On the dynamic nature of Mo sites for methane dehydroaromatization

Conference paper (2019)

Authors

F. Kapteijn

I. Vollmer

B. van der Linden , ChemE/O&O groep -

Samy Ould-Chikh King Abdullah University of Science and Technology

I. Yarulina King Abdullah University of Science and Technology,

A.I. Olivos Suarez

J. Gascon Sabate King Abdullah University of Science and Technology

Mo/HZSM-5 Methane dehydroaromatization Labelling experiments Molybdenum carbide

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Published Date

2019

Language

English

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Abstract

The mechanism of methane activation on Mo/HZSM-5 is poorly described, despite the great interest in methane dehyd roa romatization (MDA) to replace oil refineries for producing aromatics. It is difficult to assess the exact nature of the active site due to fast coking. By pre-carburizing Mo/HZSM-5 with carbon monoxide, the active site for MDA can be isolated and studied without the formation of coke. This strategy helped us examine how methane is activated on the catalytic site by carrying out MDA using isotopically labelled methane (^{1 3} C H ₄ ) . We show that carbon originating from the preformed carbide is incorporated into the main products of the reaction, ethylene and benzene, demonstrating the dynamic nature of these active sites.