This study investigates the Mode-I fracture toughness of laminates with varying interface angles. A method for identifying crack tip location using grayscale characteristic parameters in DIC is proposed. The findings demonstrate that both initial and steady-state fracture toughness exhibit a bilinear relationship with interface angle. A cohesive constitutive model incorporating the interface angle was developed and integrated into a double cantilever beam finite element model, predicting delamination propagation behavior that was highly consistent with experimental results. Numerical analysis suggests that zigzag cracks may improve fracture toughness before steady-state toughness is achieved, with peak toughness correlating to the length of the zigzag cracks.