Metal hydrides may play a paramount role in a future hydrogen economy. While most applications are based on nanostructured and confined materials, studies considering the structural response of these materials to hydrogen concentrate on bulk material. Here, using in situ in- and out-of-plane X-ray diffraction and reflectometry, we study the fcc ↔fct transition in Hf thin films, an optical hydrogen-sensing material. We show that the confinement of Hf affects this transition: compared to bulk Hf, the transition is pushed to a higher hydrogen-to-metal ratio, the tetragonality of the fct phase is reduced, and phase coexistence is suppressed. These nanoconfinement effects ensure the hysteresis- free response of hafnium to hydrogen, enabling its remarkable performance as a hydrogen-sensing material. In a wider perspective, the results highlight the profound influences of the nanostructuring and nanoconfinement of metal hydrides on their structural response to hydrogen with a significant impact on their applicability in future devices.@en

We study a problem related to the spin-coating process in which a fluid coats a rotating surface. Our interest lies in the contact-line region for which we propose a simplified travelling wave approximation. We construct solutions to this problem by a shooting method that matches solution branches in the contact-line region and in the interior of the droplet. Furthermore, we prove uniqueness and qualitative properties of the solution connected to the fourth-order nature of the equation, such as a global maximum in the film height close to the contact line, elevated from the average height of the film.@en