Terrorists often take the chemical clusters as the attacking target because of the adverse impacts of a chemical accident on society and the environment. In addition to some fixed countermeasures, previous studies have verified the feasibility of a patrol in addressing adversarial attacks. However, the previous patrolling practices fail to tackle the terrorist attacking problems in a large-scale area cost-effectively. To further tackle the protection issue with cost-beneficial solutions in a large-scale scenario, i.e., in a chemical cluster, we propose an area-partition-involved collaborative patrolling (APCP) game. We first leverage the proposed greedy deployment algorithm to determine the initial deployment of defenders (patrollers), including the quantity and position of patrol vehicles. Then, the large-scale area is partitioned into multiple smaller areas by using the collaborative idea of static partitioning. In the meantime, corresponding patrolling graphs are constructed based on graphic modeling methods. Finally, the APCP game is built between patrol vehicles (namely defender) and potential terrorists (namely attacker), in which patrol vehicles aim at detecting attack behaviors of terrorists by intelligently scheduling the patrolling routes. After formalizing the problem into a sequential game, we compute the Stackelberg equilibrium through the MultiLPs algorithm. Through case studies of three practical chemical cluster scenarios, the results explicitly show the superiority of our proposed APCP game by saving up to 25.48 % patrolling costs in a one-shot game compared to the results before partition. As for the collaborative patrolling problem in a large-scale area, the methods and models proposed in this paper can facilitate the management department of chemical clusters with intelligently scheduled patrolling routes, which can effectively reduce the cost of patrollers, and better protect the chemical cluster.

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Estimating gas source terms is essential and significant for managing a gas emission accident. Optimization method, as a kind of estimation methods, is helpful to figure out the source terms by solving the inverse problem. Significantly, the performance of optimization method on source term estimation is affected by the accuracy of forward dispersion model. To enhance the estimation accuracy, previous works have demonstrated the feasibility of using Back Propagation Neural Network (BPNN) trained by actual experimental datasets as a forward dispersion model. However, the overall accuracy of source estimation is still limited by backward estimation methods. Most related studies used a single optimization algorithm to estimate source terms, which usually fails to realize the requirements of both high calculation accuracy and satisfying computational efficiency. Therefore, a hybrid strategy was proposed in this study to combine optimization algorithms with different characteristics, including particle swarm optimization, genetic algorithm and simulated annealing algorithm, to not only achieve high accuracy in global searching, but also converge to a stable result efficiently. Finally, extensive experiments are conducted to testify our proposed hybrid optimization algorithms. The Skill scores of hybrid optimization algorithms decrease obviously compared to those of single optimization algorithm. Hence, the proposed hybrid strategy is potentially useful for guiding the combination of optimization algorithms for gas source terms estimation, which further contributes to deal with a gas emission accident with satisfying calculation accuracy and computational efficiency.

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Chemical production activities in industrial districts pose great threats to the surroundingatmospheric environment and human health. Therefore, developing appropriate and intelligentpollution controlling strategies for the management team to monitor chemical production processesis significantly essential in a chemical industrial district. The literature shows that playing a chemicalplant environmental protection (CPEP) game can force the chemical plants to be more compliantwith environmental protection authorities and reduce the potential risks of hazardous gas dispersionaccidents. However, results of the current literature strictly rely on several perfect assumptions whichrarely hold in real-world domains, especially when dealing with human adversaries. To addressbounded rationality and limited observability in human cognition, the CPEP game is extended togenerate robust schedules of inspection resources for inspection agencies. The present paper isinnovative on the following contributions: (i) The CPEP model is extended by taking observationfrequency and observation cost of adversaries into account, and thus better reflects the industrialreality; (ii) Uncertainties such as attackers with bounded rationality, attackers with limited observationand incomplete information (i.e., the attacker’s parameters) are integrated into the extended CPEPmodel; (iii) Learning curve theory is employed to determine the attacker’s observability in the gamesolver. Results in the case study imply that this work improves the decision-making process forenvironmental protection authorities in practical fields by bringing more rewards to the inspectionagencies and by acquiring more compliance from chemical plants.@en

The accurate prediction of hazardous gas dispersion process is essential to air quality monitoring and the emergency management of contaminant gas leakage incidents in a chemical cluster. Conventional Gaussian-based dispersion models can seldom give accurate predictions due to inaccurate input parameters and the computational errors. In order to improve the prediction accuracy of a dispersion model, a data-driven air dispersion modeling method based on data assimilation is proposed by applying particle filter to Gaussian-based dispersion model. The core of the method is continually updating dispersion coefficients by assimilating observed data into the model during the calculation process. Another contribution of this paper is that error propagation detection rules are proposed to evaluate their effects since the measured and computational errors are inevitable. So environmental protection authorities can be informed to what extent the model output is of high confidence. To test the feasibility of our method, a numerical experiment utilizing the SF₆ concentration data sampled from an Indianapolis field study is conducted. Results of accuracy analysis and error inspection imply that Gaussian dispersion models based on particle filtering and error propagation detection have better performance than traditional dispersion models in practice though sacrificing some computational efficiency.

