Laser induced predissociation of SF6 clusters

Journal article (1981)

Authors

Jo M.P. Geraedts Radboud Universiteit Nijmegen, Fysisch Laboratorium
S. Setiadi Radboud Universiteit Nijmegen
S. Stolte Radboud Universiteit Nijmegen
J. Reuss Radboud Universiteit Nijmegen
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Published Date

1981

Language

English

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Abstract

Dimer predissociation is sensitively detected as attenuation of the SF+5 ion signal from a SF6 molecular beam crossed by a line tunable cw CO2 laser. The dimer spectra show a double peak structure which is assigned to the symmetric and anti-symmetric combination of the v3 vibration. The minimum observed linewidth is 3 cm-1 fwhm.