Enhancing gas-liquid mass transfer is key to promote gas hydrate formation kinetics. Encapsulation of CO₂ hydrate is expected to dramatically increase gas-liquid contact to enhance mass transfer. However, gas hydrate encapsulation has never been proposed as the technical issues of gas permeation through capsule shells have never been addressed. In this work, based on the principles of biomimetics, we proposed a novel red blood cell (RBC) inspired carbon capture capsule to promote CO₂ hydrate formation kinetics. An experimentally validated model is established to compare the carbon capture performance in an RBC-shaped and a spherical capsule. It is revealed that the gas uptake efficiency of the RBC-shaped capsule is 143% higher than that of the spherical one. The effect of initial pressure and capsule size on CO₂ hydrate formation kinetics is also investigated. Furthermore, the structure of RBC is optimised and it is found the average amount of hydrate formation per surface area achieves a peak when the ratio of the height at the centre to the width of the ring is between 0.128 and 0.160, which is close to that of real RBCs in human bodies. This work enables the informed design of hydrate-based carbon capture units with high gas uptake efficiency.

This article proposes a fixed-time adaptive fault-tolerant control methodology for a larger class of high-order (powers are positive odd integers) nonlinear systems subject to asymmetric time-varying state constraints and actuator faults. In contrast with the state-of-the-art control methodologies, the distinguishing features of this study lie in that: (a) high-order asymmetric time-varying tan-type barrier Lyapunov function (BLF) is devised such that the state variables can be convergent to the preassigned compact sets all the time provided their initial values remain therein, which not only preserves the constraints satisfaction, but warrants the validity of the adopted neural network approximator; (b) the proposed control design ensures the tracking errors converge to specified residual sets within fixed time and makes the size of the convergence regions of tracking errors adjustable a priori by means of a new BLF-based tuning function and a projection operator; (c) a variable-separable lemma is delicately embedded into the control design to extract the control terms in a “linear-like” fashion which not only overcomes the difficulty that virtual control signals appear in a non-affine manner, but also solves the problem of actuator faults. Comparative simulations results finally validate the effectiveness of the proposed scheme.