Thiol-ene polymer beads via liquid–liquid printing: armored interfaces and photopolymerization via graphitic carbon nitride

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Abstract

Polymerization of multifunctional thiol-ene molecules is attractive as a proof of concept in photopolymerization, yet the formation of a bead structure is highly restricted. This manuscript will show graphitic carbon nitride based liquid–liquid printing and subsequent photopolymerization to form thiol-ene polymer beads with extreme simplicity and potential scalability.