Energy transition is a result of mankind’s reaction to climate change and individuals are expected to have a crucial role in achieving it in developed countries. The purpose of this study is to apply the social life cycle assessment (S-LCA) tool and investigate the social performance of the Dutch energy transition while focusing on individual behavior, and if this is not possible, to develop indicators focusing on individual behavior dimension. The social performance of the energy transition in the Netherlands was assessed on a hotspot level. Additionally, the S-LCA guidelines were examined to identify the human dimension and behavior in the existing subcategories, and environmental psychology literature was explored to identify drivers and behavior that are important for the energy transition. Existing subcategories fail to show the extent of social progress of the Dutch energy transition nor how individuals perceive it. As a result, a total of 8 subcategories and 25 indicators at a hotspot and site-specific levels are developed. These subcategories and indicators focus on prosumer’s and individual’s behaviors, and traits of local communities. Application of the developed hotspot indicators shows that the Dutch government still subsidies fossil energy and, even though Dutch citizens show environmental concerns, the energy transition is delayed due to insufficient top-down coordination. Developed indicators are considered to be both feasible and relevant to investigate the social aspects of the energy transition in developed countries.

Social life cycle assessment (SLCA) was developed to complement the environmental life cycle assessment (LCA) and economic assessment. Contrary to LCA, SLCA is not yet standardized, and the consequential approach is little discussed in literature. This study aims to perform a consequential SLCA and investigate the applicability of the method in industrial decision making. The aforementioned assessment is done within the Zero Brine project, which works on zero liquid discharge technology for water, salt, and magnesium recovery from brine efluents. The developed SLCA systems are gate-to-gate, and the analysis is performed at two levels: Hotspot and site-specific. The system boundaries consist of a demineralized water (DW) production company, a chlor-alkali company, an electricity provider, a magnesium distributor in the Netherlands, and a Russian mining company. The latter exists only in the boundaries before the change due to the Zero Brine project, because recovered magnesium is expected to replace the Russian magnesium imported in the Netherlands. Within the system boundaries, the stakeholders contributing the most are the DW and the magnesium distributor companies. The former produces the brine and thus recovers the magnesium and salt. The latter is the exclusive distributor of Russian magnesium in the Netherlands. Overall, we find that the recovered magnesium results in improving social performance mainly in "Freedom of association and collective bargaining", "Fair salary", and "Health and Safety" due to decreasing the dependency of the Netherlands on Russia, while increasing operation in a country with much stronger environmental regulation and corporate commitment to sustainability issues. Modelling with SLCA may not result in the expected societal benefits, as the Russian community and workers may not benefit due to the large geographical boundaries of the system under study. Nevertheless, the application of the consequential approach can be considered suitable, yet complicated, for offering decision makers adequate social information. We recommend that decision makers in the DW company invest in magnesium recovery and that decision makers in the magnesium distributor company distribute the recovered magnesium.

Furfural is a very promising product of lignocellulosic biomass-based biorefineries and has the potential to become a useful resource for further conversion and utilization. Aquatic plants show an enormous potential as feedstock since they do not compete for land use, and they require minimal water consumption in a biorefinery concept due to their very high water content. This work is focused on experimental studies of furfural production from water hyacinth (Eichhornia crassipes) by means of aqueous, acid-catalyzed dehydration. The temperature range of the process, and the acid and seawater presence were chosen based on the previous relevant studies. The aim of the study was to determine whether water hyacinth is suitable for furfural production. The experiments were performed between 160°C and 200°C with a water hyacinth concentration of 2 wt%. The results suggest that the effects of acid catalyst presence on biomass dehydration are similar to the case of pure pentose dehydration. Furthermore, the addition of seawater did not have a positive catalytic effect in terms of the furfural yield. The maximum yield was 53.2 mol% based on the C5 sugar content in the original biomass. The furfural yield of 7.9 wt% of water hyacinth input was comparable to the yield of feedstocks such as corn cob, bagasse, and oat's residue and higher than the cases of rice straw or hulls. Thanks to the comparatively high pentose potential, water hyacinth shows promising results as a candidate feedstock for furfural production. A certain variability of pentosan should be taken into account, as the chemical composition of the plant depends on the source and harvesting seasons.

