Unwanted breakdown of insulation is one of the primary challenges affecting the reliability of power systems. Liquid insulation is commonly used in power grids and subsea installations due to its preferred qualities, such as heat transfer and safety. Some insulating liquids have been available since the earliest times, and some have been proven to be harmful to humans, animals, and the environment. Consequently, the search for better candidates has always been ongoing. Unfortunately, the knowledge of the quality of the insulating liquids is insufficient since numerous phenomena related to electrical discharge and breakdown in insulating liquids happen unexpectedly, often surprising the personnel involved. Therefore, gaining a deep understanding of the breakdown physics of these liquids and mechanisms leading to the degradation of their dielectric properties is crucial. This understanding ensures that the new replacements are suitable for specific equipment. Partial discharge (PD), as one of the initial stages before breakdown and a major player in ageing the insulators, is the main focus of this work. One way to monitor a liquid’s insulation quality is through the Partial Discharge Inception Voltage (PDIV)
level. Based on PDIV measurements, there are defined standards, such as IEC 61294. This work is focused on investigating the behavior of different types of liquids under the AC voltage stress above and below the PDIV level to determine if the defined standards reflect the dielectric characteristics of each liquid properly. Three liquids have been examined, including two candidates from commonly used insulating liquids in electrical installations. Tests are performed in a needle-plane geometry under high-voltage AC stress. The same liquids and geometry have been used multiple times in previous studies under lower frequency AC voltage, yielding unexpected results. Therefore, this study aims to investigate deeper by testing the liquids at higher frequencies and comparing observations with previous results. The experimental setup used for this work includes a 20 kV resonance voltage source, and the needle-plane gap distance is 20 mm. The current flow from the plane to the needle is mostly capacitive in the range up to 100 nA, but space charges are proved to play a major role in the conductive component of the current. PD behavior has been found to relate to molecular structure and, in some cases, to the previous stresses, likely due to residual ions remaining from previous cycles. The presence and nature of space charges have been investigated carefully by testing liquids at higher frequencies below and above the PDIV level. Further, the test setup was facilitated, and half-cycle voltages were applied to involve only one polarity of space charges, and the differences were observed. Another part of this work involved the optical PD measurement method, which utilized two photomultiplier tubes (PMTs) and a coincidence circuit to filter out ambient dark noise. This method was employed alongside the well-known charge acquisition method to detect the initial PD pulses in the liquid. The results demonstrated a noteworthy difference between the two methods, prompting further investigation.