Effect of Activator Solutions on the Thixotropic Behavior of Alkali-Activated Slag Concrete

Abstract

Alkali-activated material (AAM) is developed as a green alternative binder to replace Portland cement (PC) in the construction field. However, the large-scale application with AAM concrete is limited so far, with the insufficient knowledge of rheological behavior being a major obstruct. Thixotropy of concrete is of great interest, which can be helpful to predict various early-age performances. The current study dedicates to evaluating the thixotropy of alkali-activated slag (AAS) concrete mixtures with different silicate and water content in activator solutions. In specific, the silicate modulus (Ms) and water to binder (w/b) ratio have been varied. The thixotropic index calculated by the initial and equilibrium shear stress from the stress growth test, as well as the breakdown area obtained by applying different shear speeds were used to evaluate the thixotropy of AAM concrete. Results indicate a good correlation between different approaches. It was found that an increase in Ms led to more pronounced thixotropic behaviors in AAS concrete due to the rapid nucleation and accumulation of early hydration products, resulting in significant increases in peak torque values and slight reductions of torque at equilibrium. Besides, the concrete thixotropy gradually declined by applying a higher w/b ratio.