This study evaluates whether a transition of large ports facilities to biofuel production for mobility improves the environmental performance and satisfies the renewable energy directive (RED) and it is the first LCA study that considers biofuel production from torrefied wood. The systems studied are wood, torrefied wood, and straw pellets circulating fluidized bed gasification for H₂, synthetic natural gas, or Fischer–Tropsch (FT) diesel production and use. These systems are evaluated for their global warming, acidification, eutrophication and particulate matter potentials, as well as, for their aggregated environmental performance. The effects of the electricity mix selection and ecoinvent database’s economic allocation are also analyzed. All biomass systems result in a better aggregated environmental performance and benefits for the global warming potential. However, regarding the acidification, particulate matter, and eutrophication potentials, most biomass systems are inferior to the reference systems. Switching to a zero-emission electricity mix offers benefits for all the biomass and fossil-H₂ systems and researchers should use databases cautiously. The bio-H₂ and FT diesel of wood-based systems show the best environmental performance and satisfy the current and future RED targets. On one hand, the bio-H₂ systems result in the largest benefits regarding the global warming potential, and on the other hand, both wood-based FT diesel systems offer overall benefits which concern not only the sustainable target of CO₂ emissions reduction, but also the air quality improvement of the broader area as well.

Torrefaction is a promising biomass upgrading technology as it makes biomass more coal alike and offers benefits in logistics and handling operations. Gasification is an attractive thermochemical conversion technology due to its flexibility in the product gas end-uses. Therefore, it is valuable to investigate whether additional benefits are foreseen when torrefaction is coupled with gasification. Therefore, two commercial torrefied wood fuels and their parent materials are gasified at 800–850 °C under atmospheric steam-oxygen circulating fluidized bed gasification conditions and magnesite as bed material. The torrefied feedstocks consisted of wood residues torrefied by Topell at 250 °C (Topell black), and mixed wood and wood residues torrefied by Torrcoal at 300 °C (Torrcoal black). The gasification results show that torrefaction resulted in an increased gas quality, as it yielded higher H₂ and CO contents, a decrease of the CO₂ content, increased gas yield and a significant decrease of the total tar content for both feedstocks. For the Torrcoal samples, torrefaction resulted in a decrease in the carbon conversion efficiency (CCE). In addition, the cold gas efficiency (CGE) remained approximately the same due to the increase in the H₂ and CO contents. The Topell samples showed an increase in the CCE and CGE upon torrefaction, but this could be attributed to a significant grinding in the screw feeder. It is generally concluded that both torrefied fuels may offer benefits as a feedstock for steam-oxygen blown circulating fluidized bed gasification, in particular in terms of gas quality and yield.

Torrefaction is a promising biomass upgrading method, offering advantages in logistics and handling. Gasification is an attractive thermochemical conversion technology due to its flexibility in the product gas end-use. The aim of this paper is to investigate the impact of torrefaction on the gasification performance of a softwood (spruce) and a hardwood (ash). Spruce and ash were torrefied at 260 and 280 °C, and at 250 and 265 °C, respectively, and pelletized. All feedstocks were gasified at 850 °C and atmospheric pressure under oxygen-steam circulating fluidized bed gasification conditions, with magnesite as bed material and with an equivalence ratio (ER) of 0.3 and a steam-to-biomass mass ratio (SBR) of 1.0. Only the torrefied feedstocks were gasified varying ER and SBR values. The results show that torrefaction affected the gasification performance of both feedstocks leading to decreasing the cold gas and carbon conversion efficiencies. For spruce, torrefaction did not affect the permanent gas composition but led to a decrease of the total tar content for both spruce 260 and spruce 280. For ash, torrefaction resulted in decreasing the CH₄ volume fraction, and increasing the H₂ volume fraction and the total tar content for both torrefaction temperatures. Varying the ER and SBR affected only the Class 3 tars of ash 250. Conclusively, torrefaction of spruce and ash did not offer substantial benefits on the gasification performance under the investigated conditions. It is suggested that research of torrefied wood gasification includes feedstock's chemical analysis and characterization of products obtained under fast devolatilization conditions.

There are various attempts to industrialize the supercritical water gasification (SCWG) of wet biomass process, however, there are still process challenges to overcome. Such challenges include slurry pumpability, energy efficiency, low conversion, char and tar formation, and clogging problems due to salt precipitation. Fortunately, some of the aforementioned challenges can be eliminated by having long residence times, high heating rates and utilization of fluidized bed reactors. This study presents the first results and experiences obtained from the TU Delft/Gensos semi-pilot scale setup which has a capacity of 50 kg/h and incorporates a fluidized bed reactor. A dry starch concentration of 4.4 wt % was used as feedstock. Reactor temperatures of 500 °C, 550 °C and 600 °C, and the mass flow rates of 24.5 kg/h and 35 kg/h were tested. The results indicate that the heating profile in the heat exchanger and the residence time at higher temperatures (>500 °C) play a significant role in the conversion efficiencies. No clogging problem was observed, however small quantities of char (2.3 wt % at highest) and oil production (10.4 wt % at highest) were observed. The highest carbon gasification efficiency was 73.9% and this was obtained at a reactor temperature of 600 °C and at a feed flow rate of 24.5 kg/h.