in organic matter (i.e., humics) concentration was observed in the pumped water, which increases the risk of trihalomethanes being produced if post-chlorination is implemented. The economic study ultimately demonstrated that BF is an economic and sustainable technique for implementation in Aswan City to address the demand for potable water.

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Riverbank filtration (RBF) represents a low-cost and sustainable alternative to advanced treatment technologies to pre-treat or remove several organic micropollutants (OMPs) from surface water. The objective of this research was to investigate the efficacy of biodegradation and adsorption processes in the removal of OMPs at high temperatures (20-30 ± 2 °C) during RBF. Laboratory-scale batch studies were conducted using silica sand at different temperatures (20, 25 and 30 °C) to study the removal of 19 OMPs (6 polyaromatic hydrocarbons (PAHs), 8 herbicides and 5 insecticides) from various water sources with different organic matter characteristics. Simazine, atrazine, metolachlor, and isoproturon exhibited partial persistent characters (16% < removal < 59%), which apparently decreased with increase in temperature. DDT, pyriproxyfen, pendimethalin, β-BHC, endosulfan sulfate and PAHs with high hydrophobicity (solubility in terms of logS < -4) tend to be well adsorbed onto sand grains (removal> 80%), regardless of temperature, redox conditions or type of organic carbon fraction fed to the batch reactors. These findings indicate that these hydrophobic compounds are effectively removed during RBF regardless of the environmental conditions. Hydrophilic compounds (molinate, dimethoate, and propanil) showed temperature-dependent characteristics for influent water with low organic matter; their attenuation increased at higher temperature (removal > 95%) due to the high microbial activity. This study revealed that temperature is an important parameter affecting the removal of OMPs with hydrophilic and low-hydrophobicity characters. However, temperature has less influence on the removal of highly hydrophobic OMPs during RBF process and thus should be considered during RBF system design.@en

Dissolved organic matter (DOM) in source water highly influences the removal of different contaminants and the dissolution of aquifer materials during bank filtration (BF). The fate of DOM during BF processes under arid climate conditions was analysed by conducting laboratory-scale batch and column studies under different environmental conditions with varying temperature (20-30 °C), redox, and feed water organic matter composition. The behaviour of the DOM fractions was monitored using various analytical techniques: fluorescence excitation-emission matrix spectroscopy coupled with parallel factor analysis (PARAFAC-EEM), and size exclusion liquid chromatography with organic carbon detection (LC-OCD). The results revealed that DOM attenuation is highly dependent (p < 0.05) on redox conditions and temperature, with higher removal at lower temperatures and oxic conditions. Biopolymers were the fraction most amenable to removal by biodegradation (> 80%) in oxic environments irrespective of temperature and feed water organic composition. This removal was 20-24% lower under sub-oxic conditions. In contrast, the removal of humic compounds exhibited a higher dependency on temperature. PARAFAC-EEM revealed that terrestrial humic components are the most temperature critical fractions during the BF processes as their sorption characteristics are negatively correlated with temperature. In general, it can be concluded that BF is capable of removing labile compounds under oxic conditions at all water temperatures; however, its efficiency is lower for humic compounds at higher temperatures.

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