We present mm observations constructed from Atacama Large (sub)Millimeter Array (ALMA) data of SO2, SO, and KCl when Io went from sunlight into eclipse (2018 March 20) and vice versa (2018 September 2 and 11). There is clear evidence of volcanic plumes on March 20 and September 2. The plumes distort the line profiles, causing high-velocity (≥500 m s-1) wings and red-/blueshifted shoulders in the line profiles. During eclipse ingress, the SO2 flux density dropped exponentially, and the atmosphere re-formed in a linear fashion when reemerging in sunlight, with a "post-eclipse brightening"after ~10 minutes. While both the in-eclipse decrease and in-sunlight increase in SO was more gradual than for SO2, the fact that SO decreased at all is evidence that selfreactions at the surface are important and fast, and that in-sunlight photolysis of SO2 is the dominant source of SO. Disk-integrated SO2 in-sunlight flux densities are ~2-3 times higher than in eclipse, indicative of a roughly 30%-50% contribution from volcanic sources to the atmosphere. Typical column densities and temperatures are N≈(1.5±0.3)×1016 cm-2 and T ≈ 220-320 K both in sunlight and in eclipse, while the fractional coverage of the gas is two to three times lower in eclipse than in sunlight. The low-level SO2 emissions present during eclipse may be sourced by stealth volcanism or be evidence of a layer of noncondensible gases preventing complete collapse of the SO2 atmosphere. The melt in magma chambers at different volcanoes must differ in composition to explain the absence of SO and SO2, but simultaneous presence of KCl over Ulgen Patera.

We obtained the first maps of Jupiter at 1-3 mm wavelength with the Atacama Large Millimeter/Submillimeter Array (ALMA) on 2017 January 3-5, just days after an energetic eruption at 16.5S jovigraphic latitude had been reported by the amateur community, and about two to three months after the detection of similarly energetic eruptions in the northern hemisphere, at 22.2-23.0N. Our observations, probing below the ammonia cloud deck, show that the erupting plumes in the South Equatorial Belt bring up ammonia gas from the deep atmosphere. While models of plume eruptions that are triggered at the water condensation level explain data taken at uv-visible and mid-infrared wavelengths, our ALMA observations provide a crucial, hitherto missing, link in the moist convection theory by showing that ammonia gas from the deep atmosphere is indeed brought up in these plumes. Contemporaneous Hubble Space Telescope data show that the plumes reach altitudes as high as the tropopause. We suggest that the plumes at 22.2-23.0N also rise up well above the ammonia cloud deck and that descending air may dry the neighboring belts even more than in quiescent times, which would explain our observations in the north.