This study compares the degradation behavior of the alkali-activated slag/fly ash (AASF) and ordinary Portland cement (OPC) mortars exposed to phosphoric acid with different pH values. The experimental results show that AASF mortars exhibit better resistance than OPC mortars against surface damage, although both systems get white deposits on the surface in phosphoric acid with a relatively high pH level. AASF mortars obtained lower mass loss than OPC mortars in phosphoric acid with pH at 2 and 3. The strength reduction in AASF mortars after immersion in phosphoric acid is more significant than that in OPC mortars. However, total degradation depth of AASF was smaller than that of OPC regardless of the pH of the acid solutions. Based on the experimental data, linear relationships were identified between the slope of degradation depth–mass loss curves and the Al/Si and Ca/Si ratios of the binders. This may indicate a new way to assess the degradation behavior of AASF and OPC based on their chemical compositions.@en

In this research, the effects of natural seawater (SW) on the properties of alkali-activated slag/fly ash (AASF) are studied. AASF prepared with deionized water is set as the reference mixture. The results showed that the use of natural SW resulted in a prolonged setting time and lower heat release, but no obvious impact on the flowability of AASF specimens. The long-term compressive strength became higher when SW was used, whereas the corresponding flexural strength and fractural toughness turned lower. The use of SW induced the formation of new products that were not identified in the reference mixture, such as Cl–hydrocalumite and gypsum. In addition, it is evidenced that the dissolution of fly ash (FA) particles was significantly delayed with the incorporation of SW. All these results were related to the various ions introduced by the natural SW and their interactions with the alkaline activator as well as the precipitation of salts on slag and FA surfaces or in the matrix.

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