Potential production and emission of nitrosamines during post-combustion CO₂ capture has drawn some attention due to their toxicity and potential carcinogenicity. One of the possible ways to reduce the concentration of nitrosamines is irradiation of the liquid streams of the capture plant with UV light. This paper shows experimental results of the degradation of nitrosamines such as N-nitroso-diethanolamine (NDELA) and N-mononitroso- piperazine (MNPZ) in different solvent matrices. These solvent matrices include water and laboratory grade monoethanolamine (MEA) aqueous solutions, as well as aqueous MEA solution and wash water that had been used in a CO₂ capture pilot plant connected to a coal-fired power plant. Experiments were conducted in dedicated batch set-ups and in a continuous mini CO₂ capture plant. Results show that the UV absorbance of impurities (degradation products and/or dissolved metals) present in MEA solvent that had been used in a pilot plant significantly reduces the UV degradation rate of nitrosamines. Furthermore, UV light seems to accelerate the degradation of the capture solvent itself. For these reasons, if UV light treatment is to be used in full-scale post-combustion CO₂ capture plants, suitable locations would be the absorber's washing section or the stripper's condensate. At these locations, less interference of degradation products can occur and there is less solvent to be degraded.