Flint, or chert, sources in the Rhine-Meuse delta are generally distinguished based on macroscopic characteristics such as fossil inclusions, colour variations, and translucency. Previous studies on chemical characterisations of flint sources proved challenging due to the variation and overlap between different sources. Energy Dispersive X-ray Fluorescence (ED-XRF) analysis, therefore, cannot, in our view, be used as an alternative to these traditional sourcing methods. Nevertheless, in this paper, we demonstrate that X-ray spectrometry can be used as a viable method when used in tandem with traditional methodologies. Macroscopically, Spiennes and Lanaye flints, notably Rijckholt flint, cannot be distinguished based on variations in colour, texture, and microfossil content. In the present study, we used a non-destructive portable ED-XRF to distinguish Spiennes, Rijckholt, and eluvial Lanaye flints. While it proved impossible to distinguish between different Lanaye sources, it is possible to distinguish between Spiennes and Lanaye flints based on the higher phosphorus concentrations in Spiennes flint. The archaeological implications have been studied using material derived from four Neolithic Vlaardingen Culture (3400–2500 BC) sites in the Rhine-Meuse delta. We demonstrated that Spiennes and Lanaye flints were present at all sites. Proximity to either of these sources was not a decisive factor in procurement strategies. Flint was exchanged both via the Meuse (leading to the Lanaye flint sources) and the Scheldt (leading to Spiennes). The four selected Vlaardingen Culture sites are located at the intersection between these exchange routes. This favourable location provided good access to high-quality exotic flint at these sites.

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This paper addresses technological dynamics revealed through raw material analyses of Late Hallstatt (seventh–fifth centuries BCE) ceramics from the famous Heuneburg site (Herbertingen-Hundersingen, SW Germany). The study combines, for the first time, separate sets of thin-sections produced over the last 50 years in order to provide a comprehensive and consolidated characterisation of technological changes in ceramic production taking place at the site during the Hallstatt phases D1 to D3. It provides significant new insights into the relation between raw material procurement and preparation, on the one hand, and changes in ceramic typology and production methods, on the other hand (i.e. the introduction of the potter’s wheel). The results reveal a shift from a broad spectrum of fabrics tempered with grog, sand or crushed calcite in phase Hallstatt D1, to the increasing use of non-calcareous, grog or sand-tempered fabrics. The new wheel-turned pottery (appearing from phase Hallstatt D3) is exclusively produced using a non-calcareous clay, often tempered with fine sand, indicating a specialisation in raw material selection alongside the introduction of novel shaping techniques. Evidence of continuity between the fabrics used in phase Hallstatt D1 and the new wheel-turned pottery suggests craft specialists drew upon established technological knowledge to integrate the potter’s wheel. The adoption of the potter’s wheel was likely also stimulated by the increased demand for new vessels to accommodate the consumption of fermented drinks such as grape wine, fruit wine or beer.

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This research characterizes and reconstructs clay procurement and production practices through the integration of in-situ portable XRF and petrographic analysis on ancient ceramics and clay materials recovered from the Mayales river subbasin (central Nicaragua). A particular choice for this study was the largest and arguably most significant archaeological site in the area, Aguas Buenas (cal 400–1250 CE), a pre-Hispanic indigenous agglomeration consisting of 371 human-made mounds of various shapes arranged in geometric patterns. Microanalytical approaches were applied to reconstruct the use of raw mineral resources in the production of ubiquitous pottery materials found at this site and in its immediate surroundings. The resulting compositional analysis produced geochemical and mineralogical data allowing for the characterisation of distinct, geologically-based compositional groups throughout the valley, improving on the limited geological data resolution previously available. The integrated microscopic and compositional analysis (through p-XRF) of archaeological pottery materials and raw clay samples, generates a number of hypotheses and insights about the nature of the Aguas Buenas site, and its role as a shared space amongst groups living in the Mayales river Subbasin. Additionally, this study provides a solid research framework of investigation that can be employed for more detailed and extensive future studies on pre-Hispanic human occupation in this research area or elsewhere.@en

This paper presents the first archaeometrical data on colonial glazed wares (taches noires) imported in Haiti (Fort Liberté). The analysis evidenced the exclusive presence of Italian taches noires products, dated before 1820 and related to the colonial era. The presence of English wares next to colonial materials demonstrated continuity in the use of landscape after the Independence and the establishment of international trade relationships between the state of Haiti and the British Empire. Results are an important step forward in the understanding of production and movement of the Taches noires ware, which were exported globally between the eighteenth and nineteenth centuries.

