The threat of global climate change has caused the international community to pay close attention to atmospheric levels of greenhouse gases such as carbon dioxide. Transportation sector carbon dioxide emissions efficiency (TSCDEE) is a key indicator used to prioritize sustainable development in the transportation sector. In this paper, the epsilon-based measure data envelopment analysis model with undesirable outputs is applied to estimate TSCDEE for 30 provinces in China from 2010 to 2016. We also analyze influencing factors using the spatial Durbin model. Research shows that the overall TSCDEE of the Chinese provinces studied was 0.618, indicating that most regions are still in need of improvements. The provinces with the highest TSCDEE are located in developed coastal regions of China. This study shows that factors such as transportation structure, traffic infrastructure level, and technological progress have prominent positive effects on TSCDEE, while both urbanization level and urban population density exert significantly negative effects on TSCDEE. The findings should have a far-reaching impact on the sustainable development of global transportation.

A bienzymatic cascade for selective sulfoxidation is presented. The evolved recombinant peroxygenase from Agrocybe aegeritra catalyses the enantioselective sulfoxidation of thioanisole whereas the choline oxidase from Arthrobacter nicotianae provides the H2 O2 necessary via reductive activation of ambient oxygen. The reactions are performed in choline chloride-based deep eutectic solvents serving as co-solvent and stoichiometric reductant at the same time. Very promising product concentrations (up to 15 mM enantiopure sulfoxide) and catalyst performances (turnover numbers of 150,000 and 2100 for the peroxygenase and oxidase, respectively) have been achieved.

A photobiocatalytic cascade transforming natural triglycerides into alkanes/alkenes is proposed. Starting from natural triglycerides, free fatty acids have been obtained using lipases. The free fatty acids were then, in a photoenzymatic step, decarboxylated into the C1-shortened alkanes using a recently described photodecarboxylase from Chlorella variabilis NC64A. This cascade produced alkanes from various natural (waste) oils in significant amounts (up to 24 g L⁻¹) and may provide a basis for valorisation of waste oils into a next generation of biodiesel.

The use of natural deep eutectic solvents (NADES) as multifunctional solvents for limonene bioprocessing was reported. NADES were used for the extraction of limonene from orange peel wastes, as solvent for the chemoenzymatic epoxidation of limonene, and as sacrificial electron donor for the in situ generation of H ₂ O ₂ to promote the epoxidation reaction. The proof-of-concept for this multifunctional use was provided, and the scope and current limitations of the concept were outlined.