The RILEM TC 272 PIM (Phase and Interphase behaviour of innovative bituminous Materials) – TG1 Binder has initiated an inter-laboratory program investigating the phase and interphase behaviour of bituminous binders. Five laboratories evaluated the low temperature properties of seven standard and complex binders with differential scanning calorimetry (DSC). DSC has been accepted as a powerful tool to evaluate, among others, the glass transitions, Tg, monitoring the endothermic or exothermic heat flow of a material under controlled temperature conditions. There are different ways to run the test, conventional temperature linear-DSC (TL-DSC), and temperature modulation-DSC (TM-DSC). The latter has been proven as an efficient method differentiating the structural relaxation phenomena from the heat capacity. In this study, emphasis was laid on comparing the Tg measured by TL- and TM-DSC improving the interpretation of binder glass transitions. To restrain the scope of this study, two SBS polymer modified binders (PmBs), a commercially available PmB and an highly modified PmB (7.5 % SBS) , were evaluated and compared with two neat bituminous binders. It was observed that the modification by 7.5% SBS resulted in a decrease of the Tg. This reduction of Tg reflects the positive influence of SBS at low temperatures. @en

In the past years, the use of liquid additives as bitumen modifiers has increased to enhance or adjust the properties of bitumen for wide range of applications. Their molecular composition and mutual interaction result in a specific phase morphology in the binders. Hence, there is a need to evaluate the phase and interphase framework and physical properties of complex binders. The RILEM Technical Committee 272-PIM ‘Phase and Interphase behaviour of innovative bituminous Materials’, Task Group TG1 investigates the characterization of assessing phase interphase properties of complex bituminous binders. In this framework, three liquid additives have been selected with different viscosity, nature and use. They were blended with base bitumen to achieve similar consistency and the blends were further aged. Physical properties were evaluated through rheology using dynamic shear rheometer (DSR) in a wide range of conditions. The phase morphology was addressed by atomic force microscopy (AFM), differential scanning calorimetry (DSC) techniques. AFM and DSC results, from fresh and aged binders, reveal that each binder display specific phase morphology and glass transition characteristics, manifesting mutual compatibility of the individual binder components. This approach of binder assessment: combining phase characteristics and rheological response can assist material selection to specific applications.@en

The RILEM TC 272 PIM (Phase and Interphase behavior of innovative bituminous Materials)—TG1 Binder has initiated an inter-laboratory program investigating the phase and interphase behaviour of bituminous binders. Within the scope, four laboratories evaluated the low temperature properties of seven binders with differential scanning calorimetry (DSC). DSC has been accepted as a powerful tool to evaluate, among others, the glass transitions, Tg, monitoring the endothermic or exothermic heat flow of a material under controlled temperature conditions. There are different ways to run the test, conventional temperature linear-DSC (TL-DSC), and temperature modulation-DSC (TM-DSC). The latter has been proven as an efficient method differentiating the structural relaxation phenomena from the heat capacity. In this study, emphasis was placed on comparing the Tg measured by TL- and TM-DSC to improve the interpretation of binder glass transitions. In this study, the scope was restrained to two Polymer modified Binders (PmBs): a commercially available modified binder named PmB1 and a highly modified binder (7.5 wt% high vinyl SBS) named PmB2, were evaluated and compared with two neat bituminous binders. Based on the thermographs of the PmB2 obtained through this inter-laboratory program, it was observed that the modification by 7.5% SBS resulted in a decrease of the Tg. This reduction of Tg reflects the positive influence of SBS at low temperatures.@en

The asphalt industry is constantly working to enhance the performances of asphalt materials, introducing innovative and more sustainable solutions. In this context, the incorporation of materials, such as additives, polymers, is more and more used to improve the properties of neat bitumen. This leads to even more complex bituminous binders, raising the question, are the current specifications and test methods appropriate for complex materials? To deal with this, the RILEM Technical Committee 272-PIM ‘Phase and Interphase behaviour of innovative bi-tuminous Materials’ with its Task Group TG1 is looking at the efficiency of vari-ous test methods for complex binders with an extensive inter-laboratory program with 17 laboratories. It includes seven different binders, two neat bitumen, two polymer modified bitumen and three binders with liquid additives, emphasising on compositional and physical changes at different conditions. The focus is low temperature; while a complementary experimental program encompasses as well as testing at intermediate and high temperatures. The outcomes of the work will provide indications on how robust the current binder characterisation techniques are and establish technical recommendations for future test methods specially de-signed for complex binders. Some first results are presented hereby.@en