Producing hard carbon from lignocellulosic biomass has been the focus of recent studies as a promising source of anode material for Na-ion batteries. Woody biomass is a potential source, but it is already well valorized. Consequently, river driftwood can be an excellent alternative, especially since it is a disturbing waste for dam regulators. It can jeopardize dam safety, damage intake works, and sink in reservoirs, lowering water quality and decreasing reservoir volume. We examine the potential of river driftwood as a source of hard carbon for Na-ion batteries. Hydrothermal carbonization (HTC) was carried out at temperatures between 180 and 220 °C as the first step to produce hydrochar followed by an upgrading pyrolysis step at 1400 °C under an inert atmosphere to obtain hard carbon. We investigated the effect of HTC operational conditions and driftwood biomass (genera) on hydrochar and hard carbon properties, as well as the latter's impact on Na-ion batteries. The produced carbon electrodes delivered a reversible capacity of 270–300 mAh·g^-1 for the first cycle and showed high coulombic efficiencies of 77–83%. We also observed promising cyclability of a maximum 2% loss after 100 cycles. Moreover, results suggest that obtained hard carbon can compete with commercial materials and is capable to supply large battery factories with anode material.

Driftwood in river catchments might pose a hazard for the safety of infrastructures, such as dams and river dwellers, and thus is often removed. Génissiat dam in France presents a case study where annually approximately 1300 tons of driftwood are removed to prevent driftwood sinking and to protect the dam infrastructure. Collected river driftwood is rarely studied for utilization purposes and is commonly combusted or landfilled. However, driftwood can be valorized for biochar production through pyrolysis or hydrothermal carbonization (HTC). This study follows a novel approach in characterizing river driftwood by identifying the different common genera present at Génissiat dam on the upper Rhône, France. Moreover, the research provides for the first time a comprehensive analysis of river driftwood different physico-chemical properties, such as moisture content, major elemental composition (CHNSO), HHV, and macromolecular composition (cellulose, hemicellulose, lignin, and extractives). The study shows that the transportation of driftwood through rivers can enhance its properties by reducing the bark content resulting in lower ash content. Results indicate that driftwood can be mixed and further processed as a feedstock regardless of their genera and type for biochar production by pyrolysis or hydrothermal carbonization.