Recently, researchers in the road field are focusing on the development of green asphalt materials with lower emission of volatile organic compounds (VOCs). The characterization methodology of asphalt VOCs and the influencing factors on VOCs release have always been the basic issue of asphalt VOCs emission reduction research. Researchers have proposed a variety of asphalt VOCs characterization methodologies, which also have mutually irreplaceable characteristics. Asphalt VOCs volatilization is affected by many factors. In this study, asphalt VOCs characterization methodologies were summarized, including their advantages, disadvantages, characteristics and applicable requirements. Subsequently, the influencing factors of VOCs release, such as asphalt types and environment conditions, are summarized to provide theoretical support for the emission reduction research. The classification and mechanism of newly-development asphalt VOCs emission reduction materials are reviewed. The reduction efficiencies are also compared to select better materials and put forward the improvement objective of new materials and new processes. In addition, the prospects about development of VOCs release mechanism of asphalt materials during the full life cycle and feasibility research of high-efficiency composite emission reduction materials in the future were put forward.@en

Due to the complex organic properties of asphalt materials, the heating process during asphalt pavement construction will lead to the release of asphalt VOCs‧ Asphalt VOCs volatilization will cause irreversible harm to both the environment and health of construction workers‧ Researchers in the field of road construction have carried out extensive research on various emission reduction materials and technologies based on release mechanism of asphalt VOCs‧ There are no comprehensive research and intuitive comparison on emission reduction materials due to the differences between quantitative standards for emission reduction effects‧ This paper summarizes the current research status of asphalt VOCs emission reduction, including the development history of emission reduction technology and reduction mechanism of various asphalt VOCs emission reduction materials mainly based on inhibitors, warm mixing agents and flame retardants‧ In addition, the emission reduction effects of different emission reduction materials are compared and the improvement trend research direction of new and efficient asphalt VOCs reduction technology and materials are proposed to achieve green and low-emission construction‧ Finally, around the environmental protection theme of VOCs emission reduction, this study also put forward the prospect of full life cycle emission mechanism and feasibility of efficient composite materials design to support the urgent need for green transport.

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Asphalt material is an irreplaceable material in road construction. However, it releases VOCs (Volatile Organic Compounds), which do cause pollution to the surrounding environment, during its full life cycle, especially in high-temperature paving stage and summer service time. Asphalt VOCs release mechanism and effective emission reduction technologies are therefore urgently needed. The chemical analysis of VOCs from asphalt binder always invariably excludes a vast number of compounds of unknown relevance, making the quantitative analysis lower data accuracy. In order to address this problem, fingerprint database was developed and introduced in this study, with the detected VOCs data from 104 kinds of asphalt binders. The analysis parameters, including fingerprint components and calibration curves were optimized through quantitative study. With the help of a self-developed fingerprint database, the calculation formulas of single VOC and total released VOCs were established for quantitative analysis of VOCs from asphalt binder. In addition, the influencing mechanism of heating temperature and asphalt types on VOCs volatilization characteristic were explored to achieve emission reduction in asphalt industry.

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Polycyclic Aromatic Hydrocarbons (PAHs) in asphalt materials is a type of serious environmental hazard, and the main pollution resource in road engineering. Aiming at the requirement of PAHs rapid detection method in asphalt pavement construction for low environmental hazard, this research concentrated in experiments about PAHs content, fluorescence characteristics, solvent environment impact mechanism and correlation between fluorescence intensity and concentration in different asphalt materials, based on the fluorescence effect of PAHs from condensed ring structure. It is found that coal tar asphalt has a typical aggregation-caused quenching phenomenon and higher fluorescence quantum efficiency. Taking the three solvent environment parameters polarity, viscosity and pH value as the research objects, the optimal solvent environment for the fluorescence phenomenon of PAHs in asphalt materials was explored and established as dimethyl sulfoxide: tetrahydrofuran: deionized water: glycerol = 1 : 1 : 1 : 2. Under the optimal solvent environment, fluorescence intensity and concentration of the three asphalt materials all showed obvious linear relationship. Under the same concentration condition, fluorescence intensity of asphalt material showed positive correlation with the PAHs content. This study proves that the asphalt material has the linear relationship between fluorescence intensity and PAHs concentration, which will provide theoretical basis for the detection of PAHs content in asphalt materials, and support the development of low environmental hazard in construction technology for road engineering.

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