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The overall goal of this project is to contribute to reconstruct the innovation mechanisms and development of ceramic production using forensic engineering techniques. Instead of optimizing materials as a driver in modern engineering, here we wish to use these methodologies, but aim to solve questions on advancement in the past fabrication process – and thus ultimately understand the key issues of a less or (un)successful design and subsequent improvement. This paper wishes to address the advantages and constraints regarding to use of basalt in ceramic matrices. By utilizing a standardized set of different test bars comprising different amounts of basalt fired at both 800°C and 1000°C, it can be concluded basalt tempered ceramics have a higher fracture toughness when compared to quartz enriched materials. It is there plausible to identify basalt as a good temper material for (ancient) earthenwares in terms of thermal (shock) activities.@en

A collection of Prime Cultural Heritage artefacts consisting of Egyptian late Middle Kingdom figurines (c. 1850–1700 BCE), made of unfired clay and covered in inscriptions, is kept at the Royal Museums of Art and History (RMAH) in Brussels, Belgium. Several of these hieratic inscriptions curse enemies of the Egyptian state, including Canaanite, Nubian and Libyan entities; thus providing invaluable information for Middle Bronze topography in ancient Near Eastern studies. What makes the extensive Brussels group even more exceptional, is the fact that these figurines were discovered in a closed archaeological context in Saqqara, Lower Egypt. Defining and classifying clay and ancient ceramic provenance groups in Egypt is highly complex due to variability in Nile and marl clay deposits. Chemical characterization of this figurine assemblage (n = 91) allows to effectively study the potential direct use of clays in the vicinity of Saqqara and characterize the nature of the raw materials used. Additionally, it aims to assess the validity of portable XRF spectrometry for this type of materials and its provenance resolution. Analyses show that very similar clays were used to produce the different morphological types of figurines in the assemblage. The chemical profile indicates the use of a mixed source at Saqqara rather than pure marl or Nile clays, which are common for ancient pottery production.

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A total of 119 middle to late second millennium bce pottery samples from six sites in the Kur River Basin (Fars, Iran) were examined to characterize these ceramics and reconstruct their manufacturing technology and the origin of the primary materials. For this, a combined study of handheld XRF and thin-section petrography was performed. The geochemical signatures of these ceramics were defined and interpreted in their archaeological and geological framework, resulting in the determination of different production processes and clay types used for four ceramic wares (Middle Elamite, Qaleh, Shogha and Taimuran) and the identification of possible outcrops used for Shogha–Taimuran production.

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The introduction of the Corded Ware Culture (3000–2500 BCE) is considered a formative event in Europe's past. Ancient DNA analyses demonstrate that migrations played a crucial role in this event. However, these analyses approach the issue at a supra-regional scale, leaving questions about the regional and local impact of this event unresolved. This study pilots an approach to ceramics that brings this small-scale impact into focus by using the transmission of ceramic technology as a proxy for social change. It draws on ethno-archaeological studies of the effects of social changes on the transmission of ceramic production techniques to hypothesise the impact of three idealised scenarios that archaeologists have proposed for the introduction of Corded Ware Culture: migration, diffusion, and network interactions. Subsequently, it verifies these hypotheses by integrating geochemical (WDXRF), mineralogical (petrography), and macromorphological analysis of ceramics with network analysis. This method is applied to 30 Late Neolithic ceramic vessels from three sites in the western coastal area of the Netherlands (Hazerswoude-Rijndijk N11, Zandwerven, and Voorschoten-De Donk). This study concludes that the introduction of Corded Ware material culture is a process that varies from site to site in the western coastal area of the Netherlands. Moreover, the introduction of the Corded Ware Culture is characterised by continuity in technological traditions throughout the study area, indicating a degree of social continuity despite typological changes in ceramics.

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The continued importance of pottery studies for the development of the archaeological discipline can hardly be overstated. In this paper we discuss the pottery found at the settlement at Düzen Tepe (SW Anatolia), following the template of the well-established typological and fabric identification practices developed by the Sagalassos Archaeological Research Project for the Sagalassos Red Slip Ware production from Roman imperial times. A newly devised typology of the late Achaemenid to early Hellenistic (5th to 2nd centuries BCE) material of Düzen Tepe is presented. Comparisons with parallels in pottery material indicate that this material was firmly embedded in a (southwestern) Anatolian framework, generally matching a chronological window from the fourth to third centuries BCE. @en

Petrography has developed into an indispensable tool for ceramic fabric analysis, specifically studying the mineralogical and textural composition of ceramic objects. Petrography is a technique commonly used in geology to describe and classify rocks. Ceramic petrography studies clay-based archaeological or historical materials. Using a polarizing light microscope (PLM) in ceramic studies, the different raw materials used to make a ceramic object can be identified, ranging from clays and other minerals to rock fragments and inorganic or organic temper. The technique moreover feeds into the study of raw material provenance and origin, and is able to discern the different technological procedures followed to make the ceramic object (from shaping to firing), next to providing clues on the function of the object. This information not only helps reconstruct trade and exchange of raw materials and ceramics, but aids in reconstructing society behind the pot.@en

