Limited overall efficiency and excessive complexity can hinder the competitiveness of biomass gasifier solid oxide fuel cell micro combined heat and power systems. To overcome these problems, hydrocarbons direct internal reforming is analysed as a strategy to increase efficiency and reduce system complexity. To the same end, two biosyngas heating-up strategies are compared: catalytic partial oxidation and afterburner off gases utilization. A comprehensive approach combining thermodynamic equilibrium calculations, experimental measurements, and system modelling was used. The gas cleaning unit should operate at 400 °C to decrease H₂S and HCl below 1 ppmv. A tar amount of 120–130 g Nm⁻³ dry biosyngas for woodchips and 190 g Nm⁻³ for straw pellets was measured and 2-methoxyphenol, hydroxyacetic acid and hydroxyacetone were selected as representative compounds. With direct internal reforming the cathode air flow rate decreases from approximately 90 kg h⁻¹ to 60 kg h⁻¹. This leads to an increase of around 1% point in electrical efficiency and of even 5–6% points in thermal efficiency. Direct internal tar reforming seems therefore an advantageous strategy. The catalytic partial oxidation unit increases the system overall efficiency but reduces the electric efficiency from roughly 38%–30% and is therefore not advised.

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Solid oxide cell systems (SOCs) are increasingly being considered for electrical energy storage and as a means to boost the use of renewable energy and improve the grid flexibility by power-to-gas electrochemical conversion. The control of several variables (e.g., local temperature gradients and reactant utilization) is crucial when the stacks are used in dynamic operation with intermittent electrical power sources. In the present work, two 1D models of SOC stacks are established and used to investigate their dynamic behavior and to select and tune a suitable control strategy. Subsequently, safe operating ranges were determined to meet the thermal constraints of the stack by analysing not only the fuel cell (SOFC) and electrolyzer (SOEC) individual modes but also the switching between the two modes when the stack operates reversibly. The dynamic analysis shows that the control loops of our multi-input (reactant molar flow rates), multi-output (reactant utilization and maximum local temperature gradients) control system are strongly decoupled. Therefore, a proportional integral control strategy can be used to prevent dangerous stack operating conditions in dynamic operation. Finally, the controllers were tuned, and their transfer functions were reported. Convective heat transfer via air flow allows controlling the temperature of the solid structure of the cell/stack component, thus avoiding issues related to temperature variation during transient operation. Moreover, the reactant utilization controllers can avoid component fracture or degradation owing to fuel starvation under dynamic operation. The process can be approximated by two first order transfer functions. It can help in the design of more complex control systems in the future if necessary, with embedded process models, such as model predictive control. Results in the simulation environment are preparatory to the programming phase of an actual controller in real-world applications.

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The steel industry is one of the major sources of CO₂ emissions that are released in the manufacture and process of steel as well as in related power production. Focused on reduction of CO₂ emissions in the power production, this paper presents a novel solid oxide fuel cell-gas turbine combined heat and power system fed by coke oven gas. The solid oxide fuel cell-gas turbine system design consists of an adequate gas cleaning section for contaminants removal, solid oxide fuel cell as the main power producer and an anode offgas pressure swing adsorption based CO₂ capture unit. This system is thermodynamically and techno-economically analyzed and compared with a reheat steam turbine. Furthermore, the reheat steam turbine is retrofitted with a CO₂ capture unit. It is then compared to the solid oxide fuel cell-gas turbine system to analyse the difference in system efficiencies. The solid oxide fuel cell-gas turbine system yields an electrical efficiency of 64%, which is significantly higher than electrical efficiency achieved by both, a conventional reheat steam cycle (34.1%) and the retrofitted system (27.0%). Moreover, it depicts a combined heat and power efficiency of 73%. Results also reveal that the solid oxide fuel cell-gas turbine system can achieve a reduction of 50% in CO₂ emissions for equal power production. Furthermore, techno-economic analysis lead to a payback period of 9 years, taking into account state-of-the-art taxes and variation in the cost of components over the lifetime, without taking into account the fuel cost.

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This paper describes the steps involved in the design, construction, and testing of a gasifier-specific solid oxide fuel cell (SOFC) system. The design choices are based on reported thermodynamic simulation results for the entire gasifier- gas cleanup-SOFC system. The constructed SOFC system is tested and the measured parameters are compared with those given by a system simulation. Furthermore, a detailed exergy analysis is performed to determine the components responsible for poor efficiency. It is concluded that the SOFC system demonstrates reasonable agreement with the simulated results. Furthermore, based on the exergy results, the components causing major irreversible performance losses are identified.@en