In light of the huge investments needed to acquire sediment cores and the growing need of energy-providing companies to predict reservoir quality, it is remarkable that the standard workflow in core analysis has not been optimized to extract as much information from cores as possible. The Integrated Core Analysis (ICA) protocol presented in this study provides a statistical framework for multivariate calibration and prediction of a wide range of properties measured in core, based on integration of high-resolution X-ray fluorescence core-scanning (XRF-CS) proxy records with records of sparsely sampled petrophysical data and sedimentological core descriptions. The downscaling of numerical data involves the application of invertible transformations to remove range constraints on data, followed by calibration with Partial Least Squares regression through cross validation. Categorical data (i.e. lithofacies) are downscaled by associating each class with a statistical model based on the XRF-CS data. All data points are reassigned to their most likely class by applying Quadratic Discriminant Analysis. The result of the ICA is a multivariate data set in which all properties are specified at the same high resolution along the core with their prediction uncertainties. Downscaling of all variables to 1-cm vertical resolution permits investigation of the variability among petrophysical properties, geochemical proxies, and lithofacies memberships. Petrographic analysis is fundamental for interpretation of the XRF-CS records (element-mineral affinity) and for understanding the sedimentological controls on predicted petrophysical properties. Application of the ICA protocol to a 32 m thick, heterogeneous, Upper Carboniferous fluvial sandstone interval resulted in a near 30-fold increase of the petrophysical data base, which allowed identification of the main depositional and diagenetic controls on the spatial distribution of reservoir quality. Successful implementation of the novel ICA protocol will greatly increase the economic value of legacy core data in studies that aim to re-use depleted hydrocarbon reservoirs.@en

We present an early Holocene record from Lake Meerfelder Maar in Germany for in-depth interpretation of depositional changes in annually laminated lake sediments as proxies for climatic and local environmental changes. We characterized the compositional changes in the sediment record using Ward's clustering analyses of the micro X-ray fluorescence core scanning data and linked these to microfacies descriptions. The down-core distribution of the clusters allowed us to define boundaries that represent variations of a comprehensive element assemblage occurring at 11 555, 11 230, 10 650, 10 515 and 9670 varve a BP. Our main results show that during the Early Holocene the long-term vegetation reorganization and evolution of the lake's catchment played a predominant role for sediment deposition. Abrupt shifts occurred at the Younger Dryas/Holocene and the Preboreal/Boreal biostratigraphical boundaries. We do not observe clear signals corresponding to known short-term climatic oscillations described in the North Atlantic region such as the Preboreal Oscillation. A unique and intriguing episode in the history of the lake of predominantly organic deposition and very low amounts of allochthonous sediments occurred between 10 515 and 9670 varve a BP and is related to hydrological thresholds.

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