One of the manifestations of chirality-induced spin selectivity is the appearance of a magnetocurrent. Magnetocurrent is defined as the difference between the charge currents at finite bias in a two terminal device for opposite magnetizations of one of the leads. In experiments on chiral molecules assembled in monolayers the magnetocurrent is dominantly odd in bias voltage, while theory often yields an even one. From theory it is known that the spin-orbit coupling and chirality of the molecule can only generate a finite magnetocurrent in the presence of interactions, either of the electrons with vibrational modes or among themselves, through the Coulomb interaction. Here we analytically show that the magnetocurrent in bipartite-chiral structures mediated through Coulomb interactions is exactly even in the wide band limit and exactly odd for semi-infinite leads due to the bipartite lattice symmetry of the Green’s function. Our numerical results confirm these analytical findings.

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In this thesis we perform a theoretical study on the Chirality Induced Spin Selectivity effect in the context of two-terminal measurements for realistic parameters. In twoterminal measurements on chiral molecules one of the leads is magnetized and the current is measured for opposite magnetizations. In experiment it is found that the currents for opposite magnetizations are different for finite bias voltage. We call this finite difference a magnetocurrent. The magnetocurrent is odd in bias voltage and the size of the effect of the order of a few percent. Our aim is to explain this effect through modeling junctions with interactions and the spin-orbit where we always use choose realistic parameters.@en

One of the manifestations of chirality-induced spin selectivity (CISS) is the appearance of a magnetocurrent. Magnetocurrent is the observation that the charge currents at finite bias in a two terminal device for opposite magnetizations of one of the leads differ. Magnetocurrents can only occur in the presence of interactions of the electrons either with vibrational modes or among themselves through the Coulomb interaction. In experiments on chiral molecules assembled in monolayers, the magnetocurrent seems to be dominantly cubic (odd) in bias voltage while theory finds a dominantly even bias voltage dependence. Thus far, theoretical work has predicted a magnetocurrent which is even bias. Here we analyze the bias voltage dependence of the magnetocurrent numerically and analytically involving the spin-orbit and Coulomb interactions (through the Hartree-Fock and Hubbard One approximations). For both approximations it is found that for strong Coulomb interactions the magnetocurrent is dominantly odd in bias voltage, confirming the symmetry observed in experiment.

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One of the manifestations of chirality-induced spin selectivity is the magnetoresistance (MR) in two-terminal transport measurements on molecular junctions. This paper investigates the effect of spin-orbit coupling in the leads on the polarization of the transmission. A helicene molecule between two gold contacts is studied using a tight binding model. To study the occurrence of MR, which is prohibited in coherent transport, as a consequence of the Büttiker reciprocity, we add Büttiker probes to the system in order to incorporate inelastic scattering effects. We show that for a strict two-terminal system without inelastic scattering, the MR is strictly zero in the linear and nonlinear regimes. We show that for a two-terminal system with inelastic scattering, a nonzero MR does appear in the nonlinear regime, reaching values of the order of 0.1%. Our calculations show that for a two-terminal system respecting time-reversal symmetry and charge conservation, a nonzero MR can only be obtained through inelastic scattering. However, spin-orbit coupling in the leads in combination with inelastic scattering modeled with the Büttiker probe method cannot explain the magnitude of the MR measured in experiments.

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