This study combines multiscale analyses of geological, fault, fracture, and stable isotope data to investigate strike-slip deformation and channeling of hydrothermal fluids along the Cafarnaum fault and calcite veins at different distances from the fault, which is a structure in the São Francisco Craton, northeastern Brazil. Meteoric fluids with δD values near −45‰ and δ¹⁸O values near −6.5‰ and temperatures at 40–70 °C precipitated as calcite veins in the host carbonate units. The Cafarnaum fault, a N-S-striking vertical, ~170 km long fault zone, juxtaposes Neoproterozoic carbonate rocks in the western block and Mesoproterozoic siliciclastic rocks in the eastern block. A zone of restraining bends occurs at the central part of the fault, whereas termination zones of horsetail geometry occur at both ends of the Cafarnaum fault. These zones are marked by NW-SE-striking extensional faults that are oblique to the main N-S-striking fault zone, where hydrothermal deposits occur. The zone of influence of the Cafarnaum fault is ~ 20 km wide around the main fault. The fault formed during the Brasiliano orogeny (740–560 Ma) after Neoproterozoic carbonate platform deposition. In contrast with the host units, fluids along the fault zone originated in deeper levels of the crust and show much lower δ¹⁸O values, indicating higher crystallization temperatures. These fluids caused brecciation in the Neoproterozoic carbonate host rocks, whereas a subsequent decrease in fluid pressure and cooling near the surface resulted in the precipitation of a hydrothermal paragenesis in veins, also affecting the host rock.

The shallow-marine carbonate rocks of the Jandaíra Formation have been subject to significant permeability variations through time due to various events of fracturing and calcite cementation. As a consequence, the Jandaíra Formation accommodated fluid flow only during specific moments in time. We reconstructed these episodes of fluid flow based on isotope characterizations and microscope characteristics of calcite veins and host rock cements. The Jandaíra Formation, which belongs to the post-rift sequence of the Potiguar Basin in northeast Brazil, was deposited from the Turonian onward until a marine regression exposed it in the Campanian. Due to the subaerial exposure, meteoric waters flushed out marine connate waters, leading to an event of early diagenesis and full cementation of the Jandaíra Formation. Fluid flow through the resulting impermeable carbonate formation appears to be closely related to fracturing. Fracturing in the Late Cretaceous induced a drastic increase in permeability, giving rise to extensive fluid circulation. Host rock dissolution associated to the circulating fluids led to calcite vein cementation within the fracture network, causing it to regain an impermeable and sealing character. In the research area, fluid flow occurred during early burial of the Jandaíra Formation at estimated depths of 400–900 m. This study documents the first application of fluid inclusion isotope analysis on vein precipitates, which allowed full isotopic characterization of the paleo-fluids responsible for calcite vein cementation. The fluid inclusion isotope data indicate that upwelling of groundwater from the underlying Açu sandstones provided the fluids to the fracture network. In Miocene times, renewed tectonic compression of a lower intensity created a secondary fracture network in the Jandaíra Formation. The density of this fracture network, however, was too low to induce a new episode of fluid circulation. As a result, this tectonic event is associated with the development of barren extensional fractures.

Pervasive fracture networks are common in many reservoir-scale carbonate bodies even in the absence of large deformation and exert a major impact on their mechanical and flow behaviour. The Upper Cretaceous Jandaíra Formation is a few hundred meters thick succession of shallow water carbonates deposited during the early post-rift stage of the Potiguar rift (NE Brazil). The Jandaíra Formation in the present onshore domain experienced <1.5 km thermal subsidence and, following Tertiary exhumation, forms outcrops over an area of >1000 km². The carbonates have a gentle, <5⁰, dip to the NE and are affected by few regional, low displacement faults or folds. Despite their simple tectonic history, carbonates display ubiquitous open fractures, sub-vertical veins, and sub-vertical as well as sub-horizontal stylolites. Combining structural analysis, drone imaging, isotope studies and mathematical modelling, we reconstruct the fracturing history of the Jandaíra Formation during and following subsidence and analyse the impact fractures had on coeval fluid flow. We find that Jandaíra carbonates, fully cemented after early diagenesis, experienced negligible deformation during the first few hundreds of meters of subsidence but were pervasively fractured when they reached depths >400-500 m. Deformation was accommodated by a dense network of sub-vertical mode I and hybrid fractures associated with sub-vertical stylolites developed in a stress field characterised by a sub-horizontal σ₁ and sub-vertical σ₂. The development of a network of hybrid fractures, rarely reported in the literature, activated the circulation of waters charged in the mountainous region, flowing along the porous Açu sandstone underlying the Jandaíra carbonates and rising to the surface through the fractured carbonates. With persisting subsidence, carbonates reached depths of 800-900 m entering a depth interval characterised by a sub-vertical σ₁. At this stage, sub-horizontal stylolites developed liberating calcite which sealed the sub-vertical open fractures transforming them in veins and preventing further flow. During Tertiary exhumation, several of the pre-existing veins and stylolites opened and became longer, and new fractures were created typically with the same directions of the older features. The simplicity of our model suggests that most rocks in passive margin settings might have followed a similar evolution and thus display similar structures. Basin Research