When detecting the presence of partial discharge (PD) activity in the insulation system in high-voltage equipment, the excitation voltages at variable frequency have been widely used instead of power-frequency (50/60 Hz) sinusoidal voltage in order to reduce the charging power. This work reviews the relevant research on PD activity at very low frequency (VLF) method, including sinusoidal or cosine-rectangular voltage shape, and damped AC (DAC) method. Based on the research history and development status, some major PD characteristics, such as PD inception voltage (PDIV), PD amplitude, PD charge, PD phase-resolved pattern, and several hot issues, such as surface charge decay and statistical time lag, have been discussed. Moreover, the advantages, disadvantages, and applied conditions of two reviewed methods has been summarized. Finally, the prospects have been made on the main development trends of this research field in the future.@en

In this study, we construct a 193 nm ultraviolet laser dissociation high-resolution mass spectrometry (HRMS) platform to produce Pt+ cations with high efficiency, which is in situ applied for monitoring the "Pt+ + alkanes" reactions (where alkanes include methane, ethane, and propane). The conversion intermediates and products could be accurately determined by an orbitrap detector with high resolution (up to 150 000). Importantly, methane conversion by Pt+ cations yields [Pt + ethane]+ and [Pt + ethylene]+ as the sole products formed via the cross-coupling reaction of the Pt-CH2 intermediate with gaseous methane. However, the Pt+ cations promote only the nonoxidative dehydrogenation of ethane and propane to give the corresponding [Pt + alkenes]+ and [Pt + alkynes]+. The details of the reaction mechanism are corroborated by density functional theory (DFT) calculations. These results highlight the power of HRMS with the laser dissociation of metal clusters in the generation and reaction characterization of metal ions.

@en