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Locating and quantifying the emission source plays a significant role in the emergency management of hazardous gas leak accidents. Due to the lack of a desirable atmospheric dispersion model, current source estimation algorithms cannot meet the requirements of both accuracy and efficiency. In addition, the original optimization algorithm can hardly estimate the source accurately, because of the difficulty in balancing the local searching with the global searching. To deal with these problems, in this paper, a source estimation method is proposed using an artificial neural network (ANN), particle swarm optimization (PSO), and a simulated annealing algorithm (SA). This novel method uses numerous pre-determined scenarios to train the ANN, so that the ANN can predict dispersion accurately and efficiently. Further, the SA is applied in the PSO to improve the global searching ability. The proposed method is firstly tested by a numerical case study based on process hazard analysis software (PHAST), with analysis of receptor configuration and measurement noise. Then, the Indianapolis field case study is applied to verify the effectiveness of the proposed method in practice. Results demonstrate that the hybrid SAPSO algorithm coupled with the ANN prediction model has better performances than conventional methods in both numerical and field cases.

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The chemical industry is of paramount importance to the world economy and this industrial sector represents a substantial income source for developing countries. However, the chemical plants producing inside an industrial district pose a great threat to the surrounding atmospheric environment and human health. Therefore, designing an appropriate and available air quality monitoring network (AQMN) is essential for assessing the effectiveness of deployed pollution-controlling strategies and facilities. As monitoring facilities located at inappropriate sites would affect data validity, a two-stage data-driven approach constituted of a spatio-temporal technique (i.e. Bayesian maximum entropy) and a multi-objective optimization model (i.e. maximum concentration detection capability and maximum dosage detection capability) is proposed in this paper. The approach aims at optimizing the design of an AQMN formed by gas sensor modules. Owing to the lack of long-term measurement data, our developed atmospheric dispersion simulation system was employed to generate simulated data for the above method. Finally, an illustrative case study was implemented to illustrate the feasibility of the proposed approach, and results imply that this work is able to design an appropriate AQMN with acceptable accuracy and efficiency.

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Dispersion prediction plays a significant role in the management and emergency response to hazardous gas emissions and accidental leaks. Compared with conventional atmospheric dispersion models, machine leaning (ML) models have both high accuracy and efficiency in terms of prediction, especially in field cases. However, selection of model type and the inputs of the ML model are still essential problems. To address this issue, two ML models (i.e., the back propagation (BP) network and support vector regression (SVR) with different input selections (i.e., original monitoring parameters and integrated Gaussian parameters) are proposed in this paper. To compare the performances of presented ML models in field cases, these models are evaluated using the Prairie Grass and Indianapolis field data sets. The influence of the training set scale on the performances of ML models is analyzed as well. Results demonstrate that the integrated Gaussian parameters indeed improve the prediction accuracy in the Prairie Grass case. However, they do not make much difference in the Indianapolis case due to their inadaptability to the complex terrain conditions. In addition, it can be summarized that the SVR shows better generalization ability with relatively small training sets, but tends to under-fit the training data. In contrast, the BP network has a stronger fitting ability, but sometimes suffers from an over-fitting problem. As a result, the model and input selection presented in this paper will be of great help to environmental and public health protection in real applications.

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Hazardous gas leak accident has posed a potential threat to human beings. Predicting atmospheric dispersion and estimating its source become increasingly important in emergency management. Current dispersion prediction and source estimation models cannot satisfy the requirement of emergency management because they are not equipped with high efficiency and accuracy at the same time. In this paper, we develop a fast and accurate dispersion prediction and source estimation method based on artificial neural network (ANN), particle swarm optimization (PSO) and expectation maximization (EM). The novel method uses a large amount of pre-determined scenarios to train the ANN for dispersion prediction, so that the ANN can predict concentration distribution accurately and efficiently. PSO and EM are applied for estimating the source parameters, which can effectively accelerate the process of convergence. The method is verified by the Indianapolis field study with a SF₆ release source. The results demonstrate the effectiveness of the method.

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The chemical industry is very important for the world economy and this industrial sector represents a substantial income source for developing countries. However, existing regulations on controlling atmospheric pollutants, and the enforcement of these regulations, often are insufficient in such countries. As a result, the deterioration of surrounding ecosystems and a quality decrease of the atmospheric environment can be observed. Previous works in this domain fail to generate executable and pragmatic solutions for inspection agencies due to practical challenges. In addressing these challenges, we introduce a so-called Chemical Plant Environment Protection Game (CPEP) to generate reasonable schedules of high-accuracy air quality monitoring stations (i.e., daily management plans) for inspection agencies. First, so-called Stackelberg Security Games (SSGs) in conjunction with source estimation methods are applied into this research. Second, high-accuracy air quality monitoring stations as well as gas sensor modules are modeled in the CPEP game. Third, simplified data analysis on the regularly discharging of chemical plants is utilized to construct the CPEP game. Finally, an illustrative case study is used to investigate the effectiveness of the CPEP game, and a realistic case study is conducted to illustrate how the models and algorithms being proposed in this paper, work in daily practice. Results show that playing a CPEP game can reduce operational costs of high-accuracy air quality monitoring stations. Moreover, evidence suggests that playing the game leads to more compliance from the chemical plants towards the inspection agencies. Therefore, the CPEP game is able to assist the environmental protection authorities in daily management work and reduce the potential risks of gaseous pollutants dispersion incidents.

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