Aegyptiaca-like Domitian’s obelisk is now decorating Bernini’s fountain on Piazza Navona or the Egyptian lions flanking Michelangelo’s stairs towards the Capitol figure prominently amidst Rome’s cultural heritage. Motivations for the import, contextualization, and copying of these objects during the Imperial Roman period are as heavily debated as they are ill understood. Provenance determination plays an important role in these discussions in terms of a (supposed) dichotomy between Egyptian (real) versus egyptianising (copy) but has only been applied stylistically and never been tested analytically. A scientific characterization of the materials themselves is even lacking altogether, as is an investigation into the cultural and symbolic meaning of the materials used. This paper is a first attempt to address these important lacunae on the basis of an explorative study of a selected sample of Egyptian statues from Rome. The identification and provenance attribution of the materials used for these statues are often problematic due to their relatively fine-grained nature and dark color. Therefore, a full non-destructive analysis of Egyptian statues in dark-colored rocks is presented in this study, with the stones evaluated by macroscopic examination and handheld X-ray fluorescence (XRF) analysis. The implemented methodology has allowed a distinction between greywacke and several varieties of granitoid rocks. In order to evaluate the potential for source attribution, a comparison was made between the results of our analyses and geochemical data for several granitoid rocks from Egypt. This has suggested Aswan as most likely source. The results presented here indicate that handheld XRF analysis can be used for the assessment of compositional variability in and potentially for the provenance of granitoid rocks, provided that a fine-grained area of the material can be measured on multiple locations, and if these values can be assessed on (in)consistencies with other published reference materials.@en

Analytical ceramic studies offer the opportunity to determine cultural development and change on the basis of origin and use of raw materials. In this particular study, an archaeometric approach on ceramics in central Pisidia contributes to the discussion of contact and exchange between indigenous communities and several cultural spheres of influence on a long-term timescale (eighth to second centuries bce). Morphological data as well as mineralogical (optical microscopy; n = 273) and chemical composition (by ICP-OES/MS; n = 122) of ceramics and raw materials show distinct resource zones for the production and distribution of ceramics in this connecting region of Anatolia. The use of trace element profiles (REE, HFSE, LILE and TTE) in particular is regarded as instrumental in detailing high-resolution provenancing of ceramics. The ceramic provenance indicates different patterns of material interactions during the Archaic, Classical and Hellenistic periods. A significant increase in regional interaction occurs coinciding with the development of pottery activities at Sagalassos.

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The colors of copper alloys are of particular interest in archaeology and can be characterized quantitatively and systematically. The CIELAB color system can determine different color parameters such as a* b* and L* by means of a spectrophotometer that describes the surface color. Additional information such as C* and h values can be calculated from these parameters which allows one to build a set of color-composition diagrams that connects chromaticity and alloy composition. With such data it is possible to estimate the color of prehistoric metal artifacts with similar chemical composition. A better understanding of the association between metallurgical composition and color will aid the research of prehistoric metalwork because choices in production and use of metal were likely influenced by this particular quality of metal.

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The Egyptian collection of the RMAH comprises about one hundred execration figurines made of unbaked clay, bearing curses written in hieratic script (a cursive writing system related to hieroglyphs) and dating to the Middle Kingdom (c. 1850 BC). These represent captured (foreign) enemies and were buried ritually in order to symbolically neutralise foreign and domestic enemies and general threats. Nearly 90 years after their discovery, the red and black pigments used to inscribe these four millennia old objects are now faded or damaged. The Execration texts on these figurines are regarded as one of the most renowned collections of written sources for ancient Near Eastern studies, Egyptian history and Biblical studies for the early 2nd millennium BCE. When it comes to documenting every characteristic of an object in a highly detailed way, clay artefacts inscribed with ink and other pigments, such as the aforementioned figurines, pose a particular challenge. These three-dimensional media with curved surfaces hold traces of writing that, in some cases, have faded or have disappeared completely. The study of these objects is generally hampered by their poor state of conservation, any handling can result in a considerable loss of material (and therefore also valuable information). The EES project aimed to develop new imaging techniques (using interactive 2D, 3D and multispectral images) that can improve the legibility of faded inscriptions and enhance the decorations on clay objects. Combining 3D digitisation and multispectral imaging in a user-friendly and transportable system, that is also manageable by curators, conservators, researchers and other stakeholders in the museum, is a truly pioneering project. It must facilitate the management of recorded collections and offer numerous possibilities for historical and art-technical studies on these objects, while the future handling is limited to a minimum, thus ensuring their sustainability.@en